Precision Synthesis of Polymer Gels by Pre-Polymerization Crosslinking
| Project/Area Number |
25810126
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Polymer/Textile materials
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| Research Institution | The University of Shiga Prefecture |
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Principal Investigator |
IDA Shohei 滋賀県立大学, 工学部, 助教 (80610740)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
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| Keywords | ゲル / 均一網目 / RAFT重合 / 架橋 / アクリルアミド / 温度応答性 / ラジカル重合 / リビング重合 / RAFT / 刺激応答性 / クリックケミストリー |
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| Outline of Final Research Achievements |
This research aims to establish the new design criteria of polymer gels by “Pre-Polymerization Crosslinking” method, which produces polymer gels by network-expansion polymerization from network-shaped initiator prepared by crosslinking reaction of low-molecule initiator. For this, we examined three topics: (1) the synthesis of a novel bifunctional divinyl crosslinker which could grow to extend the chain-length between two vinyl groups throughout the gelation reacton, (2) the design of homogeneous network structure by end-crosslinking reaction of telechelic polymers, and (3) the regulation of swelling properties by network structure control of polymer gels.
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Report
(3 results)
Research Products
(12 results)
