• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Fabrication of Fluorescent Chiral Sensor Consisting of Conjugated Polymer

Research Project

Project/Area Number 25810127
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Polymer/Textile materials
Research InstitutionAsahikawa National College of Technology

Principal Investigator

SAKAI Ryosuke  旭川工業高等専門学校, 物質化学工学科, 准教授 (90507196)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords共役系ポリマー / キラル / 超分子化学 / ポリジアセチレン / 蛍光分析 / キラルポリマー
Outline of Final Research Achievements

In order to provide an innovative methodology for simple and quick detection of chirality, development of novel chiral sensor consisting of fluorescent conjugated polymer was investigated in this research. A conjugated polymer functionalized with chiral amino groups was found to show fluorescence that varied dependent on the chirality of optically active carboxylic acids. Hence, the polymer was concluded to be applicable to visual inspection of chirality.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (14 results)

All 2015 2014 2013 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results) Presentation (10 results) (of which Invited: 3 results)

  • [Journal Article] Synthesis and chiral recognition of helical poly(phenylacetylene)​s bearing L-​phenylglycinol and its phenylcarbamates as pendants2015

    • Author(s)
      Zhang, Chunhong; Wang, Hailun; Yang, Taotao; Ma, Rui; Liu, Lijia; Sakai, Ryosuke; Satoh, Toshifumi; Kakuchi, Toyoji; Okamoto, Yoshio
    • Journal Title

      Journal of Polymer Science, Part A: Polymer Chemistry

      Volume: 53 Issue: 6 Pages: 809-82

    • DOI

      10.1002/pola.27506

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Helical Poly(Phenylacetylene)s with Amide Linkage Bearing L-Phenylalanine and L-Phenylglycine Ethyl Ester Pendants and Their Applications as Chiral Stationary Phases for HPLC2013

    • Author(s)
      C. Zhang, H. Wang, Q. Geng, T. Yang, L. Liu, R. Sakai, T. Satoh, T. Kakuchi, Y. Okamoto
    • Journal Title

      Macromolecules

      Volume: 46 Issue: 21 Pages: 8406-8415

    • DOI

      10.1021/ma4015802

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Influence of stereoregularity and linkage groups on chiral recognition of poly(phenylacetylene) derivatives bearing L-leucine ethyl ester pendants as chiralstationary phases for HPLC2013

    • Author(s)
      C. Zhang, F. Liu, Y. Li, X. Shen, X. Xu, R. Sakai, T. Satoh, T. Kakuchi, Y. Okamoto
    • Journal Title

      J. Polym. Sci., Part A: Polym. Chem.

      Volume: 51 Issue: 10 Pages: 2271-2278

    • DOI

      10.1002/pola.26611

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chiral Recognition of Helical Poly(Phenylacetylene) Derivatives Bearing L-Amino Acid Ethyl Ester Pendants2013

    • Author(s)
      C. Zhang, H. Wang, F. Liu, X. Shen, L. Liu, R. Sakai, T. Satoh, T. Kakuchi, Y. Okamoto
    • Journal Title

      Acta Polymerica Sinica

      Volume: 6 Pages: 811-816

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 側鎖にキラルアミノ基を有するポリジアセチレンによるカルボン酸のキラル識別2015

    • Author(s)
      小澤駿・中村亮介・津田勝幸・梅田哲・佐藤敏文・覚知豊次・堺井亮介
    • Organizer
      第49回 高分子学会北海道支部研究発表会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-01-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] ロイシン由来のウレア基を有するポリ(フェニルアセチレン)の合成 およびキラル識別能の評価2015

    • Author(s)
      二階堂佑作・小澤駿・酒井直哉・津田勝幸・梅田哲・佐藤敏文・覚知豊次・堺井亮介
    • Organizer
      第49回 高分子学会北海道支部研究発表会
    • Place of Presentation
      北海道大学(北海道札幌市)
    • Year and Date
      2015-01-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 側鎖にキラルアミノ基を有するポリジアセチレンによるキラルセンシング2014

    • Author(s)
      間藤芳允、小澤駿、井上亮平、津田勝幸、梅田 哲、佐藤敏文、覚知豊次、堺井亮介
    • Organizer
      第4回 CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] L-フェニルアラニン由来アミド基を有するポリ(フェニルアセチレン)によるキラル識別2014

    • Author(s)
      小澤 駿、酒井直哉、津田勝幸、梅田 哲、佐藤敏文、覚知豊次、堺井亮介
    • Organizer
      第4回 CSJ化学フェスタ2014
    • Place of Presentation
      タワーホール船堀(東京都)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Conjugated Polymer-Based Sensor for Visual Inspection of Chirality2014

    • Author(s)
      Ryosuke SAKAI
    • Organizer
      Japan-France Joint Seminar on Functional Block Copolymer 2014 (JFJS2014)
    • Place of Presentation
      Hokkaido University, Sapporo
    • Year and Date
      2014-05-21 – 2014-05-22
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Colorimetric Chirality Sensing Based on Conjugated Polymer2013

    • Author(s)
      Ryosuke SAKAI
    • Organizer
      The 20th International SPACC Symposium
    • Place of Presentation
      Changchun, China
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 色彩可変高分子を利用したキラリティーの可視化2013

    • Author(s)
      堺井亮介
    • Organizer
      第29回分析化学緑陰セミナー(日本分析化学会北海道支部主催)
    • Place of Presentation
      旭川
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 側鎖にキラルアミノ基を導入したポリジアセチレンの合成とキラルセンシング

    • Author(s)
      井上亮平・中村亮介・津田勝幸・梅田哲・佐藤敏文・覚知豊次・堺井亮介
    • Organizer
      第 48 回 (2013年度) 高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Related Report
      2013 Research-status Report
  • [Presentation] ロイシン由来のウレア基を有するポリ(フェニルアセチレン)によるキラル識別

    • Author(s)
      奥山しおり, 小澤駿, 津田勝幸, 梅田哲, 佐藤敏文, 覚知豊次, 堺井亮介
    • Organizer
      第 48 回 (2013年度) 高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Related Report
      2013 Research-status Report
  • [Presentation] フェニルグリシン由来アミド基を有するポリ(フェニルアセチレン)のキラル識別能の評価

    • Author(s)
      西山浩史, 小澤駿, 津田勝幸, 梅田哲, 佐藤敏文, 覚知豊次, 堺井亮介
    • Organizer
      第 48 回 (2013年度) 高分子学会北海道支部研究発表会
    • Place of Presentation
      札幌
    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi