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Physical mechanism for suppression of dendritic growth using nanoporous electrodes based on liquid-state theory

Research Project

Project/Area Number 25810135
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

FUKAMI KAZUHIRO  京都大学, 工学(系)研究科(研究院), 准教授 (60452322)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywordsポーラス電極 / 電析 / デンドライト / 金属負極 / ポーラス / ナノポーラス電極 / 充電
Outline of Final Research Achievements

The suppression of dendritic growth observed in electrodeposition has been achieved not by using additives but by using nanoporous electrodes as host matrices. In order to suppress dendritic growth using nanoporous electrodes, it is obvious that metal ions must be supplied effectively. In addition, coexisting ions must be selected appropriately. In particular, cations with a large ionic diameter and thus low charge density are preferable. Low charge density cations, e.x. tetraethylammonium cations, enhance the supply of metal anions such as [PtCl4]2-.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (30 results)

All 2015 2014 2013

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results) Presentation (25 results) (of which Invited: 5 results) Book (1 results)

  • [Journal Article] Spontaneous formation of microgroove arrays on the surface of p-type porous silicon induced by a Turing instability in electrochemical dissolution2015

    • Author(s)
      Kazuhiro Fukami, Tomoko Urata, Katharina Krischer, Naoya Nishi, Tetsuo Sakka, Atsushi Kitada, Kuniaki Murase
    • Journal Title

      ChemPhysChem

      Volume: 16 Issue: 8 Pages: 1613-1618

    • DOI

      10.1002/cphc.201500037

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photo-assisted immersion deposition of Cu clusters onto Porous Silicon: a Langmuir-Hill ligand-locus model applied to the growth kinetics2014

    • Author(s)
      Gonzalo Recio, Dario Gallach, Miguel Manso Silvan, Kazuhiro Fukami, Raul J Martin Palma, German Castro, Alvaro Munoz-Noval
    • Journal Title

      J. Phys. Chem. C

      Volume: 118 Issue: 27 Pages: 14905-14912

    • DOI

      10.1021/jp502108b

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Cations Species on Surface-Induced Phase Transition Observed for Platinum Complex Anions in Platinum Electrodeposition Using Nanoporous Silicon2014

    • Author(s)
      Ryo KODA, Akira KOYAMA, Kazuhiro FUKAMI, Naoya NISHI, Tetsuo SAKKA, Takeshi ABE, Atsushi KITADA, Kuniaki MURASE, and Masahiro KINOSHITA
    • Journal Title

      Journal of Chemical Physics

      Volume: 141 Issue: 7 Pages: 074701-074701

    • DOI

      10.1063/1.4892596

    • NAID

      120005477195

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Lateral growth of polypyrrole electropolymerized along hydrophobic insulative substrates2014

    • Author(s)
      Akira Koyama, Kazuhiro Fukami, Takeshi Yamauchi, Naoya Nishi, Tetsuo Sakka, Atsushi Kitada, Kuniaki Murase
    • Journal Title

      ECS Electrochemistry Letters

      Volume: 未定

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ポーラスシリコン電極へのイオンの浸透挙動2015

    • Author(s)
      今岡勇仁, 小山 輝, 深見一弘, 北田 敦, 邑瀬邦明
    • Organizer
      表面技術協会第131回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2015-03-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノポーラス電極への亜鉛電解析出と錯体種の関係2015

    • Author(s)
      鈴木湧也, 小山 輝, 深見一弘, 北田 敦, 安部武志, 邑瀬邦明
    • Organizer
      表面技術協会第131回講演大会
    • Place of Presentation
      関東学院大学
    • Year and Date
      2015-03-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] ポーラスシリコンの電気化学:ポアの形成と利用2015

    • Author(s)
      深見一弘
    • Organizer
      表面技術協会ARS部会第89回例会(Surtech2015)
    • Place of Presentation
      東京ビッグサイト
    • Year and Date
      2015-01-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ナノポーラス電極の電気化学におけるイオンの協同的振る舞い2014

    • Author(s)
      深見一弘
    • Organizer
      第24回非線形反応と協同現象研究会
    • Place of Presentation
      東京電機大学
    • Year and Date
      2014-12-06
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] ナノ細孔を用いた亜鉛デンドライト抑制効果と錯体種の影響2014

    • Author(s)
      鈴木湧也, 幸田吏央, 小山 輝, 深見一弘, 北田 敦, 安部武志, 邑瀬邦明
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      甲南大学
    • Year and Date
      2014-11-27 – 2014-11-28
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノポーラス電極を用いた亜鉛デンドライト析出の抑制:錯体種の影響2014

    • Author(s)
      鈴木湧也, 幸田吏央, 小山 輝, 深見一弘, 北田 敦, 安部武志, 邑瀬邦明
    • Organizer
      第31回ARS足柄コンファレンス
    • Place of Presentation
      いこいの村あしがら
    • Year and Date
      2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノポーラス電極を用いた亜鉛デンドライト析出の抑制:共存イオンの影響2014

    • Author(s)
      幸田吏央, 小山 輝, 深見一弘, 西 直哉, 作花哲夫, 北田 敦, 安部武志, 邑瀬邦明
    • Organizer
      第31回ARS足柄コンファレンス
    • Place of Presentation
      いこいの村あしがら
    • Year and Date
      2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] p型シリコンの陽極酸化でみられる時空間パターンの温度依存性2014

    • Author(s)
      鈴木湧也, 浦田智子, 深見一弘, 北田 敦, 作花哲夫, 邑瀬邦明
    • Organizer
      第31回ARS足柄コンファレンス
    • Place of Presentation
      いこいの村あしがら
    • Year and Date
      2014-11-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] Spatiotemporal Patterns Formed on p-Type Silicon Electrodes during Electrochemical Dissolution2014

    • Author(s)
      Yuya Suzuki, Tomoko Urata, Kazuhiro Fukami, Atsushi Kitada, Kuniaki Murase
    • Organizer
      226th Meeting of The Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-08
    • Related Report
      2014 Annual Research Report
  • [Presentation] Porosification of silicon from the viewpoint of nonlinear dynamics2014

    • Author(s)
      Kazuhiro Fukami
    • Organizer
      226th Meeting of The Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-08
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Effect of Hydration Property of Pore Wall on Performance of Electric Double Layer Capacitors2014

    • Author(s)
      Yujin Imaoka, Akira Koyama, Ryo Koda, Kazuhiro Fukami, Atsushi Kitada, Kuniaki Murase
    • Organizer
      226th Meeting of The Electrochemical Society
    • Place of Presentation
      Cancun, Mexico
    • Year and Date
      2014-10-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] ルゲート型ポーラスシリコン形成における溶媒の影響2014

    • Author(s)
      竹田直人,浦田智子,深見一弘,作花哲夫,北田敦,邑瀬邦明
    • Organizer
      表面技術協会第129回講演大会
    • Place of Presentation
      東京理科大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Suppression of zinc dendritic growth using microporous electrodes caused by high efficiency of the deposition in confined nanopores2014

    • Author(s)
      Ryo Koda, Kazuhiro Fukami, Yukio H. Ogata, Tetsuo Sakka
    • Organizer
      7th KIFEE International symposium on environment, energy and materials
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Two-dimensional growth of polypyrrole thin films on insulating substrates by electropolymerization2014

    • Author(s)
      Akira Koyama, Kazuhiro Fukami, Takeshi Yamauchi, Naoya Nishi, Tetsuo Sakka, Atsushi Kitada, Kuniaki Murase
    • Organizer
      7th KIFEE International symposium on environment, energy and materials
    • Place of Presentation
      同志社大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 絶縁体表面上における導電性高分子薄膜の二次元成長2014

    • Author(s)
      小山輝,山内健,西直哉,作花哲夫,北田敦,深見一弘,邑瀬邦明
    • Organizer
      日本化学会第94回春季大会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ポーラスシリコンへの白金置換析出:共存カチオンの影響2014

    • Author(s)
      幸田吏央,小山輝,深見一弘,西直哉,作花哲夫,安部武志,北田敦,邑瀬邦明,木下正弘
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ポーラスシリコンへの白金置換析出:孔径と白金錯イオン径の影響2014

    • Author(s)
      小山輝,深見一弘,幸田吏央,西直哉,作花哲夫,安部武志,北田敦,邑瀬邦明,木下正弘
    • Organizer
      電気化学会第81回大会
    • Place of Presentation
      関西大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 溶媒の観点からみた多孔質シリコンへの 金属電析-ナノ細孔の革新的利用法-2013

    • Author(s)
      深見一弘
    • Organizer
      表面技術協会ARS部会第85回例会
    • Place of Presentation
      近畿大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 溶媒の観点からみたナノポーラス電極へ の金属電析2013

    • Author(s)
      深見一弘
    • Organizer
      電気化学会電解プロセス研究会
    • Place of Presentation
      京都大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] ナノ細孔内における白金析出反応の急激な促進2013

    • Author(s)
      幸田吏央,小山輝,深見一弘,西直哉,作花哲夫
    • Organizer
      表面技術協会第128回講演大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 不導体基板上への電解重合による導電性高分子薄膜の二次元成長2013

    • Author(s)
      小山輝,深見一弘,西直哉,作花哲夫
    • Organizer
      表面技術協会第128回講演大会
    • Place of Presentation
      福岡工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノ多孔質電極を用いた亜鉛デンドライト抑制における共存イオン種の影響2013

    • Author(s)
      幸田吏央,深見一弘,西直哉,作花哲夫
    • Organizer
      2013年電気化学秋季大会
    • Place of Presentation
      東京工業大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 疎水性基板表面に形成する液体の局所構造に着目した導電性高分子薄膜の二次元成長2013

    • Author(s)
      小山輝,深見一弘,西直哉,作花哲夫
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ミクロ多孔質電極内の金属析出挙動に置ける共存イオン種の影響2013

    • Author(s)
      幸田吏央,小山輝,深見一弘,西直哉,作花哲夫
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Presentation] シリコンの陽極酸化におけるマイクログルーブの自己組織化的形成2013

    • Author(s)
      浦田智子,深見一弘,Katharina Krischer,作花哲夫
    • Organizer
      第15回関西表面技術フォーラム
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
  • [Book] Handbook of Porous Silicon (Chapter 60)2015

    • Author(s)
      Yukio H. Ogata, Kazuhiro Fukami
    • Total Pages
      1012
    • Publisher
      Springer International Publishing
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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