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Synergetic Electronic Property Based on the Formation of Hetero-Interface

Research Project

Project/Area Number 25810142
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Device related chemistry
Research InstitutionKeio University

Principal Investigator

Yamamoto Takashi  慶應義塾大学, 理工学部, 講師 (40532908)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords超伝導 / 光化学反応 / 電気化学 / 表面修飾 / フォトクロミズム / 光磁気相転移 / 外場応答性分子
Outline of Final Research Achievements

In the current research project, I have developed the photofunctional material, where superconducting properties could be modulated upon photochemical reaction.
First, I have examined the superconducting properties of a boron-doped diamond (BDD). As surface termination of BDD can be easily modified by chemical reactions, I have especially examined the superconducting properties of hydrogen- and oxygen-terminated BDD (denoted as H- and O-BDD). Critical current density was reversibly modulated between H- and O-BDD, derived from changes in the superconducting volume fraction.
Next. I have fabricated a hybrid superconductor composed of BDD and a photochromic azobenzene compound (denoted as AZ-BDD). In AZ-BDD, critical current density was reversibly modulated upon photoisomerization of AZ. The photochromism-induced amplification of critical current density was about 55 % that was 4 times larger than the previous report.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (18 results)

All 2016 2015 2014 2013

All Journal Article (2 results) (of which Peer Reviewed: 2 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Int'l Joint Research: 2 results,  Invited: 3 results)

  • [Journal Article] Photochromism-Induced Amplification of Critical Current Density in Superconducting Boron-Doped Diamond with an Azobenzene Molecular Layer2015

    • Author(s)
      Keisuke Natsui, Takashi Yamamoto, Miku Akahori, Yasuaki Einaga
    • Journal Title

      ACS Applied Materials & Interfaces

      Volume: 7 Issue: 1 Pages: 887-894

    • DOI

      10.1021/am5074613

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Modulation of Critical Current Density in Polycrystalline Boron-Doped Diamond by Surface Modification2013

    • Author(s)
      Keisuke Natsui, Takashi Yamamoto, Takeshi Watanabe, Yoichi Kamihara, Yasuaki Einaga
    • Journal Title

      Physica Status Solidi B

      Volume: 250 Issue: 9 Pages: 1943-1949

    • DOI

      10.1002/pssb.201349058

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] ヘマグルチニン結合性ペプチドを修飾したダイヤモンド電極によるインフルエンザウイルスの高感度検出法の開発2016

    • Author(s)
      氏江 美智子、赤堀 未来、松原 輝彦、山本 崇史、栄長 泰明、佐藤 智典
    • Organizer
      5th Negative Strand Virus-Japan Symposium
    • Place of Presentation
      ホテルモントレ沖縄 (沖縄県・国頭郡恩納村)
    • Year and Date
      2016-01-25
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electrochemical Detection of Influenza Virus Using Hemagglutinin-Binding Peptide-Modified Diamond Electrode2015

    • Author(s)
      Michiko Ujie, Miku Akahori, Teruhiko Matsubara, Takashi Yamamoto, Yasuaki Einaga, Toshinori Sato
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015 (PACIFICHEM 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 超伝導ダイヤモンドにおける臨界電流密度の光制御2015

    • Author(s)
      夏井 敬介、山本 崇史、赤堀 未来、栄長 泰明
    • Organizer
      第29回・ダイヤモンドシンポジウム
    • Place of Presentation
      東京理科大学 (東京都・葛飾区)
    • Year and Date
      2015-11-17
    • Related Report
      2015 Annual Research Report
  • [Presentation] 糖鎖ミミックペプチドを修飾したダイヤモンド電極によるインフルエンザウイルスの電気化学的検出2015

    • Author(s)
      氏江 美智子、赤堀 未来、松原 輝彦、山本 崇史、栄長 泰明、佐藤 智典
    • Organizer
      GlycoTOKYO 2015
    • Place of Presentation
      慶應義塾大学 (神奈川県・横浜市)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] 糖鎖模倣ペプチド固定化ダイヤモンド電極によるインフルエンザウイルスの電気化学的検出2015

    • Author(s)
      松原 輝彦、氏江 美智子、赤堀 未来、山本 崇史、栄長 泰明、佐藤 智典
    • Organizer
      第64回・高分子討論会
    • Place of Presentation
      東北大学 (宮城県・仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Click Functionalization of Boron-Doped Diamond Electrode2015

    • Author(s)
      Takashi Yamamoto, Miku Akahori, Keisuke Natsui, Yasuaki Einaga
    • Organizer
      The 21st China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME’21)
    • Place of Presentation
      Xiamen (CHINA)
    • Year and Date
      2015-09-10
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ペプチド固定化ダイヤモンド電極によるヘマグルチニンおよびインフルエンザウイルスの電気化学的検出2015

    • Author(s)
      氏江 美智子、赤堀 未来、松原 輝彦、山本 崇史、栄長 泰明、佐藤 智典
    • Organizer
      第25回バイオ・高分子シンポジウム
    • Place of Presentation
      東京工業大学 (東京都・目黒区)
    • Year and Date
      2015-07-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] ヘマグルチニン結合性ペプチドを固定したダイヤモンド電極によるインフルエンザウイルスの電気化学的検出2015

    • Author(s)
      氏江 美智子、赤堀 未来、松原 輝彦、山本 崇史、栄長 泰明、佐藤 智典
    • Organizer
      第64回・高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター (北海道・札幌市)
    • Year and Date
      2015-05-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] ホウ素ドープダイヤモンドにおける超伝導特性の光変調2014

    • Author(s)
      山本 崇史、赤堀 未来、夏井 敬介、栄長 泰明
    • Organizer
      2014年・光化学討論会
    • Place of Presentation
      北海道大学 (北海道)
    • Year and Date
      2014-10-11 – 2014-10-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Reversible Photomodulation of Superconducting Property in Boron-Doped Diamond2014

    • Author(s)
      Takashi Yamamoto, Miku Akahori, Keisuke Natsui, Yasuaki Einaga
    • Organizer
      The 20th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME’20)
    • Place of Presentation
      Chengdu, CHINA
    • Year and Date
      2014-09-20 – 2014-09-24
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Functionalization of Superconducting Boron-Doped Diamond via Electro-Click Chemistry2014

    • Author(s)
      Miku Akahori, Keisuke Natsui, Takashi Yamamoto, Yasuaki Einaga
    • Organizer
      65th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Lausanne, SWITZERLAND
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Photocontrollable Superconductivity in boron -Doped Diamond by Immobilizing Co-Fe Prussian Blue2014

    • Author(s)
      Keisuke Natsui, Takashi Yamamoto, Yasuaki Einaga
    • Organizer
      The 14th International Conference on Molecule-Based Mangets (ICMM 2014)
    • Place of Presentation
      Saint Petersburg, RUSSIA
    • Year and Date
      2014-07-05 – 2014-07-09
    • Related Report
      2014 Research-status Report
  • [Presentation] ホウ素ドープダイヤモンドにおける超伝導特性の光制御2014

    • Author(s)
      夏井 敬介・赤堀 未来・山本 崇史・栄長 泰明
    • Organizer
      日本化学会・第94春季年会
    • Place of Presentation
      名古屋大学 (愛知)
    • Related Report
      2013 Research-status Report
  • [Presentation] Boron-Doped Diamond as Superconductor2014

    • Author(s)
      Takashi Yamamoto, Keisuke Natsui, Miku Akahori, Yasuaki Einaga
    • Organizer
      International Symposium on Diamond Electrochemistry
    • Place of Presentation
      Yokohama, JAPAN
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Modulation of Critical Current Density in Superconducting Diamond by Surface Modification2014

    • Author(s)
      Keisuke Natsui, Takashi Yamamoto, Takeshi Watanabe, Yoichi Kamihara, Yasuaki Einaga
    • Organizer
      International Symposium on Diamond Electrochemistry
    • Place of Presentation
      Yokohama, JAPAN
    • Related Report
      2013 Research-status Report
  • [Presentation] Functionalization of Boron-Doped Diamond by Surface Click Modification2013

    • Author(s)
      Miku Akahori, Keisuke Natsui, Takashi Yamamoto, Yasuaki Einaga
    • Organizer
      The 19th China-Japan Bilateral Symposium on Intelligent Electrophotonic Materials and Molecular Electronics (SIEMME’19)
    • Place of Presentation
      Beijing, CHINA
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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