Kinetics study for the systematic development of detailed chemical kinetics model of alcohol combustion
| Project/Area Number |
25820060
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Thermal engineering
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| Research Institution | Nagoya University |
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Principal Investigator |
KANNO Nozomu 名古屋大学, 工学(系)研究科(研究院), 助教 (40529046)
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| Project Period (FY) |
2013-04-01 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
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| Budget Amount *help |
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
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| Keywords | 燃焼 / 化学反応素過程 / アルコール / 反応素過程 |
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| Outline of Final Research Achievements |
The initial steps for the alcohol combustion were investigated from both experimental and theoretical approach. In the case of the reaction of beta-hydroxyethyl radical with molecular oxygen, the stabilization path for the peroxy radicals and the OH dissociation path were suggested to be compete at low pressure and temperature conditions. For the reaction of hydroxymethyl radical with molecular oxygen, quasi-classical trajectory calculation and RRKM calculation was performed. Although non-statistical trajectories were observed, the contribution for the thermal rate coefficients were confirmed to be negligible, thus the rate coefficient prediction based on the RRKM theory should be valid for these type of reactions.
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Report
(3 results)
Research Products
(1 results)
