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Exploring Superconducting Mechanisms of One-Dimensional Metallic Sulfur Crystals inside Carbon Nanotubes

Research Project

Project/Area Number 25820331
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Research InstitutionShinshu University

Principal Investigator

FUJIMORI Toshihiko  信州大学, 先鋭領域融合研究群環境・エネルギー材料科学研究所, 准教授(特定雇用) (60586824)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords一次元電子系 / 硫黄 / カーボンナノチューブ / 一次元結晶
Outline of Final Research Achievements

The aim of this research project was to develop a new way to utilize abundant sulfur. In this research, we successfully synthesized a one-dimensional conductor of elemental sulfur inside carbon nanotubes. To explore a previously unobserved one-dimensional superconductor, we synthesized a hybridized one-dimensional conductor consisting of metallic sulfur and metallic carbon nanotubes. Although superconductivity has not been confirmed directly up to now, we found a clue for a one-dimensional superconducting mechanism of the sulfur-carbon nanohybrids using Raman spectroscopy.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (19 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (12 results) (of which Invited: 6 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] 456. Conducting Linear Chains of Sulfur inside Carbon Nanotubes2013

    • Author(s)
      T. Fujimori, A. Morelos-Gómez, Z. Zhu, H. Muramatsu, R. Futamura, K. Urita, M. Terrones, T. Hayashi, M. Endo, S. Y. Hong, Y. C. Choi, D. Tománek , K. Kaneko
    • Journal Title

      Nature Comm.

      Volume: 4 Issue: 1 Pages: 2162-2169

    • DOI

      10.1038/ncomms3162

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Synthesis of one-dimensional metallic sulfur inside the nano-confined spaces of carbon nanotubes2013

    • Author(s)
      藤森利彦・金子克美
    • Journal Title

      TANSO

      Volume: 2013 Issue: 260 Pages: 292-296

    • DOI

      10.7209/tanso.2013.292

    • NAID

      130003386039

    • ISSN
      0371-5345, 1884-5495
    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] 455. Formation and Properties of Selenium Double-Helices inside Double-Wall Carbon Nanotubes: Experiment and Theory2013

    • Author(s)
      T. Fujimori, R. Batista, D. Santos, T. Hayashi, M. Endo, K. Kaneko, D. Tomanek
    • Journal Title

      ACS Nano

      Volume: 7 Issue: 6 Pages: 5607-5613

    • DOI

      10.1021/nn4019703

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Metallic Sulfur: A New Class of Artificial Nanomaterials inside Carbon Nanotubes2015

    • Author(s)
      Toshihiko Fujimori
    • Organizer
      2015 International Conference on Nanospace Materials (ICNM2015)
    • Place of Presentation
      National Taiwan University, Taipei, Taiwan
    • Year and Date
      2015-06-23 – 2015-06-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] サブナノ空間を鋳型としたカルコゲン元素の一次元伝導体の創製2015

    • Author(s)
      藤森利彦、金子克美
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日本大学理工学部船橋キャンパス
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Beyond Conventional Use of Sulfur: A Challenge toward Metal-Insulator Transitions in Nanospaces2014

    • Author(s)
      Toshihiko Fujimori
    • Organizer
      Invited Talk at The Petroleum Institute
    • Place of Presentation
      The Petroleum Institute, Abu Dhabi, UAE
    • Year and Date
      2014-11-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Utilization of Metallic Sulfur/Nanocarbon Hybrids as a Transparent Conductive Film2014

    • Author(s)
      Toshihiko Fujimori
    • Organizer
      Abu Dhabi International Petroleum Exhibition & Conference (ADIPEC2014)
    • Place of Presentation
      Abu Dhabi, UAE
    • Year and Date
      2014-11-10 – 2014-11-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Beyond Conventional Use of Sulfur: A Challenge toward Metal-Insulator Transitions in Nanospaces2014

    • Author(s)
      Toshihiko Fujimori
    • Organizer
      Invited Talk at Higher College of Technology
    • Place of Presentation
      Higher College of Technology, Abu Dhabi, UAE
    • Year and Date
      2014-11-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Highly crystalline 1D crystals of elemental chalcogens inside carbon nanotubes: A challenge toward transformation of non-metals into metals2014

    • Author(s)
      Toshihiko Fujimori, Katsumi Kaneko
    • Organizer
      The World Conference on Carbon, CARBON2014
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2014-06-29 – 2014-07-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] A New Insight for 1D Chalcogens: Transformation of Non-Metals into Metals inside Carbon Nanotubes2014

    • Author(s)
      T. Fujimori
    • Organizer
      日本化学会第94春季年会 Asian International Symposium- Division of Inorganic Chemistry-
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] A New Insight for 1D Chalcogens: Transformation of Non-Metals into Metals inside Carbon Nanotubes2014

    • Author(s)
      T. Fujimori
    • Organizer
      Seminar at JST-ERATO Itami Molecular Nanocarbon Project
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Atomically one-dimensional crystals of metallic sulfur in carbon nanotubes2013

    • Author(s)
      T. Fujimori
    • Organizer
      The Annual World Conference on Carbon (CARBON2013)
    • Place of Presentation
      Rio de Janeiro
    • Related Report
      2013 Research-status Report
  • [Presentation] Metallization of 1D sulfur crystals inside carbon nanotubes2013

    • Author(s)
      T. Fujimori
    • Organizer
      第45回フラーレン・ナノチューブ・グラフェン学会
    • Place of Presentation
      大阪大学
    • Related Report
      2013 Research-status Report
  • [Presentation] カーボンナノチューブのナノ制約空間による一次元金属化硫黄の合成2013

    • Author(s)
      藤森利彦
    • Organizer
      第40回炭素材料学会年会
    • Place of Presentation
      京都教育文化センター
    • Related Report
      2013 Research-status Report
  • [Presentation] ナノ空間内における一次元結晶の合成~擬高圧光反応による機能デザインをめざして~2013

    • Author(s)
      藤森利彦
    • Organizer
      岡山大学 第9回Future Session
    • Place of Presentation
      岡山大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Book] SPring-8 Research Frontiers 20132014

    • Author(s)
      Toshihiko Fujimori
    • Total Pages
      154
    • Publisher
      ROKKO Publishing & Sale Co.
    • Related Report
      2014 Annual Research Report
  • [Remarks] 世界初「電気をよく流す結晶性硫黄原子鎖」創製の成功を発表

    • URL

      http://archive.is/og61O

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] カーボンナノチューブ/グラフェン複合材料およびその製造方法2014

    • Inventor(s)
      藤森利彦
    • Industrial Property Rights Holder
      信州大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-129637
    • Filing Date
      2014-06-24
    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] カーボンナノチューブ及びその製造方法2013

    • Inventor(s)
      藤森利彦・金子克美
    • Industrial Property Rights Holder
      信州大学
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-11-21
    • Related Report
      2013 Research-status Report
    • Overseas

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Published: 2014-07-25   Modified: 2019-07-29  

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