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Development of metal-organic framework-based separation membranes

Research Project

Project/Area Number 25820385
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

NOBUO Hara  独立行政法人産業技術総合研究所, 化学プロセス研究部門, 主任研究員 (70613545)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords気体分離膜 / 金属有機構造体 / 対向拡散法 / 多孔質物質 / 選択透過 / MOF
Outline of Final Research Achievements

Metal-organic frameworks (MOFs) have attracted tremendous attentions as new materials for separation membranes. In this study, we developed uniquely micro-structured MOF-based molecular sieve membranes by a counter-diffusion method using porous α-alumina hollow substrate. We successively applied the counter-diffusion method for the preparation of zeolitic imidazolate frameworks-8 (ZIF-8) based membranes. Permeation properties were studied using the single-component gas permeation properties, and ideal propylene/propane separation factor of up to 135 was achieved. We clarified the contribution of diffusive separation for propylene/propane with ZIF-8 membranes based on the characterization of diffusion and solution properties from the membrane permeation measurements. The preparation, structural characteristics, and gas permeation properties of the ZIF-8 membranes prepared by the counter-diffusion method are thoroughly studied.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (25 results)

All 2015 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (18 results) Book (2 results)

  • [Journal Article] ZIF-8 membranes prepared at miscible and immiscible liquid-liquid interface2015

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Journal Title

      MICROPOROUS AND MESOPOROUS MATERIALS

      Volume: 206 Pages: 75-80

    • DOI

      10.1016/j.micromeso.2014.12.018

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of temperature on the synthesis of ZIF-8 membranes for propylene/propane separatio2015

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Journal Title

      JOURNAL OF THE JAPAN PETROLEUM INSTITUTE

      Volume: 58

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Thickness Reduction of the Zeolitic Imidazolate Framework-8 Membrane by Controlling the Reaction Rate during the Membrane Preparation2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 47 Issue: 10 Pages: 770-776

    • DOI

      10.1252/jcej.14we340

    • NAID

      130004699180

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Diffusive separation of propylene/propane with ZIF-8 membranes2014

    • Author(s)
      N. Hara, M. Yoshimune, H. Negishi, K. Haraya, S. Hara, T. Yamaguchi
    • Journal Title

      Journal of Membrane Science

      Volume: 450 Pages: 215-223

    • DOI

      10.1016/j.memsci.2013.09.012

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Metal-organic framework membranes with layered structure prepared within the porous support2013

    • Author(s)
      N. Hara, M. Yoshimune, H. Negishi, K. Haraya, S. Hara, T. Yamaguchi
    • Journal Title

      RSC Advances

      Volume: 3 Issue: 34 Pages: 14233-14236

    • DOI

      10.1039/c3ra22733b

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 不混和の溶液界面を用いたZIF-8膜の作製2015

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      化 学工学会第80年会
    • Place of Presentation
      芝浦工業大学(東京)
    • Year and Date
      2015-03-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] プロピレン/プロパン分離用のZIF-8膜の開発2015

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      物質・デバイス領域共同研究拠点シンポジウム
    • Place of Presentation
      東京工業大学(横浜)
    • Year and Date
      2015-03-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属有機構造体膜によるプロピレン/プロパン分離2015

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      環境・エネルギーシンポジウムシリーズ
    • Place of Presentation
      つくば国際会議場(つくば)
    • Year and Date
      2015-02-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZIF-8 Based Separation Membrane2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      Internat ional Symposium on Advanced Materials for Energy & Environment-201
    • Place of Presentation
      Tokyo Institute of Technology(Yokohama)
    • Year and Date
      2014-11-04
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZIF-8膜のプロピレン/プロパン混合ガス分離特性2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学(福岡)
    • Year and Date
      2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] MOF-based Molecular Sieve Membranes Prepared by Counter-Diffusion Metho2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      ICOM201
    • Place of Presentation
      Suzhou(China)
    • Year and Date
      2014-07-20
    • Related Report
      2014 Annual Research Report
  • [Presentation] ZIF-8 membranes for diffusive separation of propylene/propan2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      13th International Conference on Inorganic Membrane
    • Place of Presentation
      Brisbane(Australia)
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属有機構造体膜によるプロピレン/プロパン分離2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      第3回JACI/GSCシンポジウム
    • Place of Presentation
      東京国際フォーラム(東京)
    • Year and Date
      2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] 対向拡散法によるZIF-8膜の作製と薄層化2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      日 本膜学会第36年会
    • Place of Presentation
      早稲田大学(東京)
    • Year and Date
      2014-05-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属有機構造体を用いた機能性分離膜の研究2014

    • Author(s)
      原伸生、吉宗美紀、根岸秀之、原谷賢治、原重樹、山口猛央
    • Organizer
      物質・デバイス領域共同研究拠点第四回活動報告会
    • Place of Presentation
      ホテルメトロポリタン仙台(仙台)
    • Year and Date
      2014-04-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属有機構造体膜を用いたプロピレン/プロパン分離2014

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      環境・エネルギーシンポジウムシリーズ
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] ZIF-8膜の薄層化によるプロピレン透過度の向上2014

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 金属有機構造体を用いた分離膜への挑戦2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      機能性材料を応用したデバイス・システム開発の最前線
    • Place of Presentation
      産業技術総合研究所
    • Related Report
      2013 Research-status Report
  • [Presentation] Cu-BTC membrane with layer structure prepared within the porous α-alumina support2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      第8回メソ構造物質国際シンポジウム IMMS 2013
    • Place of Presentation
      淡路夢舞台国際会議場
    • Related Report
      2013 Research-status Report
  • [Presentation] Cu-BTC Membrane with Layer Structure within the Porous α-Alumina Substrate2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      8th Converence of the Aseanian Membrane Society
    • Place of Presentation
      西安(中国)
    • Related Report
      2013 Research-status Report
  • [Presentation] ZIF-8膜の作製とプロピレン/プロパン透過特性2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      化学工学会第45回秋季大会
    • Place of Presentation
      岡山
    • Related Report
      2013 Research-status Report
  • [Presentation] Diffusive Separation of Propylene/Propane With ZIF-8 Membranes2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      2013 AIChE Annual Meeting
    • Place of Presentation
      サンフランシスコ(アメリカ)
    • Related Report
      2013 Research-status Report
  • [Presentation] 金属有機構造体を用いたプロピレン/プロパン分離膜の開発2013

    • Author(s)
      原 伸生、吉宗 美紀、根岸 秀之、原谷 賢治、原 重樹、山口 猛央
    • Organizer
      物質・デバイス領域共同研究拠点シンポジウム
    • Place of Presentation
      東京工業大学資源化学研究所
    • Related Report
      2013 Research-status Report
  • [Book] 平成26年度物資・デバイス領域共同研究拠点成果報告書2015

    • Author(s)
      原伸生
    • Total Pages
      35
    • Publisher
      物質・デバイス領域共同研究拠点本部
    • Related Report
      2014 Annual Research Report
  • [Book] エネルギー・化学プロセスにおける膜分離技術2014

    • Author(s)
      原伸生
    • Total Pages
      306
    • Publisher
      S&T出版株式会社
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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