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Development of hybrid material of lithium hydroxide and mesoporous silica for high-density chemical heat storage

Research Project

Project/Area Number 25820456
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionNagoya University

Principal Investigator

KUBOTA Mitsuhiro  名古屋大学, 工学(系)研究科(研究院), 助教 (60345931)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords水酸化リチウム / メソポーラスシリカ / ハイブリッド材料 / 水和反応速度 / 化学蓄熱 / 複合材料
Outline of Final Research Achievements

Lithium hydroxide (LiOH)/lithium hydroxide monohydrate (LiOH·H2O) reaction is a promising one for low-temperature thermal energy below 100 degrees Celsius, because LiOH·H2O can store thermal energy around 70 degrees Celsius with density of 1,440 kJ/kg. Towards practical use, hydration rate of LiOH is required to be greatly promoted. To achieve this objective, in this study, a hybrid material of LiOH and mesoporous silica (MPS) was tried to prepare for supporting LiOH particle inside pore of MPS by impregnating method with MPS and LiOH or LiNO3 aqueous solution.
The material was prepared at various LiOH or LiNO3 solution concentrations, impregnation times, and number of impregnations. As a result, it was demonstrated that initial hydration rate for 10 min. and endothermic heat of prepared material were improved compared to pure lithium hydroxide and pure mesoporous silica.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (3 results)

All 2014

All Presentation (3 results)

  • [Presentation] メソポーラスシリカとの複合化による水酸化リチウムの水和速度向上に関する研究2014

    • Author(s)
      松本 怜、窪田 光宏、松田 仁樹
    • Organizer
      第4回潜熱工学シンポジウム
    • Place of Presentation
      東京工業大学大岡山キャンパス(東京都・目黒区)
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 低温熱利用を目指した水酸化リチウム・メソポーラスシリカ複合材料の開発2014

    • Author(s)
      松本 怜、窪田 光宏、松田 仁樹
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学伊都キャンパス(福岡県・福岡市)
    • Year and Date
      2014-09-17 – 2014-09-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] 水酸化リチウムとメソポーラスシリカを併用した低温化学蓄熱材料の開発2014

    • Author(s)
      窪田 光宏、松本 怜、松田 仁樹
    • Organizer
      2014年度日本冷凍空調学会年次大会
    • Place of Presentation
      佐賀大学本庄キャンパス(佐賀県・佐賀市)
    • Year and Date
      2014-09-10 – 2014-09-12
    • Related Report
      2014 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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