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Synthesis of Si based high performance thermoelectric material by fabricating all-scale phonon scattering structure

Research Project

Project/Area Number 25820457
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy engineering
Research InstitutionOsaka University

Principal Investigator

OHISHI Yuji  大阪大学, 工学(系)研究科(研究院), 助教 (20571558)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
KeywordsナノSi / 熱電特性 / 熱電 / ボールミル / コンポジット / ナノ結晶シリコン / 環境調和型熱電材料 / 低熱伝導率
Outline of Final Research Achievements

The thermoelectric properties of heavily doped n-type and p-type single crystal Si were studied. A theoretical model based on the Boltzmann transport equation was developed from the experimentally observed data. A bulk nanocrystalline Si was synthesized by ball milling and spark plasma sintering. TEM observation showed that the grain size was around 50 nm. The thermal conductivity was reduced compared to that of the single crystal Si due to the enhanced phonon scattering at grain boundaries. Further reduction of the thermal conductivity was achieved by adding NiSi2 nanoparticles and Ge impurities. However, the thermoelectric performance was not improved compared to that of Si-Ge alloys. This result suggests that optimization of the sizes of the grains and nanoparticles are necessary to reduce the thermal conductivity significantly and enhance the thermoelectric performance.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (5 results)

All 2015 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (4 results)

  • [Journal Article] Thermoelectric properties of heavily boron- and phosphorus-doped Si2015

    • Author(s)
      Yuji Ohishi, Jun Xie, Yoshinobu Miyazaki, Yusufu Aikebaier, Hiroaki Muta, Ken Kurosaki, Shinsuke Yamanaka, Noriyuki Uchida, and Tetsuya Tada
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 印刷中

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Effect of acid washing on thermoelectric properties of heavily doped p-type nanocrystalline silicon2014

    • Author(s)
      Yusuke Ito, Yuji Ohishi, Hiroaki Muta, Ken Kurosaki, Shinsuke Yamanaka
    • Organizer
      2014 MRS Fall Meeting and Exhibit
    • Place of Presentation
      Boston, Massachusetts
    • Year and Date
      2014-11-30 – 2014-12-05
    • Related Report
      2014 Annual Research Report
  • [Presentation] フッ化水素酸によって不純物を除去したp型ナノ結晶化Siの熱電特性2014

    • Author(s)
      伊藤 優介、大石 佑治、牟田 浩明、黒崎 健、山中 伸介
    • Organizer
      日本熱電学会
    • Place of Presentation
      独立行政法人物質・材料研究機構千現地区管理棟
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Annual Research Report
  • [Presentation] Effect of acid washing on thermoelectric properties of nanocrystalline silicon prepared by ball milling2013

    • Author(s)
      Yusuke Ito, Yuji Ohishi, Aikebaier Yusufu, Ken Kurosaki, Shinsuke Yamanaka
    • Organizer
      The 32nd International Conference on Thermoelectrics
    • Place of Presentation
      Kobe (Japan)
    • Related Report
      2013 Research-status Report
  • [Presentation] フッ化水素酸によって不純物を除去したナノ結晶化Siの熱電特性2013

    • Author(s)
      伊藤優介, 大石佑治, Aikebaier Yusufu, 牟田浩明, 黒崎健, 山中伸介
    • Organizer
      第十回日本熱電学会学術講演会
    • Place of Presentation
      名古屋大学大学院工学研究科
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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