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Two types of quasi-liquid layers on ice crystal surfaces observed by atomic force microscopy

Research Project

Project/Area Number 25870009
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Crystal engineering
Thin film/Surface and interfacial physical properties
Research InstitutionHokkaido University

Principal Investigator

Nagashima Ken  北海道大学, 低温科学研究所, 助教 (60436079)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2015: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Keywords氷 / 疑似液体層 / 結晶成長 / 原子間力顕微鏡 / 干渉計 / 擬似液体層
Outline of Final Research Achievements

I improved Atomic Force Microscope (AFM) for observation of ice crystal surfaces. I controlled ambient temperature and humidity by using commercial incubator and homemade observation cell by using Peltier elements with water-cooled system. Then I succeeded in scanning single ice crystals by using AFM.
However, we newly found that Quasi-Liquid Layers (QLLs) on ice crystal surfaces do not appear under equilibrium environment because QLLs are deposited from supersaturated water vapor. The most important point of AFM observation of ice crystals is suppression of vertically moving of ice surfaces. Therefore, it was difficult that QLLs were stably observed by AFM under saturated water vapor pressure. Instead of using AFM, we could estimate the thicknesses of two types of QLLs by interferometer and wetting theory. In addition, we found that QLLs are stable under equilibrium environment in the presence of hydrogen chloride gas and QLLs under such environment would be observed by AFM.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (20 results)

All 2016 2015 2014 2013

All Journal Article (8 results) (of which Peer Reviewed: 7 results,  Open Access: 1 results,  Acknowledgement Compliant: 2 results) Presentation (11 results) (of which Int'l Joint Research: 1 results) Book (1 results)

  • [Journal Article] Nanostructure for Hybrid Plasmonic-Photonic Crystal Formed on Gel-Immobilized Colloidal Crystal Observed by AFM after Drying2016

    • Author(s)
      Sho Kawakami, Atsushi Mori, Ken Nagashima, Shuichi Hashimoto, Masanobu Haraguchi
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 89 Issue: 3 Pages: 385-393

    • DOI

      10.1246/bcsj.20150281

    • NAID

      130005137566

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Two types of quasi-liquid layers on ice crystals are formed kineticcally2016

    • Author(s)
      Harutoshi. Asakawa, Gen. Sazaki, Ken. Nagashima, S. Nakatsubo, Y. Furukawa
    • Journal Title

      Proceedings of the National Academy of Sciences of the United States of America

      Volume: 113 Issue: 7 Pages: 1749-1753

    • DOI

      10.1073/pnas.1521607113

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Direct Visualization of Quasi-Liquid Layers on Ice Crystal Surfaces Induced by Hydrogen Chloride Gas2016

    • Author(s)
      K. Nagashima, G. Sazaki, T. Hama, H. Asakawa, K. Murata, Y. Furukawa
    • Journal Title

      Crystal Growth & Design,

      Volume: 16 Issue: 4 Pages: 2225-2230

    • DOI

      10.1021/acs.cgd.6b00044

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Prism and Other High-Index Faces of Ice Crystals Exhibit Two Types of Quasi-Liquid Layers2015

    • Author(s)
      Harutoshi Asakawa, Gen Sazaki, Ken Nagashima, Shunichi Nakatsubo, Yoshinori Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 15 Issue: 7 Pages: 3339-3344

    • DOI

      10.1021/acs.cgd.5b00438

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ Determination of Surface Tension-to-Shear Viscosity Ratio for Quasiliquid Layers on Ice Crystal Surfaces2015

    • Author(s)
      Ken-ichiro Murata, Harutoshi Asakawa, Ken Nagashima, Yoshinori Furukawa, Gen Sazaki
    • Journal Title

      Physical review letters

      Volume: 115 Issue: 25 Pages: 256103-256103

    • DOI

      10.1103/physrevlett.115.256103

    • NAID

      120005829704

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 氷ベーサル面上での形態が異なる2種類の擬似液体層の生成過程2014

    • Author(s)
      佐﨑元, 麻川明俊, 長嶋剣, 中坪俊一, 古川義純
    • Journal Title

      Int. J. Microgravity Sci. Appl.

      Volume: 31 Pages: 100-105

    • NAID

      130007842470

    • Related Report
      2014 Research-status Report
  • [Journal Article] Roles of surface/volume diffusion in the growth kinetics of elementary spiral steps on ice basal faces grown from water vapor2014

    • Author(s)
      H. Asakawa, G. Sazaki, E. Yokoyama, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 7 Pages: 3210-3220

    • DOI

      10.1021/cg4014653

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Double spiral steps on Ih ice crystal surfaces grown from water vapor just below the melting point2014

    • Author(s)
      G. Sazaki, H. Asakawa, K. Nagashima, S. Nakatsubo, Y. Furukawa
    • Journal Title

      Crystal Growth & Design

      Volume: 14 Issue: 5 Pages: 2133-2137

    • DOI

      10.1021/cg4014448

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 氷表面に生じる塩酸液滴挙動の水蒸気量依存性2016

    • Author(s)
      長嶋剣,佐﨑元,羽馬哲也,村田憲一郎,古川義純
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学(宮城県・仙台市)
    • Year and Date
      2016-03-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Liquid layers on ice surfaces induced by hydrochloric gas2015

    • Author(s)
      Ken Nagashima, Gen Sazaki, Hama Tetsuya, Harutoshi Asakawa, Kenichiro Murata, Shunichi Nakatsubo, Yoshinori Furukawa
    • Organizer
      ILTS International Symposium on Low Temperature Science
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-11-30
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 塩化水素ガスによって氷ベーサル面に生成する液体層2015

    • Author(s)
      長嶋剣, 佐﨑元, 羽馬哲也, 村田憲一郎, 中坪俊一, 古川義純
    • Organizer
      第45回結晶成長国内会議
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-10-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] 塩化水素ガスによって氷ベーサル面に生成する液体層2015

    • Author(s)
      長嶋剣, 佐﨑元, 羽馬哲也, 村田憲一郎, 中坪俊一, 古川義純
    • Organizer
      日本物理学会2015年秋季大会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2015-09-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 氷ベーサル面の成長に与える塩化水素ガスの効果2015

    • Author(s)
      長嶋剣, 佐﨑元, 羽馬哲也, 麻川明俊, 村田憲一郎, 中坪俊一, 古川義純
    • Organizer
      日本物理学会 第70回年次大会
    • Place of Presentation
      早稲田大学早稲田キャンパス, 東京都新宿区
    • Year and Date
      2015-03-21 – 2015-03-24
    • Related Report
      2014 Research-status Report
  • [Presentation] 氷ベーサル面の成長に与える塩化水素ガスの効果2014

    • Author(s)
      長嶋剣,佐﨑元,羽馬哲也,麻川明俊,村田憲一郎,中坪俊一,古川義純
    • Organizer
      第44回結晶成長国内会議
    • Place of Presentation
      学習院大学, 東京都豊島区
    • Year and Date
      2014-11-06 – 2014-11-08
    • Related Report
      2014 Research-status Report
  • [Presentation] 液中周波数変調方式原子間力顕微鏡による 可溶性結晶の原子分解能観察2014

    • Author(s)
      長嶋剣
    • Organizer
      日本物理学会 2014年秋季大会
    • Place of Presentation
      中部大学春日井キャンパス, 愛知県春日井市
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 液中非接触原子間力顕微鏡による結晶表面での吸着分子観察2014

    • Author(s)
      長嶋剣
    • Organizer
      日本地球惑星科学連合 連合大会 2014年大会
    • Place of Presentation
      パシフィコ横浜, 神奈川県横浜市
    • Year and Date
      2014-04-28 – 2014-05-02
    • Related Report
      2014 Research-status Report
  • [Presentation] Investigation of hydration structure on water-solid interface by non-contact atomic force microscopy2014

    • Author(s)
      Ken Nagashima, Gen Sazaki, Harutoshi Asakawa, Yoshinori Furukawa
    • Organizer
      13th International Conference on the Physics and Chemistry of Ice (PCI-2014)
    • Place of Presentation
      Dartmouth College, Hanover, NH, USA
    • Related Report
      2013 Research-status Report
  • [Presentation] 非接触原子間力顕微鏡による溶液結晶成長のナノ観察2013

    • Author(s)
      長嶋剣
    • Organizer
      日本地球惑星科学連合 連合大会 2013年大会
    • Place of Presentation
      幕張メッセ、千葉
    • Related Report
      2013 Research-status Report
  • [Presentation] Atomic or molecular resolution investigation of soluble crystals in liquid by frequency-modulation (non-contact) AFM2013

    • Author(s)
      Ken Nagashima, Gen Sazaki, Harutoshi Asakawa, Yoshinori Furukawa
    • Organizer
      17th International Conference on Crystal Growth and Epitaxy (ICCGE-17)
    • Place of Presentation
      The University of Warsaw, Warsaw, Poland
    • Related Report
      2013 Research-status Report
  • [Book] 北海道大学低温科学研究所編「低温科学便覧」2015

    • Author(s)
      佐崎元,古川義純,長嶋剣,村田憲一郎
    • Total Pages
      383
    • Publisher
      丸善出版(株)
    • Related Report
      2015 Annual Research Report

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Published: 2014-07-25   Modified: 2019-07-29  

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