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Preparation of rare earth metal free catalysts for automobile exhaust gas purification by solvothermal reactions

Research Project

Project/Area Number 25870054
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Energy-related chemistry
Inorganic materials/Physical properties
Research InstitutionTohoku University

Principal Investigator

DONG QIANG  東北大学, 多元物質科学研究所, 助教 (00643230)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Keywordsレアメタルフリー / 自動車排ガス浄化 / 助触媒 / 酸素吸蔵能 / 酸化スズ / アルカリ土類金属
Outline of Final Research Achievements

In 2013 year, according to solvothermal reactions, in order to confirm the the optimal chemical composition and morphology for OSC of promoter, the rich resources of SnO2 was selected, which valence can be changed from 2+ to 4+. Based on the first principles calculation, it was expected that by doping alkaline earth metal ions in SnO2, the oxygen desorption energy can be decreased, indicating the possibility of the improvement of OSC performance.
In 2014 year, by using solvothermal synthesis, alkaline earth metal doped tin oxide which showed higher specific surface area and higher OSC compared with commercially available SnO2 after calcination could be prepared, as expected. Above-mentioned results have been reported in the 8 international conferences, 9 domestic conferences and 4 papers of international journals.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (16 results) (of which Invited: 1 results) Remarks (2 results)

  • [Journal Article] Single-crystalline porous NiO nanosheets preparaed from β-Ni(OH)2 nanosheets: magnetic property and photocatalytic activity2014

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Xiaoyong Wu, Nobuhiro Kumada, Takahiro Takei, Akira Miura, Yoshinori Yonesaki, and Tsugio Sato
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 147 Pages: 741-747

    • DOI

      10.1016/j.apcatb.2013.10.007

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Aluminium doped ceria-zirconia supported palladium-alumina catalyst with high oxygen storage capacity and CO oxidation activity2013

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Xiaoyong Wu, Takeshi Kimura, Tsugio Sato
    • Journal Title

      Materials Research Bulletin

      Volume: 48 Issue: 12 Pages: 4989-4992

    • DOI

      10.1016/j.materresbull.2013.05.054

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Cobalt doped ceria-zirconia supported paradium-alumina catalyst with high oxygen storage capacity for CO oxidation2013

    • Author(s)
      Qiang Dong, Shu Yin, Chongshen Guo, Xiaoyong Wu, Takeshi Kimura, Thihang Le, Taro Sakanakura and Tsugio Sato
    • Journal Title

      IOP Conference Series: Materials Science and Engineering

      Volume: 47 Pages: 12065-12065

    • DOI

      10.1088/1757-899x/47/1/012065

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Tin Oxides as Novel Oxygen Storage Materials for Automotive Three-Way Catalytic Application2014

    • Author(s)
      Qiang Dong, Mizuki Yoshida, Shu Yin, Tsugio Sato
    • Organizer
      International Symposium on Functional Materials (ISFM 2014)
    • Place of Presentation
      Singapore, Singapore
    • Year and Date
      2014-08-04 – 2014-08-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Automobile Three-way Catalytic Application of Novel Oxygen Storage Materials: Calcium-Doped Ceria-Zirconia Solid Solutions2014

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      International Conferences on Modern Materials & Technologies (CIMTEC) 13th International Ceramics Congress
    • Place of Presentation
      Montecatini Terme, Italy
    • Year and Date
      2014-06-08 – 2014-06-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] タングステンベース均一ナノ粒子の温熱療法における応用2014

    • Author(s)
      殷 しゅう、果 崇伸、董 強、佐藤 次雄
    • Organizer
      第128回無機マテリアル学会 学術講演会
    • Place of Presentation
      東京
    • Year and Date
      2014-06-05 – 2014-06-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] ソルボサーマル反応による革新的自動車排ガス浄化触媒の開発2014

    • Author(s)
      董 強、殷 しゅう、佐藤 次雄
    • Organizer
      新化学技術推進協会第3回JACI/GSCシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2014-05-22 – 2014-05-23
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation of Multifunctional Ceria for Enviromental Cleanup and Human Health2014

    • Author(s)
      Qiang Dong, Shu Yin, Takehiro Goto, Tsugio Sato
    • Organizer
      The 15th International Symposium on Eco-materials Processing and Design (ISEPD2014)
    • Place of Presentation
      Hanoi, Vietnam
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 新規酸素貯蔵材料とその自動車三元触媒活性2014

    • Author(s)
      董 強、殷 シュウ、佐藤 次雄
    • Organizer
      第4期研究所連携プロジェクト平成25年度成果報告会
    • Place of Presentation
      仙台、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] ソルボサーマル反応による新規自動車排ガス浄化触媒の開発2014

    • Author(s)
      董 強、殷 しゅう、佐藤 次雄
    • Organizer
      東北大学 多元物質科学研究所 新機能無機物質探索研究センター第4回 シンポジウム
    • Place of Presentation
      仙台、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] セリア基金属酸化物の形態制御とその酸素貯蔵能2014

    • Author(s)
      董 強、殷 しゅう、佐藤 次雄
    • Organizer
      日本セラミックス協会2014年年会
    • Place of Presentation
      横浜、日本
    • Related Report
      2013 Research-status Report
  • [Presentation] カルシウムをドープしたセリア-ジルコニアの酸素貯蔵能と自動車排ガス浄化機能2013

    • Author(s)
      董 強、殷 しゅう、佐藤 次雄
    • Organizer
      第126回無機マテリアル学会学術講演会
    • Place of Presentation
      千葉県船橋市
    • Related Report
      2013 Research-status Report
  • [Presentation] Control of Chemical Composition and Morphology of Ceria for Enviromental Cleanup and Human Health2013

    • Author(s)
      Qiang Dong, Shu Yin, Takehiro Goto, Tsugio Sato
    • Organizer
      International Conference on Nanoscience & Technology, China 2013 (ChinaNANO 2013)
    • Place of Presentation
      Beijing, China
    • Related Report
      2013 Research-status Report
  • [Presentation] Novel Oxygen Storage Materials and Their Automotive Three-way Catalytic Application2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      International Symposium for the 70th Anniversary of the Tohoku Branch of the Chemical Society of Japan
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] スズドープしたセリアージルコニアの三元触媒の作製とその自動車排ガス浄化機能2013

    • Author(s)
      董 強、殷 しゅう、佐藤 次雄
    • Organizer
      平成25年度日本セラッミクス協会東北北海道支部研究発表会
    • Place of Presentation
      新潟県長岡
    • Related Report
      2013 Research-status Report
  • [Presentation] Alkaline Earth Metal Ions Doped M-SnO2 (M=Mg, Ca, Sr, Ba): Novel Oxygen Storage Materials and Automotive Three-way Catalytic Application2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      2nd International Symposium on Inorganic and Environmental Materials (ISIEM2013)
    • Place of Presentation
      Rennes, France
    • Related Report
      2013 Research-status Report
  • [Presentation] 高い酸素ストレージ能をもつCeO2-Mn3O4複合金属酸化物の合成とその触媒活性2013

    • Author(s)
      董 強、肴倉 太郎、殷 しゅう、佐藤 次雄
    • Organizer
      第127回無機マテリアル学会学術講演会
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Solvothermal Synthesis of Ceria Based Metal Oxides for Automotive Catalysts2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      Tenth International Conference on Flow Dynamics (ICFD2013)
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Novel Oxygen Storage Materials and Their Automotive Three-way Catalytic Application2013

    • Author(s)
      Qiang Dong, Shu Yin, Tsugio Sato
    • Organizer
      Sixth French Research Organizations- Tohoku University Joint Workshop on Frontier Materials, FRONTIER 2013
    • Place of Presentation
      Sendai, Japan
    • Related Report
      2013 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所新機能無機物質探索研究センター

    • URL

      http://www.tagen.tohoku.ac.jp/center/CENIM/

    • Related Report
      2013 Research-status Report
  • [Remarks] 東北大学多元物質科学研究所新機能無機物質探索研究センター環境無機材料化学研究分野佐藤次雄研究室

    • URL

      http://www.tagen.tohoku.ac.jp/modules/laboratory/index.php?laboid=45

    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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