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Peeling methods of high quality graphene from metal catalysts by low-cost

Research Project

Project/Area Number 25870064
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Composite materials/Surface and interface engineering
Nanomaterials chemistry
Research InstitutionTohoku University

Principal Investigator

OGAWA Shuichi  東北大学, 多元物質科学研究所, 助教 (00579203)

Research Collaborator YAMADA Takatoshi  
OJIRO Yoshihiro  
TANG Jiayi  
Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
KeywordsCVD / グラフェン / Cu / 光電子分光 / 酸化 / 化学気相成長法 / グラフェン剥離 / Cu酸化物 / 熱CVD / 熱酸化反応 / リアルタイム光電子分光
Outline of Final Research Achievements

(1) Confirmation of oxidation resistance of graphene and catalysts oxidation using H2O: Oxidation rate on graphene (Gr)/Cu substrates decreases compared with it on Cu surfaces. This is because graphene plays a role of barrier layer for oxygen and O2 cannot reach Gr/Cu interface. For fast oxidation of Gr/Cu substrates, H2O is proposed as oxidant in behalf of O2.
(2) Finding of the stopping power of Cu2O films for C atom diffusion: It was found that Cu2O films can intercept the C atom diffusion into Cu bulk substrate. Using this knowledge, high quality graphene can be grown on Cu2O/Cu substrates.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (9 results)

All 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results,  Acknowledgement Compliant: 1 results) Presentation (8 results) (of which Invited: 4 results)

  • [Journal Article] Graphene growth and carbon diffusion process into Cu(111)/Al2O3 substrates during the vacuum heating2013

    • Author(s)
      S. Ogawa, T. Yamada, S. Ishizuka, A. Yoshigoe, M. Hasegawa, Y. Teraoka and Y. Takakuwa
    • Journal Title

      Jpn. J. Appl. Phys.

      Volume: 52 Issue: 11R Pages: 110122-110122

    • DOI

      10.7567/jjap.52.110122

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] ナノカーボン材料開発における硬X線および軟X線光電子分光法の活用2014

    • Author(s)
      小川修一
    • Organizer
      日本真空学会 2014年12月研究例会
    • Place of Presentation
      仙台市
    • Year and Date
      2014-12-03
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 光電子制御プラズマCVDによるナノグラファイト合成と低抵抗化への挑戦2014

    • Author(s)
      小川修一
    • Organizer
      2014年電気化学秋季大会
    • Place of Presentation
      札幌市
    • Year and Date
      2014-09-27 – 2014-09-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 若手放射光ユーザーの視点:その場観察光電子分光の現状と希望2014

    • Author(s)
      小川修一
    • Organizer
      第75回応用物理学会秋季学術講演会
    • Place of Presentation
      札幌市
    • Year and Date
      2014-09-17 – 2014-09-20
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Growth mechanism of graphene on Cu(111) substrates studied by in-situ photoelectron spectroscopy2014

    • Author(s)
      S. Ogawa, T. Yamada, S. Ishidzuka, A. Yoshigoe, M. Hasegawa, Y. Teraoka, Y. Takakuwa
    • Organizer
      The International Conference on Diamond and Carbon Materials
    • Place of Presentation
      Madrid, Spain
    • Year and Date
      2014-09-07 – 2014-09-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 真空加熱実験に基づくグラフェン/Cu(111)エピタキシャル成長機構の考察2014

    • Author(s)
      小川修一,山田貴壽,石塚眞治,吉越章隆,長谷川雅孝,寺岡有殿,高桑雄二
    • Organizer
      2014年第61回応用物理学会春季学術講演会
    • Place of Presentation
      青山学院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 光電子分光によるCu(111)基板上グラフェン成長過程の解明2014

    • Author(s)
      小川修一
    • Organizer
      平成25年度文部科学省ナノテクノロジープラットフォーム事業微細構造解析プラットフォーム 第2回利用研究セミナー
    • Place of Presentation
      イーグレひめじ
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] Evaluation of thickness and oxidation state of Graphene/Cu(111)/Al2O3 substrates using photoelectron spectroscopy2013

    • Author(s)
      S. Ogawa, T. Yamada, S. Ishidzuka, A. Yoshigoe, M. Hasegawa, Y. Teraoka, Y. Takakuwa
    • Organizer
      6th International Symposium on Practical Surface Analysis
    • Place of Presentation
      沖縄コンベンションセンター
    • Related Report
      2013 Research-status Report
  • [Presentation] Angle-resolved X-ray Photoelectron Spectroscopy Study of Oxide Formation at Epitaxial Graphene/Cu(111) Interface Exposed to the Atmosphere2013

    • Author(s)
      S. Ogawa, T. Yamada, S. Ishidzuka, A. Yoshigoe, M. Hasegawa, Y. Teraoka, Y. Takakuwa
    • Organizer
      12th International Conference on Atomically Controlled Surfaces, Interfaces and Nanostructures
    • Place of Presentation
      つくば国際会議場
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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