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NOx reduction reaction using hydroxide ion conductor

Research Project

Project/Area Number 25870308
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Environmental engineering and reduction of environmental burden
Green/Environmental chemistry
Research InstitutionNagoya University

Principal Investigator

NAGAO Masahiro  名古屋大学, 環境学研究科, 講師 (40432223)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2015: ¥260,000 (Direct Cost: ¥200,000、Indirect Cost: ¥60,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywords窒素酸化物 / イオン導電体 / 電解 / 電極反応 / 還元反応 / 燃焼反応 / 水酸化物イオン / NOx還元 / 電極触媒
Outline of Final Research Achievements

With the growing interest in recent environmental problems, monitoring and purification technology of nitrogen oxides released into the atmosphere from diesel engines has been attracting attention. In this study, we focus on electrolysis phenomena that leads to detoxification of the nitrogen oxides. Ionic conducting ceramics were applied for the electrochemical reduction of nitrogen oxides. As a result, nitrogen oxides were reduced to harmless nitrogen by active species generated by electrolysis of water. Because the electrochemical reaction occur in the both electrodes, alternate current will become applicable instead of direct current. Simultaneous reduction of nitrogen oxides at both electrodes suggests the simplification and downsizing of the devices for sensing and purification of nitrogen oxides.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (4 results)

All 2015 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (3 results) (of which Int'l Joint Research: 1 results,  Invited: 1 results)

  • [Journal Article] An all-solid-state rechargeable aluminum-air battery with a hydroxide ion-conducting Sb(V)-doped SnP2O7 electrolyte2013

    • Author(s)
      Takashi Hibino, Kazuyo Kobayashi, Masahiro Nagao
    • Journal Title

      JOURNAL OF MATERIALS CHEMISTRY A

      Volume: 1 Issue: 47 Pages: 14844-14848

    • DOI

      10.1039/c3ta12707a

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Energy and Environmental Devices using Doped Tin Phosphates as a Solid State Electrolyte2015

    • Author(s)
      長尾征洋
    • Organizer
      International Conference on Small Science (ICSS 2015)
    • Place of Presentation
      Holiday Inn Resort Phuket, Phuket, Thailand
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Proton-conducting tin phosphates for electrochemical applications operating at intermediate temperatures2014

    • Author(s)
      Masahiro Nagao
    • Organizer
      3rd International Conference and Exhibition on Materials Science & Engineering
    • Place of Presentation
      Hilton San Antonio Airport
    • Year and Date
      2014-10-06 – 2014-10-08
    • Related Report
      2014 Research-status Report
  • [Presentation] 水酸化物イオン導電体 Sn0.92Sb0.08P2O7を電解質に使用したアルミニウム・空気二次電 池の開発2013

    • Author(s)
      日比野高士, 小林和代, 長尾征洋
    • Organizer
      第54回電池討論会
    • Place of Presentation
      大阪国際会議場
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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