Creation of PCP/metal nanoparticles for high density and rapid hydrogen storage material
Project/Area Number |
25870350
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Research Category |
Grant-in-Aid for Young Scientists (B)
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Allocation Type | Multi-year Fund |
Research Field |
Inorganic chemistry
Organic and hybrid materials
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Research Institution | Kyoto University |
Principal Investigator |
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Project Period (FY) |
2013-04-01 – 2015-03-31
|
Project Status |
Completed (Fiscal Year 2014)
|
Budget Amount *help |
¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2014: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
Fiscal Year 2013: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | 金属ナノ粒子 / 多孔性金属錯体 / 水素吸蔵 |
Outline of Final Research Achievements |
Remarkably enhanced capacity and speed of hydrogen storage in Pd nanocrystals were discovered by coating with the metal–organic framework (MOF) HKUST-1 (copper(II) 1,3,5-benzenetricarboxylate). The Pd nanocrystals covered with the MOF have twice the storage capacity of the bare Pd nanocrystals. The significantly enhanced hydrogen storage capacity was confirmed by hydrogen pressure composition isotherms. The speed of hydrogen absorption in the Pd nanocrystals is also enhanced by the MOF coating.
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Report
(3 results)
Research Products
(19 results)
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[Journal Article] Hydrogen storage in Pd nanocrystals covered with a metal–organic framework2014
Author(s)
Guangqin Li, Hirokazu Kobayashi, Jared M. Taylor, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Shoichi Toh, Syo Matsumura, Hiroshi Kitagawa
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Journal Title
Nature Mater.
Volume: 13
Issue: 8
Pages: 802-806
DOI
Related Report
Peer Reviewed
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[Journal Article] Shape-Dependent Hydrogen-Storage Properties in Pd Nanocrystals: Which Does Hydrogen Prefer, Octahedron (111) or Cube (100)?2014
Author(s)
Guangqin Li, Hirokazu Kobayashi, Shun Dekura, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Syo Matsumura, Hiroshi Kitagawa
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Journal Title
J. Am. Chem. Soc.
Volume: 136
Issue: 29
Pages: 10222-10225
DOI
Related Report
Peer Reviewed
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[Journal Article] Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability2014
Author(s)
Kohei Kusada, Hirokazu Kobayashi, Ryuichi Ikeda, Yoshiki Kubota, Masaki Takata, Shoichi Toh, Tomokazu Yamamoto, Syo Matsumura, Naoya Sumi, Katsutoshi Sato, Katsutoshi Nagaoka, Hiroshi Kitagawa
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Journal Title
J. Am. Chem. Soc.
Volume: 136
Issue: 5
Pages: 1864-1871
DOI
Related Report
Peer Reviewed
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[Journal Article] Unusual Magnetic Ordering Observed in Nanosized S = 1/2 Quantum Spin System (CH3) 2NH2CuCl 32014
Author(s)
Yuji Inagaki, Yasutaka Sakamoto, Hiroki Morodomi, Tatsuya Kawae, Yasuo Yoshida, Takayuki Asano, Kohei Hosoi, Hirokazu Kobayashi, Hiroshi Kitagawa, Yoshitami Ajiro, and Yuji Furukawa
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Journal Title
J. Phys. Soc. Jpn
Volume: 83
Issue: 5
Pages: 54716-54716
DOI
NAID
Related Report
Peer Reviewed
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