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Structural study of superionic conductors for development of novel solid electrolyes

Research Project

Project/Area Number 25870371
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Structural/Functional materials
Inorganic industrial materials
Research InstitutionKyoto University

Principal Investigator

ONODERA Yohei  京都大学, 原子炉実験所, 助教 (20531031)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2013: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Keywordsエネルギー材料 / 電池材料 / イオン伝導体 / 中性子散乱 / X線回折 / 逆モンテカルロ法 / 中性子回折
Outline of Final Research Achievements

Dramatic progresses in the performance of rechargeable batteries are necessary to fulfill various demands for the commodification of electric vehicles. All-solid-state sodium batteries with excellent safety have attracted much attention as one of candidates of post-lithium ion batteries because of great abundance and low cost of sodium. Thus, in this work, we studied three-dimensional structures for (Na2S)x(P2S5)100-x glasses (x=50, 60, 66.7, 70) and Na3PS4 metastable crystal by taking advantage of the reverse Monte Carlo modeling based on the neutron and X-ray diffraction data in order to understand relations between the structure and ionic conductivity.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (11 results)

All 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (10 results)

  • [Journal Article] Structural origin of ionic conductivity for Li7P3S11 metastable crystal by neutron and X-ray diffrcation2014

    • Author(s)
      Y. Onodera, K. Mori, T. Otomo, H. Arai, Y. Uchimoto, Z. Ogumi, T. Fukunaga
    • Journal Title

      J. Phys.: Conference Series

      Volume: 502 Pages: 012021-012021

    • DOI

      10.1088/1742-6596/502/1/012021

    • Related Report
      2014 Annual Research Report 2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 中性子/X線によるNa-P-S系超イオン伝導ガラスの構造研究2014

    • Author(s)
      小野寺陽平、中島広志、森一広、福永俊晴、大友季哉
    • Organizer
      日本中性子科学会第14回年会
    • Place of Presentation
      かでる2・7、札幌市
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 中性子回折によるLi-Ge-P-S系ガラス/結晶のイオン伝導空間解析2014

    • Author(s)
      笠井拓矢、小野寺陽平、森一広、福永俊晴
    • Organizer
      日本中性子科学会第14回年会
    • Place of Presentation
      かでる2・7、札幌市
    • Year and Date
      2014-12-11 – 2014-12-12
    • Related Report
      2014 Annual Research Report
  • [Presentation] 中性子/X線回折によるNa-P-S系の構造とイオン伝導特性2014

    • Author(s)
      小野寺陽平、中島広志、森一広、大友季哉、福永俊晴
    • Organizer
      第40年固体イオニクス討論会
    • Place of Presentation
      東京工業大学、東京都
    • Year and Date
      2014-11-16 – 2014-11-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] メカニカルアロイング法で作製したLi-Ge-P-S系超イオン伝導体の構造研究2014

    • Author(s)
      笠井拓矢、小野寺陽平、森一広、福永俊晴
    • Organizer
      日本金属学会2014年秋期講演大会
    • Place of Presentation
      名古屋大学、名古屋市
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Na-P-S系超イオン伝導体におけるイオン伝導空間の解析2014

    • Author(s)
      小野寺陽平、中島広志、森一広、大友季哉、福永俊晴
    • Organizer
      日本金属学会2014年秋期講演大会
    • Place of Presentation
      名古屋大学、名古屋市
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] 小野寺陽平、森一広、大友季哉、Alex C. Hannon、福永俊晴2014

    • Author(s)
      メカニカルアロイング法によって作製したアモルファスP2S5の構造
    • Organizer
      日本金属学会 2014年春期講演大会
    • Place of Presentation
      東京工業大学大岡山キャンパス、東京都
    • Related Report
      2013 Research-status Report
  • [Presentation] Structural origin of lithium diffusion for Li7P3S11 metastable crystal2013

    • Author(s)
      Y. Onodera, K. Mori, T. Otomo, T. Fukunaga
    • Organizer
      International Conference on Neutron Scattering (ICNS2013)
    • Place of Presentation
      Edinburgh, UK
    • Related Report
      2013 Research-status Report
  • [Presentation] Local structure and ionic conductivity for Li7P3S11 metastable crystal by neutron and X-ray diffraction2013

    • Author(s)
      Y. Onodera, K. Mori, T. Otomo, H. Arai, Y. Uchimoto, Z. Ogumi, T. Fukunaga
    • Organizer
      Light and Particle Beams in Materials Science 2013 (LPBMS 2013)
    • Place of Presentation
      つくば国際会議場,つくば市
    • Related Report
      2013 Research-status Report
  • [Presentation] 中性子/X線回折および逆モンテカルロモデリングによるLi-P-S系超イオン伝導体の構造研究2013

    • Author(s)
      小野寺陽平、森一広、大友季哉、福永俊晴
    • Organizer
      日本セラミックス協会第26回秋季シンポジウム
    • Place of Presentation
      信州大学長野キャンパス,長野市
    • Related Report
      2013 Research-status Report
  • [Presentation] 中性子/次世代二次電池開発に向けたNa-P-S系固体電解質の構造解析2013

    • Author(s)
      中島広志、小野寺陽平、森一広、福永俊晴
    • Organizer
      日本金属学会 2013年秋期講演大会
    • Place of Presentation
      金沢大学角間キャンパス,金沢市
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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