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Layer-by-Layer Assembly of Cyclodextrin Polymers as Highly Effective Adsorbents for Removal of Polychlorobiphenyls

Research Project

Project/Area Number 25870402
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Nanomaterials chemistry
Green/Environmental chemistry
Research InstitutionOsaka Municipal Technical Research Institute

Principal Investigator

Kawano Shintaro  地方独立行政法人大阪市立工業研究所, 生物・生活材料研究部, 研究員 (50646198)

Co-Investigator(Renkei-kenkyūsha) AKASHI Mitsuru  大阪大学, 大学院生命機能研究科, 特任教授 (20145460)
KIDA Toshiyuki  大阪大学, 大学院工学研究科, 准教授 (20234297)
NAKANO Takeshi  大阪大学, 環境安全研究管理センター, 招へい教授 (00446791)
Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Keywordsシクロデキストリン / 吸着剤 / ポリ塩化ビフェニル / 分子認識 / ハロゲン化芳香族化合物 / 交互積層法 / カラム担持粒子 / シクロデキストリンポリマー / オイル / 交互反応膜
Outline of Final Research Achievements

Polychlorobiphenyls (PCBs) have prohibited both their manufacturing and commercial use due to their string toxicity. However the large amounts of oils contaminated with PCBs (several ten mass ppm) are still stored without the appropriate treatment. Under these backgrounds, we focused on novel and highly effective cyclodextrin-based adsorbents. Urethane-crosslinked cyclodextrin polymers were modified to the surface of silica gels via layer-by-layer assembly of cyclodextrin and diisocyanate linkers. The cyclodextrin polymer modified silica gel particles have high adsorption capabilities(with >95% removal efficiency) toward PCBs, such as tetra, penta and hexachlorobiphenyl in oil through the column method.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (18 results)

All 2015 2014 2013

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 2 results,  Open Access: 2 results) Presentation (13 results)

  • [Journal Article] “Adsorption Capability of Urethane-crosslinked Heptakis(2,6-di-O-methyl)-β-cyclodextrin Polymers towards Polychlorobiphenyls in Nonpolar Organic Media”2015

    • Author(s)
      S. Kawano, T. Kida, K. Miyawaki, Y. Fukuda, E. Kato, T. Nakano, M. Akashi,
    • Journal Title

      Polymer J.

      Volume: in press Issue: 6 Pages: 443-448

    • DOI

      10.1038/pj.2015.13

    • NAID

      40020479722

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] 熱可逆性を有する両親媒性シクロデキストリン架橋ポリマーの増粘特性2015

    • Author(s)
      川野 真太郎
    • Journal Title

      C&I Commun.

      Volume: 40 Pages: 19-21

    • NAID

      40020983009

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Preparation of Pickering Emulsions through Interfacial Adsorption by Soft Cyclodextrin Nanogels2015

    • Author(s)
      Shintaro Kawano, Toshiyuki Kida, Mitsuru Akashi, Hirofumi Sato, Motohiro Shizuma, Daisuke Ono
    • Journal Title

      Beilstein Journal of Organic Chemistry

      Volume: 11 Pages: 2355-2364

    • DOI

      10.3762/bjoc.11.257

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Cyclodextrin Polymers as Highly Effective Adsorbents for Removal and Recovery of Polychlorobiphenyls (PCBs) Contaminants in Insulating Oil2014

    • Author(s)
      Shintaro Kawano, Toshiyuki Kida, Kazuhiro Miyawaki, Yuki Noguchi, Eiichi Kato, Takeshi Nakano, Mitsuru Akashi
    • Journal Title

      Environmental Science & Technology

      Volume: 48 Issue: 14 Pages: 8094-8100

    • DOI

      10.1021/es501243v

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Open Access
  • [Journal Article] Continuous Porous Poly-N-Isopropylacrylamide Gels Prepared from a Bicontinuous Microemulsion2014

    • Author(s)
      K. Sakata, S. Taguchi, S. Uemura, M. Kunitake, S. Kawano, T. Nishimi,
    • Journal Title

      Chem. Lett.,

      Volume: 432 Issue: 2 Pages: 240-242

    • DOI

      10.1246/cl.130941

    • NAID

      130004867981

    • Related Report
      2013 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] エマルションをテンプレートとしたシクロデキストリンナノゲル集積化マイクロカプセルの作製2015

    • Author(s)
      ○川野真太郎,佐藤博文,靜間基博, 小野大助
    • Organizer
      第66回コロイドおよび界面化学討論会
    • Place of Presentation
      鹿児島大学郡元キャンパス(鹿児島県鹿児島市)
    • Year and Date
      2015-09-12
    • Related Report
      2015 Annual Research Report
  • [Presentation] 熱可逆性を有するシクロデキストリンポリマーの溶液物性と機能応用2015

    • Author(s)
      ○川野真太郎,小野大助, 佐藤博文,靜間基博
    • Organizer
      日本油化学会第54回年会
    • Place of Presentation
      名城大学天白キャンパス(愛知県名古屋市)
    • Year and Date
      2015-09-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] 両親媒性環状オリゴ糖ポリマーの溶液物性と機能2015

    • Author(s)
      ○川野真太郎,佐藤博文,靜間基博,中野博文,小野大助
    • Organizer
      第16回 関西グライコサイエンスフォーラム
    • Place of Presentation
      大阪大学 大学会館(大阪府豊中市)
    • Year and Date
      2015-05-16
    • Related Report
      2015 Annual Research Report
  • [Presentation] 両親媒性環状オリゴ糖ポリマーの溶液物性と機能2015

    • Author(s)
      川野真太郎,佐藤博文,靜間基博,中野博文,小野大助
    • Organizer
      第16回 関西グライコサイエンスフォーラム
    • Place of Presentation
      大阪大学(大阪府豊中市)
    • Year and Date
      2015-05-16
    • Related Report
      2014 Research-status Report
  • [Presentation] 感熱応答性を有するシクロデキストリンナノゲル溶液の増粘制御2015

    • Author(s)
      川野真太郎、小野大助、 佐藤博文、靜間基博、木田敏之、明石満
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日本大学(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] 両親媒性シクロデキストリン架橋ナノゲルの界面集積化とPickering emulsionへの利用2014

    • Author(s)
      川野真太郎、佐藤博文、靜間基博、小野大助、 木田敏之、明石満
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学(長崎県長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 両親媒性シクロデキストリン架橋ナノ粒子の界面物性と乳化機能2014

    • Author(s)
      川野真太郎、小野大助、 佐藤博文、靜間基博、木田敏之、明石満
    • Organizer
      日本油化学会第53回年会
    • Place of Presentation
      ホテルロイトン札幌(北海道札幌市)
    • Year and Date
      2014-09-10
    • Related Report
      2014 Research-status Report
  • [Presentation] 両親媒性シクロデキストリン架橋ナノゲルの作製とPickering emulsionへの応用2014

    • Author(s)
      川野真太郎、佐藤博文、靜間基博、小野大助、 木田敏之、明石満
    • Organizer
      第65回コロイドおよび界面化学討論会
    • Place of Presentation
      東京理科大学(東京都新宿区)
    • Year and Date
      2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] Formation and Characterization of Emulsions via Adsorption of Crosslinked Cyclodextrin Nanoparticles at Oil-Water Interface2014

    • Author(s)
      Shintaro Kawano, Hirofumi Sato, Motohiro Shizuma, Daisuke Ono
    • Organizer
      20th International Symposium on Surfactants in Solution
    • Place of Presentation
      University of Coimbra, Portugal
    • Year and Date
      2014-06-26
    • Related Report
      2014 Research-status Report
  • [Presentation] 両親媒性環状オリゴ糖架橋ナノ粒子の評価と乳化剤への応用2014

    • Author(s)
      川野真太郎・佐藤博文・靜間基博・小野大助・木田敏之・明石満
    • Organizer
      日本化学会第94春季年会(2014)
    • Place of Presentation
      名古屋大学東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Removal of Polychlorobiphenyls from Oils by Crosslinked Cyclodextrin Polymers2013

    • Author(s)
      Shintaro Kawano, Toshiyuki Kida, Kazuhiro Miyawaki, Yuki Noguchi, Eiichi Kato, Takeshi Nakano, Hirofumi Sato, Motohiro Shizuma, Daisuke Ono, and Mitsuru Akashi
    • Organizer
      8th. International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC) 2013
    • Place of Presentation
      Crystal Gateway Marriott, Arlington, Virginia 22202 USA
    • Related Report
      2013 Research-status Report
  • [Presentation] 両親媒性シクロデキストリンポリマーの水および油に対するゲル化能と生成ゲルの物性評価2013

    • Author(s)
      川野真太郎・木田敏之・明石満・佐藤博文・靜間基博・小野大助
    • Organizer
      日本油化学会第52回年会
    • Place of Presentation
      東北大学川内北キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] シクロデキストリンポリマーからなる自己組織化粒子の構造制御と水および油中における芳香族ゲスト分子の包接能評価2013

    • Author(s)
      川野真太郎・木田敏之・明石満・佐藤博文・靜間基博・小野大助
    • Organizer
      第64回コロイドおよび界面化学討論会
    • Place of Presentation
      名古屋工業大学
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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