Layer-by-Layer Assembly of Cyclodextrin Polymers as Highly Effective Adsorbents for Removal of Polychlorobiphenyls
| Project/Area Number |
25870402
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Nanomaterials chemistry
Green/Environmental chemistry
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| Research Institution | Osaka Municipal Technical Research Institute |
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Principal Investigator |
Kawano Shintaro 地方独立行政法人大阪市立工業研究所, 生物・生活材料研究部, 研究員 (50646198)
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| Co-Investigator(Renkei-kenkyūsha) |
AKASHI Mitsuru 大阪大学, 大学院生命機能研究科, 特任教授 (20145460)
KIDA Toshiyuki 大阪大学, 大学院工学研究科, 准教授 (20234297)
NAKANO Takeshi 大阪大学, 環境安全研究管理センター, 招へい教授 (00446791)
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| Project Period (FY) |
2013-04-01 – 2016-03-31
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| Project Status |
Completed (Fiscal Year 2015)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Fiscal Year 2013: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
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| Keywords | シクロデキストリン / 吸着剤 / ポリ塩化ビフェニル / 分子認識 / ハロゲン化芳香族化合物 / 交互積層法 / カラム担持粒子 / シクロデキストリンポリマー / オイル / 交互反応膜 |
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| Outline of Final Research Achievements |
Polychlorobiphenyls (PCBs) have prohibited both their manufacturing and commercial use due to their string toxicity. However the large amounts of oils contaminated with PCBs (several ten mass ppm) are still stored without the appropriate treatment. Under these backgrounds, we focused on novel and highly effective cyclodextrin-based adsorbents. Urethane-crosslinked cyclodextrin polymers were modified to the surface of silica gels via layer-by-layer assembly of cyclodextrin and diisocyanate linkers. The cyclodextrin polymer modified silica gel particles have high adsorption capabilities(with >95% removal efficiency) toward PCBs, such as tetra, penta and hexachlorobiphenyl in oil through the column method.
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Report
(4 results)
Research Products
(18 results)
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[Presentation] Removal of Polychlorobiphenyls from Oils by Crosslinked Cyclodextrin Polymers2013
Author(s)
Shintaro Kawano, Toshiyuki Kida, Kazuhiro Miyawaki, Yuki Noguchi, Eiichi Kato, Takeshi Nakano, Hirofumi Sato, Motohiro Shizuma, Daisuke Ono, and Mitsuru Akashi
Organizer
8th. International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC) 2013
Place of Presentation
Crystal Gateway Marriott, Arlington, Virginia 22202 USA
Related Report
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