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Preparation of high-performance catalysts by oxidation state control of Pd on GO

Research Project

Project/Area Number 25870457
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Catalyst/Resource chemical process
Synthetic chemistry
Research InstitutionOkayama University

Principal Investigator

NISHINA Yuta  岡山大学, 異分野融合先端研究コア, 准教授 (50585940)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Fiscal Year 2013: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywordsグラフェン / パラジウム / ナノ粒子 / 触媒 / カップリング / 酸化グラフェン / クロスカップリング
Outline of Final Research Achievements

Graphene oxide (GO) is a two-dimensional sheet of sp2-hybridized carbon. Due to its extraordinary thermal, mechanical, and electrical properties, GO has attracted much interest. Pd/GO, a composite of Pd nanoparticle and exfoliated graphene, was used as a catalyst in organic reactions. In Suzuki-Miyaura cross coupling reaction, Pd/GO showed high reusability without aggregation of Pd nanoparticle.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (28 results)

All 2014 2013 Other

All Journal Article (9 results) (of which Peer Reviewed: 9 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) (of which Invited: 2 results) Book (4 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Facile preparation of Pd nanoparticles supported on single-layer graphene oxide and application for Suzuki–Miyaura cross-coupling reaction2014

    • Author(s)
      Shun-ichi Yamamoto, Hiroshi Kinoshita Hideki Hashimoto, and Yuta Nishina
    • Journal Title

      Nanoscale

      Volume: 6 Pages: 6501-6505

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fine tuning of the sheet distance of graphene oxide that affects the activity and substrate selectivity of a Pd/graphene oxide catalyst in the Heck reaction2014

    • Author(s)
      Akinori Saito, Shun-ichi Yamamoto, Yuta Nishina
    • Journal Title

      RSC Adv.

      Volume: 4 Pages: 59835-59838

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Nanocrystalline magnesium oxide-stabilized palladium(0): the Heck reaction of heteroaryl bromides in the absence of additional ligands and base2013

    • Author(s)
      Mannepalli Lakshmi Kantam, Police Vishnuvardhan Redddy, Pottabathula Srinivas, Akula Venugopal, Suresh Bhargava and Yuta Nishina
    • Journal Title

      Catalysis Science & Technology

      Volume: 3巻 Issue: 10 Pages: 2550-2554

    • DOI

      10.1039/c3cy00404j

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation2013

    • Author(s)
      Yuta Nishina, Bunsho Ohtani, Kotaro Kikushima
    • Journal Title

      Beilstein Journal of Organic Chemistry (Organic Free Radical Chemistry as a Thematic Series)

      Volume: 9巻 Pages: 1663-1667

    • DOI

      10.3762/bjoc.9.190

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Copper-Catalyzed Oxidative Aromatization Reaction of 2-Cyclohexen-1-ones to Phenols in the Presence of Catalytic Hydrogen Bromide under Molecular Oxygen2013

    • Author(s)
      Kotaro Kikushima, Yuta Nishina
    • Journal Title

      RSC Advances

      Volume: 3巻 Issue: 43 Pages: 20150-20156

    • DOI

      10.1039/c3ra43071e

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Palladium on graphene: the in situ generation of a catalyst for the chemoselective reduction of α,ß-unsaturated carbonyl compounds2013

    • Author(s)
      Naoki Morimoto, Shun-ichi Yamamoto, Yasuo Takeuchi, Yuta Nishina
    • Journal Title

      RSC Advances

      Volume: 3巻 Issue: 36 Pages: 15608-15612

    • DOI

      10.1039/c3ra42150c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Green Synthesis of Silver Nanoparticles Using Aqueous Rinds Extract of Brucea javanica (L) Merr at Ambient Temperature2013

    • Author(s)
      Salprima S. Yudha, Doni Notriawan, Eka Angasa, Totok Eka Suharto, John Hendri, Yuta Nishina
    • Journal Title

      Materials Letters

      Volume: 97巻 Pages: 181-183

    • DOI

      10.1016/j.matlet.2013.01.114

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Direct bromination of hydrocarbons catalyzed by Li2MnO3 under oxygen and photo-irradiation conditions2013

    • Author(s)
      Yuta Nishina, Junya Morita, Bunsho Ohtani
    • Journal Title

      RSC Advances

      Volume: 3巻 Issue: 7 Pages: 2158-2162

    • DOI

      10.1039/c2ra22197g

    • NAID

      120005351800

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Ionic amino acids: Application as organocatalysts in the aza-Michael reaction2013

    • Author(s)
      Naoki Morimoto,Yasuo Takeuchi, Yuta Nishina
    • Journal Title

      Journal of Molecular Catalysis A: Chemical

      Volume: 368-369巻 Pages: 31-37

    • DOI

      10.1016/j.molcata.2012.11.012

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 銅またはパラジウムを触媒とした芳香族化反応によるフェノール誘導体合成法の開発

    • Author(s)
      菊嶌 孝太郎・仁科 勇太
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] 銅触媒を用いたベンゾフラン骨格構築反応

    • Author(s)
      管生 伸矢・仁科 勇太
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] ヒドロシランを還元剤とする金属-酸化グラフェン複合体の新規調製法の開発と触媒反応への応用

    • Author(s)
      齋藤 彰範・仁科 勇太
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] バナジウム塩による芳香族化合物の酸化的脱水素C-C結合形成反応

    • Author(s)
      森奥 久実加・仁科 勇太
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] バナジウム触媒によるヒドラゾ化合物の酸素酸化反応

    • Author(s)
      中西 真奈美・菊嶌 孝太郎・仁科 勇太
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] フルオロアルキル基を有するフタリドの効率的合成

    • Author(s)
      稲葉 公則・品田 瞬・仁科 勇太・網井 秀樹
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学 東山キャンパス
    • Related Report
      2013 Research-status Report
  • [Presentation] Facile Preparation of Graphene Composite Materials and Their Application

    • Author(s)
      Y. Nishina
    • Organizer
      Nanotech 2013
    • Place of Presentation
      Gaylord National Hotel & Convention Center (Washington D.C)
    • Related Report
      2013 Research-status Report
  • [Presentation] Metal-Graphene Oxide Composites for High Performance Catalysts in Organic Synthesis

    • Author(s)
      Y. Nishina
    • Organizer
      BIT's 4th Annual Global Congress of Catalysis 2013
    • Place of Presentation
      Dalian World EXPO center(China)
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 酸化グラフェン-高分子・有機・無機化学を網羅する新奇材料-

    • Author(s)
      仁科 勇太
    • Organizer
      平成25年度中国四国地区高分子懇話会
    • Place of Presentation
      岡山大学津島キャンパス
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 高分散パラジウム-還元型酸化グラフェンを用いた酸化的環化反応の開発

    • Author(s)
      山本 俊一・仁科 勇太
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Related Report
      2013 Research-status Report
  • [Presentation] 臭化水素酸および分子状酸素存在下での銅触媒による2-シクロヘキセン -1-オン誘導体の芳香族化反応

    • Author(s)
      菊嶌 孝太郎・仁科 勇太
    • Organizer
      第60回有機金属化学討論会
    • Place of Presentation
      学習院大学(東京都豊島区)
    • Related Report
      2013 Research-status Report
  • [Presentation] Pd-Graphene Oxide Composite Catalyst for Coupling, Hydrogenation and C-H Activation Reactions

    • Author(s)
      Yuta Nishina
    • Organizer
      International Symposium on Catalysis and Fine Chemicals 2013
    • Place of Presentation
      Renmin unibersity of China
    • Related Report
      2013 Research-status Report
  • [Presentation] 金属-酸化グラフェン複合体の調製と触媒への応用

    • Author(s)
      仁科 勇太
    • Organizer
      第113回触媒討論会
    • Place of Presentation
      ロワジールホテル豊橋
    • Related Report
      2013 Research-status Report
  • [Book] グラフェン・コンポジット2014

    • Author(s)
      仁科勇太
    • Total Pages
      32
    • Publisher
      S&T出版
    • Related Report
      2014 Annual Research Report
  • [Book] Handbook of Graphene Science2014

    • Author(s)
      Yuta Nishina, Naoki Morimoto
    • Total Pages
      20
    • Publisher
      Taylor & Francis
    • Related Report
      2013 Research-status Report
  • [Book] グラフェン・コンポジット2014

    • Author(s)
      仁科勇太,齋藤彰範,森本直樹
    • Total Pages
      20
    • Publisher
      S&T出版
    • Related Report
      2013 Research-status Report
  • [Book] 触媒の設計・反応制御 事例集2013

    • Author(s)
      仁科勇太,菊島孝太郎
    • Total Pages
      9
    • Publisher
      技術情報教会
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 水系潤滑剤2013

    • Inventor(s)
      仁科勇太,木之下博
    • Industrial Property Rights Holder
      岡山大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-106493
    • Filing Date
      2013-05-20
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 酸化グラフェンに金属を担持させる方法及びこの方法で作成した金属-酸化グラフェン複合体2013

    • Inventor(s)
      仁科勇太
    • Industrial Property Rights Holder
      仁科勇太
    • Industrial Property Rights Type
      特許
    • Filing Date
      2013-09-13
    • Related Report
      2013 Research-status Report
    • Overseas

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Published: 2014-07-25   Modified: 2019-07-29  

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