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Development of the lattice-defect-type proton conductors for SOEC

Research Project

Project/Area Number 25870840
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Inorganic materials/Physical properties
Research InstitutionKanagawa University

Principal Investigator

SAITO Miwa  神奈川大学, 工学部, 助教 (60594215)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2014: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywordsペロブスカイト型 / プロトン伝導 / 酸素欠陥 / perovskite oxide / oxygen defect / proton / ペロブスカイト / プロトン / 液相合成 / 誘電緩和
Outline of Final Research Achievements

Several brownmillerite- and perovskite-type proton conductors, which show unique proton and electrical conductivities, have been successfully synthesized by a solid-state reaction chemistry route.
The conventional lattice-defect-type perovskite compounds show the proton conductivities by supplying hydrogen gas and steam for the hydrogen sources. However, these samples showed the high proton conductivities in intermediate-temperatures without the hydrogen sources.It revealed that the three kinds of water absorption in a perovskite-phase cause for the high proton conductivities in intermediate-temperature by analysis of the chemical composition.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (11 results)

All 2015 2014 2013

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (8 results) (of which Int'l Joint Research: 1 results)

  • [Journal Article] Thermoelectric and Magnetic Properties of Pr1¹xSrxMnO3 (0.1 ³ x ³ 0.7)2015

    • Author(s)
      Hiroshi Nakatsugawa, Masaki Kubota and Miwa Saito
    • Journal Title

      Materials Transactions

      Volume: 56(6)

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Journal Article] トレランスファクターを制御したCa-Mn-O系の熱電特性2014

    • Author(s)
      川上博司、齋藤美和、山村博、磯田幸宏、篠原嘉一
    • Journal Title

      傾斜機能材料論文集

      Volume: 未定

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Reduction of thermal conductivity in dually doped ZnO by design of three-dimensional stacking faults2014

    • Author(s)
      Takemoto H, Fugane K, Yan P F, Drennan J, Saito M, Mori T, and Yamamura H,
    • Journal Title

      RSC advances

      Volume: 4 Issue: 6 Pages: 2661-2672

    • DOI

      10.1039/c3ra44223c

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Synthesis and properties of intermediate-temperature-type proton conductors with perovskite-related structures2015

    • Author(s)
      Miwa Saito, Teruki Motohashi and Hiroshi Yamamura
    • Organizer
      The International Chemical Congress of Pacific Basin Societies 2015
    • Place of Presentation
      Hawaii convention center etc.
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 水の吸蔵によるBa2(Zn, M ) 2O6-δ( M = Nb, Ta, W) におけるイオン伝導性の大幅な向上2015

    • Author(s)
      齋藤 美和、植草 奈実、本橋 輝樹、山村 博
    • Organizer
      第25回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館 他
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] ソフトテンプレートに制御されたキラル酸化チタンの合成2014

    • Author(s)
      村上拳・松木囿裕之・斉藤美和・金仁華
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Intermediate-temperature-type Proton Conductors Having Perovskite-related Structures2014

    • Author(s)
      Miwa Saito, Ren-Hua Jin, Hiroshi Yamamura
    • Organizer
      17th Solid State Protonic Conductors
    • Place of Presentation
      KIST, Seoul, Korea
    • Year and Date
      2014-09-14 – 2014-09-19
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Intermediate-temperature-type Proton Conductors Having2014

    • Author(s)
      Miwa Saito, Minako Takagi, Ren-Hua Jin and Hiroshi Yamamura
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      Fukuoka University
    • Year and Date
      2014-08-24 – 2014-08-30
    • Related Report
      2014 Research-status Report
  • [Presentation] 酸塩基錯体型結晶性テンプレート表面での酸化チタンの合成2014

    • Author(s)
      村上拳・村田弘樹・松木囿裕之・斉藤美和・金仁華
    • Organizer
      第63回高分子学会年次大会
    • Place of Presentation
      名古屋国際会議場
    • Year and Date
      2014-05-28 – 2014-05-30
    • Related Report
      2014 Research-status Report
  • [Presentation] Synthesis of Intermediate-temperature-type Proton Conductors Having Perovskite-related Structures2014

    • Author(s)
      Miwa Saito, Minako Takagi, Ren-Hua Jin, and Hiroshi Yamamura
    • Organizer
      The 15th IUMRS-International Conference in Asia
    • Place of Presentation
      Fukuoka University, Fukuoka
    • Related Report
      2013 Research-status Report
  • [Presentation] Synthesis and Electrical conductivity of intermediate-temperature type proton conductor (BaxM1-x)2(Zn,M’)2O6-δ (M = La, Nd; M’ = W, Nb) having oxygen deficient perovskite-type structure2013

    • Author(s)
      M. Saito, M. Takagi, Ren-Hua Jin, and H. Yamamura
    • Organizer
      第23会日本MRS年次大会
    • Place of Presentation
      横浜市開港記念会館 他
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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