• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

A solid-state dedicated circularly polarized luminescence spectrophotometer: Development and application

Research Project

Project/Area Number 25870996
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Analytical chemistry
Research InstitutionOita University (2014)
Fukuoka University (2013)

Principal Investigator

HARADA Takunori  大分大学, 工学部, 准教授 (80581339)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Keywords円偏光蛍光 / キラル / プラズモン / ナノ複合体 / 超分子 / AIE
Outline of Final Research Achievements

In this study, we have developed a new method utilizing the phenomenon of plasmon resonance to amplify emission via circularly polarized luminescence (CPL), achieved by the use of a specially designed circular dichroism (CD) & circularly polarized luminescence (CPL) spectrophotometer and an analytical procedure. Specifically, we have constructed porphyrin complexes that are electrostatically coordinated to surfactant molecules, which in turn bind to silver nanoparticles that elicit the said plasmon resonance. The chiroptical properties of anionic meso-tetrakis(4-sulfonatophenyl)porphyrin complexed with cationic surfactants were enhanced by interaction with silver nanoparticles (AgNPs) in acidic solution. This excitation of AgNP surface plasmon resulted in |gabs| and |glum| values that were several times greater than in the unbound AgNPs. This new technique has the potential to be used in many chemical and biological applications that necessitate highly sensitive CPL measurements.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (26 results)

All 2015 2014 2013

All Journal Article (11 results) (of which Peer Reviewed: 11 results,  Open Access: 4 results,  Acknowledgement Compliant: 2 results) Presentation (13 results) Book (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Extraction of Resveratrol from Melinjo (/Gnetum gnemon L/.) Seeds Using Mixtures of Liquid Carbon Dioxide and Ethanol2015

    • Author(s)
      K. Mishima, Y. D. I. Siregar, H. Kawamura, R. Kawakami, S. Ito, Y. Inoue, T. Hirota, T. Harada, T. Kato, M. Misumi, T. Suetsugu, K. Irie, K. Mishima, S. Mustofa, F. Hasanah, H. Zaharo, L. S. E. Putri and A. Salim
    • Journal Title

      Solvent Extr. Res. Dev. Jpn.

      Volume: 22 Pages: 69-77

    • NAID

      130005071503

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Circularly polarized luminescence of chiral binaphthyl with achiral terthiophene fluorophores2015

    • Author(s)
      N. Taniguchi, K. Nakabayashi, T. Harada, N. Tajima, M. Shizuma, M. Fujiki, Y. Imai
    • Journal Title

      Chem Lett.

      Volume: - Issue: 5 Pages: 598-600

    • DOI

      10.1246/cl.150011

    • NAID

      130005067948

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Pyrene Magic: Chiroptical Enciphering and Deciphering 1,3-Dioxolane Bearing Two Wirepullings to Drive Two Remote Pyrenes2015

    • Author(s)
      T. Amako, K. Nakabayashi, N. Suzuki, S. Guo, N. A. A. Rahim, T. Harada, M. Fujiki and Y. Imai
    • Journal Title

      Chem. Commun.

      Volume: -

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spectroscopic characterization of supramolecular chiral porphyrin homoassociates at the air-water interface2014

    • Author(s)
      Harada T, Moriyama H, Takahashi H, Umemura K, Yokota H, Kawakami R, Mishima K.
    • Journal Title

      Appl. Spectrosc.

      Volume: 68 Issue: 11 Pages: 1235-1240

    • DOI

      10.1366/13-07432

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Plasmon-Resonance-Enhanced CPL for Self-Assembly Meso-tetrakis(4-sulfonatophenyl)porphyrin-Surfactant Complex interacted with Ag nanoparticles2014

    • Author(s)
      Takunori Harada, Naoki Kajiyama, Kei Ishizaka, Reona Toyofuku,b Katsuki Izumi,b Kazuo Umemura, Naoya Taniguchic and Kenji Mishima Yoshitane Imai,
    • Journal Title

      Chem. Commun.

      Volume: 50 Issue: 76 Pages: 11173-11176

    • DOI

      10.1039/c4cc04477k

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Extraction of Luteolin and Apigenin from Leaves of Perilla frutescens (L.) Britt. with Liquid Carbon Dioxide2014

    • Author(s)
      K. Mishima, R. Kawakami, H. Yokota, T. Harada, T. Kato, H. Kawamura, K. Matsuyama, S. Mustopha, F. Hasanah, Y. D. I. Siregar, L. S. E. Putri, A. Salim
    • Journal Title

      Solvent Extr. Res. Dev. Jpn.

      Volume: 21 Pages: 55-63

    • NAID

      130005056981

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Chiral Optical Properties of Phenyloxazoline Derivatives that Appear Only in the Solid State2014

    • Author(s)
      M. Hirayama, Y. Kobayashi, Y. Tanaka, T. Sato, T. Harada, N. Tajima, R. Kuroda, M. Fujiki, Y. Imai
    • Journal Title

      Eur. J. Org. Chem.

      Volume: なし Pages: 719-724

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Facile Synthetic Route to Highly Luminescent Sila[7]helicene2013

    • Author(s)
      H. Oyama, K. Nakano, T. Harada, R. Kuroda, M. Naito, K. Nobusawa, K. Nozaki
    • Journal Title

      Org. Lett.

      Volume: 15 Pages: 2104-2107

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Extraction of Xanthones from the Pericarps of Garcinia mangostana Linn. with Supercritical Carbon Dioxide and ethanol2013

    • Author(s)
      K. Mishima, R. Kawakami, H. Yokota, T. Harada, K. Irie, K. Mishima, M. Fujiwara, K. Matsuyama, S. Mustofa, A. Salim
    • Journal Title

      Solvent Extr. Res. Dev. Jpn.

      Volume: 20 Pages: 79-89

    • NAID

      130005056958

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] A New Method for Separating Configurational and Constitutional Chiralities Using Diffuse Reflectance Circular Dichroism (DRCD)2013

    • Author(s)
      T. Harada, T. Nakano, H. Moriyama, N. Tajima, H. Yokota, R. Kawakami, K. Mishima
    • Journal Title

      Appl. Spectrosc.

      Volume: 67 Pages: 1210-1213

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Solid-state circularly polarised luminescence and circular dichroism of viscous binaphthyl compounds2013

    • Author(s)
      T. Amako, T. Harada, N. Suzuki, K. Mishima, M. Fujiki, Y. Imai
    • Journal Title

      RSC Adv.

      Volume: 3 Pages: 23508-23513

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] Chirality Measurement Systems for Excited State Molecule2015

    • Author(s)
      Masayuki Watanabe, Ettore Castiglioni, Takunori Harada, Tatsuo Nehira
    • Organizer
      Chirality 2015
    • Place of Presentation
      Park Plaza Hotel, Boston
    • Year and Date
      2015-06-28 – 2015-07-01
    • Related Report
      2014 Annual Research Report
  • [Presentation] 局在表面プラズモン共鳴による円偏光蛍光増強発光メカニズム解明2015

    • Author(s)
      原田拓典・梶山直樹・梅村和夫・豊福玲於奈・和泉勝樹・三島健司・今井喜胤・谷口直哉
    • Organizer
      日本化学会年会2015
    • Place of Presentation
      日本大学理工学部船橋キャンパス、千葉
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Plasmon-Resonance-Enhanced CD and CPL for Self-Assembly Meso-tetrakis(4-sulfonatophenyl)porphyrin Composite interacted with Ag nanoparticles2014

    • Author(s)
      Naoki Kajiyama, Kei Ishizaka, Kazuo Umemura, Yoshitane Imai, Naoya Taniguchi, Kenji Mishima, Takunori Harada
    • Organizer
      モレキュラーキラリティ2014
    • Place of Presentation
      仙台国際センター、仙台
    • Year and Date
      2014-06-06 – 2014-06-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] Dual-purpose circular dichroism and circularly polarized luminescence spectrophotometer: Development and application2014

    • Author(s)
      Takunori Harada, Makoto Takamoto, Naoki Kajiyama, Hiroshi Hayakawa, Masayuki Watanabe, Kenji Mishima
    • Organizer
      モレキュラーキラリティ2014
    • Place of Presentation
      仙台国際センター、仙台
    • Year and Date
      2014-06-06 – 2014-06-07
    • Related Report
      2014 Annual Research Report
  • [Presentation] 超臨界二酸化炭素の圧力誘起法を用いた高分子マイクロコーティング2014

    • Author(s)
      三島 健司, 原田拓典
    • Organizer
      化学工学会第79年会
    • Place of Presentation
      岐阜大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 1,8-Dihydroxyanthraquinone結晶のキラル光学スペクトル:理論と実験による検討2014

    • Author(s)
      髙本真、原田拓典、田島暢夫、森山広思、三島健司
    • Organizer
      日本化学会年会2014
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 円偏光発光特性を有するアリールエチニルベンゼン系光学活性超分子有機発光体の創製2014

    • Author(s)
      西川智貴、谷口直哉、原田拓典、黒田玲子、藤木道也、今井喜胤
    • Organizer
      日本化学会年会2014
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 自己会合シアニン色素のキラル光学特性評価2013

    • Author(s)
      原田拓典、横田春生、川上亮、三島健司、黒田玲子、栗原舞、森山広思
    • Organizer
      2013モレキュラーキラリティ
    • Place of Presentation
      京都大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 粘稠軸不斉ビナフチル化合物の外部環境による非古典的光学特性制御2013

    • Author(s)
      尼子智之、赤木冬駒、木本貴也、鈴木望、原田拓典、三島健司、藤木道也、今井喜胤
    • Organizer
      2013モレキュラーキラリティ
    • Place of Presentation
      京都大学
    • Related Report
      2013 Research-status Report
  • [Presentation] Stokes-Mueller matrix approachによる次世代型円二色性分光計の開発2013

    • Author(s)
      原田拓典、横田春生、川上亮、三島健司、高橋浩三、黒田玲子
    • Organizer
      光学シンポジウム2013
    • Place of Presentation
      東京大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 光学活性ナフタレン化合物の各種マトリックス中におけるキラルな光学特性2013

    • Author(s)
      北山陽子、尼子智之、原田拓典、三島健司、黒田玲子、藤木道也、今井喜胤
    • Organizer
      基礎有機討論会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ジエチルエーテル鎖を有する軸不斉ビナフチル化合物の各種マトリックス中におけるキラルな光学特性2013

    • Author(s)
      中林和輝、尼子智之、原田拓典、三島健司、藤木道也、今井喜胤
    • Organizer
      基礎有機討論会
    • Place of Presentation
      学習院大学
    • Related Report
      2013 Research-status Report
  • [Presentation] 粘稠性軸不斉ビナフチル化合物の固体状態における円偏光発光特性2013

    • Author(s)
      尼子智之、原田拓典、鈴木望、三島健司、藤木道也、今井喜胤
    • Organizer
      有機典型元素化学討論会
    • Place of Presentation
      近畿大学
    • Related Report
      2013 Research-status Report
  • [Book] Solid-State Circular Dichroism Spectroscopy” in Encyclopedia Of Polymer Science and Technology2013

    • Author(s)
      T. Harada, H. Moriyama
    • Total Pages
      29
    • Publisher
      John Wiley & Sons, Inc.
    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] 4. 円二色性スペクトル及び円偏光蛍光を同一の光学系で測定する方法および装置2013

    • Inventor(s)
      原田拓典
    • Industrial Property Rights Holder
      原田拓典
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2013-240734
    • Filing Date
      2013-11-21
    • Related Report
      2013 Research-status Report

URL: 

Published: 2014-07-25   Modified: 2019-07-29  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi