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Development of a new type of thin film solar cell based on a new material with suitable band gap for single junction type solar cell

Research Project

Project/Area Number 25871032
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Electronic materials/Electric materials
Crystal engineering
Research InstitutionNagaoka National College of Technology

Principal Investigator

ARAKI Hideaki  長岡工業高等専門学校, 物質工学科, 准教授 (40342480)

Project Period (FY) 2013-04-01 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2013: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywords新機能材料 / 太陽電池材料 / 化合物薄膜太陽電池 / 硫化物 / 太陽電池 / 薄膜
Outline of Final Research Achievements

In- and Se-free Cu2GeS3 (CGS) thin films were prepared by thermal evaporation followed by sulfurization, and photovoltaic cells with a glass/Mo/CGS/CdS/ZnO:Al/Al structure were fabricated. The average compositions of the films were considered to be the stoichiometric compositions. The X-ray diffraction spectra of the sulfurized films were attributed to Cu2GeS3. By optical measurement, the band gap energy was estimated to be 1.5-1.6 eV. In the visible region, a CGS film has an optical absorption coefficient that is on the order of 10000 cm-1. A solar cell fabricated using the Cu2GeS3 thin film exhibited an open-circuit voltage of 380mV, a short circuit current density of 12.6mA/cm2, a fill factor of 0.355, and a conversion efficiency of 1.70%.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Research-status Report
  • Research Products

    (5 results)

All 2015 2014 2013

All Journal Article (1 results) (of which Peer Reviewed: 1 results) Presentation (4 results) (of which Invited: 1 results)

  • [Journal Article] Fabrication of Cu2GeS3-based thin film solar cells by sulfurization of Cu/Ge stacked precursors2014

    • Author(s)
      Hideaki Araki, Kotaro Chino, Kazuki Kimura, Naoya Aihara, Kazuo Jimbo, and Hironori Katagiri
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S1 Pages: 05FW10-05FW10

    • DOI

      10.7567/jjap.53.05fw10

    • NAID

      210000143916

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] GeS2とS蒸気反応を用いたCu2GeS3薄膜太陽電池の作製2015

    • Author(s)
      知野広太郎,豊永詞,金井綾香,荒木秀明
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学 湘南キャンパス(神奈川県・平塚市)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Progress in thin film solar cells based on Cu2SnS3 and the related compounds, Cu2GeS3 and Cu2SiS32014

    • Author(s)
      Hideaki Araki
    • Organizer
      2014年多元系化合物・太陽電池研究会年末講演会,International workshop for young researchers on thin film compound semiconductor solar cells
    • Place of Presentation
      Ryukoku University Avanti Kyoto Hall (Kyoto)
    • Year and Date
      2014-11-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Fabrication of Cu2GeS3-based Thin Film Solar Cells by Sulfurization of Cu/Ge Stacked Precursors2013

    • Author(s)
      Hideaki Araki, Kotaro Chino, Kazuki Kimura, Naoya Aihara, Kazuo Jimbo, and Hironori Katagiri
    • Organizer
      2013 JSAP-MRS Joint Symposia
    • Place of Presentation
      Doshisha Univ., Kyoto, Japan
    • Related Report
      2013 Research-status Report
  • [Presentation] Cu2GeS3薄膜太陽電池の作製と太陽電池への応用2013

    • Author(s)
      木村和貴,荒木秀明
    • Organizer
      第3回高専-TUT太陽電池合同シンポジウム
    • Place of Presentation
      木更津工業高等専門学校,木更津
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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