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Improvement of Performance for Fuel Cells with Phosphate Glass Electrolytes

Research Project

Project/Area Number 25871187
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic materials/Physical properties
Structural/Functional materials
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

Sumi Hirofumi  国立研究開発法人産業技術総合研究所, 無機機能材料研究部門, 主任研究員 (80613257)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords燃料電池 / ガラス / 電気化学 / 省エネルギー技術 / エネルギー変換プロセス
Outline of Final Research Achievements

In this study, the effects of dopant composition and melting temperature on glass structure and protonic conductivity for 30 mol%MO-70 mol%P2O5 (M = Ba, Zn) glasses. Mobile proton concentration increased by a decrease in the melting temperature from 1000℃ to 800℃ due to the increase in remained water in the glasses. The phosphate glass structure was changed from the branched structure to straight chain by substituting Ba with Zn, which improved the proton mobility. The proton conductivity reached to 1×10-3 S/cm at 250℃ for the 30ZnO-70P2O5 glass melted at 800℃. The power density of 1.2 mW/cm2 was obtained for the fuel cell, whose electrolyte was formed directly on the Pt/C electrodes. The power density for the cells made by the new method was 6 times larger than that for the previous cells.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (8 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (5 results)

  • [Journal Article] Proton Conduction of MO-P2O5 Glasses (M = Zn, Ba) Containing a Large Amount of Water2015

    • Author(s)
      H. Sumi, Y. Nakano, Y. Fujishiro, T. Kasuga
    • Journal Title

      Solid State Science

      Volume: 45 Pages: 5-8

    • DOI

      10.1016/j.solidstatesciences.2015.04.009

    • Related Report
      2015 Annual Research Report 2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Correlation between Protonic Conductivity and Structure of Phosphate Glasses for Intermediate Temperature Fuel Cells2013

    • Author(s)
      H. Sumi, Y. Fujishiro, T. Oine, T. Kasuga
    • Journal Title

      ECS Transactions

      Volume: 50(27) Issue: 27 Pages: 187-191

    • DOI

      10.1149/05027.0187ecst

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Journal Article] Proton Conductivities and Structures of BaO-ZnO-P2O5 Glasses in the Ultraphosphate Region for Intermediate Temperature Fuel Cells2013

    • Author(s)
      H. Sumi, Y. Nakano, Y. Fujishiro, T. Kasuga
    • Journal Title

      International Journal of Hydrogen Energy

      Volume: 38 Issue: 35 Pages: 15354-15360

    • DOI

      10.1016/j.ijhydene.2013.09.087

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] リン酸塩ガラスのプロトン伝導度に及ぼす添加元素の影響2015

    • Author(s)
      鷲見 裕史
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学(埼玉県)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] プロトン伝導性リン酸塩ガラス電解質を用いた中温作動燃料電池の開発2014

    • Author(s)
      鷲見 裕史
    • Organizer
      日本セラミックス協会第27回秋季シンポジウム
    • Place of Presentation
      鹿児島大学(鹿児島)
    • Year and Date
      2014-09-11
    • Related Report
      2014 Research-status Report
  • [Presentation] 作製条件の異なるリン酸亜鉛ガラスのプロトン伝導性

    • Author(s)
      中野雄貴, 前田浩孝, 中山将伸, 春日敏宏, 鷲見裕史, 藤代芳伸
    • Organizer
      第46回東海若手セラミスト懇話会 2013年夏期セミナー
    • Place of Presentation
      ホテル犬山館(愛知)
    • Related Report
      2013 Research-status Report
  • [Presentation] 中温作動燃料電池向けリン酸塩ガラス電解質の開発

    • Author(s)
      鷲見裕史, 藤代芳伸, 中野雄貴, 春日敏宏
    • Organizer
      日本セラミックス協会 第26回秋季シンポジウム
    • Place of Presentation
      信州大学(長野)
    • Related Report
      2013 Research-status Report
  • [Presentation] MO-P2O5ガラス(M=Zn, Ba)の構造とプロトン伝導性

    • Author(s)
      鷲見裕史
    • Organizer
      第39回固体イオニクス討論会
    • Place of Presentation
      くまもと県民交流館パレア(熊本)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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