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Electrolyte property for lithium secondary battery of low-melting alkali metal molten salt

Research Project

Project/Area Number 25871188
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Inorganic materials/Physical properties
Research InstitutionNational Institute of Advanced Industrial Science and Technology

Principal Investigator

KUBOTA KEIGO  国立研究開発法人産業技術総合研究所, 電池技術研究部門, 主任研究員 (40586559)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2014: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2013: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords溶融塩 / アルカリ金属塩 / リチウム二次電池 / イオン液体 / 電解質
Outline of Final Research Achievements

Low-melting alkali metal molten salt has possibility of a novel electrolyte of lithium secondary battery due to its specifically low melting point of 100 degree or less. This molten salt shows stable charge-discharge curves and good rate performance in a lithium battery cell. In this study, we discussed about the specific rate performance. In the result, the specific rate performance is caused by charge transfer resistance between the molten salt and electrodes, which dominates the charge transfer of lithium ion in the battery cell.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (15 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 4 results,  Acknowledgement Compliant: 3 results) Presentation (11 results)

  • [Journal Article] 低融点アルカリ金属溶融塩の電気化学デバイスへの応用2015

    • Author(s)
      窪田 啓吾
    • Journal Title

      溶融塩および高温化学

      Volume: 58 Pages: 142-147

    • NAID

      40020395510

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Electrochemical Deposition of Alkali Metal in Low-Melting Alkali Metal Perfluorosulfonylamides2014

    • Author(s)
      Keigo Kubota, Hajime Matsumoto
    • Journal Title

      ECS Transaction

      Volume: 64 Issue: 4 Pages: 319-322

    • DOI

      10.1149/06404.0319ecst

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Solvent free lithium molten salt as electrolyte of lithium secondary battery2014

    • Author(s)
      Keigo Kubota, Hajime Matsumoto
    • Journal Title

      ECS Transaction

      Volume: 62 Issue: 1 Pages: 231-234

    • DOI

      10.1149/06201.0231ecst

    • Related Report
      2014 Research-status Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Cation Mixtures of Alkali Metal (Fluorosulfonyl)(trifluoromethylsulfonyl)amide as Electrolytes for Lithium Secondary Battery2014

    • Author(s)
      窪田 啓吾, 松本 一
    • Journal Title

      Journal of The Electrochemical Society

      Volume: 161 Issue: 6 Pages: A902-A907

    • DOI

      10.1149/2.026406jes

    • Related Report
      2013 Research-status Report
    • Peer Reviewed
  • [Presentation] 低融点アルカリ金属溶融塩中における合剤電極の界面電荷移動抵抗2016

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      2016年電気化学会第83回大会
    • Place of Presentation
      大阪大学(大阪府)
    • Year and Date
      2016-03-29
    • Related Report
      2015 Annual Research Report
  • [Presentation] イオン液体中におけるナトリウム金属負極の界面抵抗の解析2015

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      第56回電池討論会
    • Place of Presentation
      愛知県産業労働センター ウインクあいち(愛知県)
    • Year and Date
      2015-11-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低融点アルカリ金属溶融塩中におけるアルカリ金属の析出挙動2015

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      2015年電気化学秋季大会
    • Place of Presentation
      埼玉工業大学 (埼玉県)
    • Year and Date
      2015-09-11
    • Related Report
      2015 Annual Research Report
  • [Presentation] 低融点アルカリ金属溶融塩の電気化学デバイスへの応用2015

    • Author(s)
      窪田 啓吾
    • Organizer
      第186回溶融塩委員会
    • Place of Presentation
      京都
    • Year and Date
      2015-02-04
    • Related Report
      2014 Research-status Report
  • [Presentation] 低融点リチウム溶融塩を用いたリチウムイオン電池の構築2014

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      第55回電池討論会
    • Place of Presentation
      京都
    • Year and Date
      2014-11-19
    • Related Report
      2014 Research-status Report
  • [Presentation] 低融点アルカリ金属ペルフルオロスルフォニルアミド溶融塩の輸送特性2014

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      第46回溶融塩化学討論会
    • Place of Presentation
      千葉
    • Year and Date
      2014-11-13
    • Related Report
      2014 Research-status Report
  • [Presentation] Electrochemical Deposition of Alkali Metal in Low-Melting Alkali Metal Perfluorosulfonylamides2014

    • Author(s)
      Keigo Kubota, Hajime Matsumoto
    • Organizer
      2014 ECS and SMEQ Joint International Meeting
    • Place of Presentation
      カンクン(メキシコ)
    • Year and Date
      2014-10-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 室温域リチウム溶融塩の物理化学的性質と電極界面抵抗の相関2014

    • Author(s)
      窪田 啓吾、松本 一
    • Organizer
      2014年 電気化学秋季大会
    • Place of Presentation
      北海道
    • Year and Date
      2014-09-27
    • Related Report
      2014 Research-status Report
  • [Presentation] Solvent free lithium molten salt as electrolyte of lithium secondary battery2014

    • Author(s)
      Keigo Kubota, Hajime Matsumoto
    • Organizer
      The 17th International Meeting on Lithium Battery
    • Place of Presentation
      コモ(イタリア)
    • Year and Date
      2014-06-12
    • Related Report
      2014 Research-status Report
  • [Presentation] 中温域アルカリ金属アミド溶融塩の輸送特性

    • Author(s)
      窪田 啓吾, 松本 一
    • Organizer
      第45回溶融塩化学討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス独立館(横浜)
    • Related Report
      2013 Research-status Report
  • [Presentation] リチウムアミド溶融塩のシングルイオン伝導特性

    • Author(s)
      窪田 啓吾, 松本 一
    • Organizer
      第4回イオン液体討論会
    • Place of Presentation
      慶應義塾大学日吉キャンパス独立館(横浜)
    • Related Report
      2013 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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