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Application of Boron-doped Diamond Microelectrodes for Dental Treatment with Pinpoint Ozone-water Production

Research Project

Project/Area Number 25871218
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Inorganic industrial materials
Conservative dentistry
Research InstitutionKanagawa Academy of Science and Technology

Principal Investigator

Ochiai Tsuyoshi  公益財団法人神奈川科学技術アカデミー, 実用化実証事業 光触媒グループ, サブリーダー (60514114)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2013: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Keywords導電性ダイヤモンド電極 / 電気化学材料 / 歯内治療学 / 電解機能水生成
Outline of Final Research Achievements

We devised a flexible pinpoint electrolysis unit employing a boron-doped diamond powder (BDDP)-based polymer composite for use in dental treatment. A metal wire surface (the anode) was coated by the BDDP-based polymer composite comprising BDDP and a 20% Nafion(R) dispersion at a mixing ratio of 2/1 (w/w). A Pt ribbon with an ion-exchange membrane was spirally wound around the metal wire’s surface for use as the cathode. When a direct current voltage was applied between the anode and cathode in water, ozone and oxidative intermediates were generated. The unit showed almost the same sterilization ability as obtained by 1 wt% aqueous NaOCl in an in vitro assessment of the root canals of human teeth. Moreover, the BDDP-based polymer composite has excellent durability, hardly cracking or peeling, even with repeated bending during electrolysis. We believe that our work will enable the development of a practical unit for dental treatment.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (21 results)

All 2016 2015 2014 Other

All Journal Article (4 results) (of which Peer Reviewed: 3 results,  Open Access: 1 results,  Acknowledgement Compliant: 1 results) Presentation (11 results) (of which Int'l Joint Research: 3 results,  Invited: 6 results) Remarks (4 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 1 results)

  • [Journal Article] Boron-doped diamond powder (BDDP)-based polymer composites for dental treatment using flexible pinpoint electrolysis unit2016

    • Author(s)
      Ochiai, T.; Tago, S.; Hayashi, M.; Hirota, K.; Kondo, T.; Satomura, K.; Fujishima, A.
    • Journal Title

      Electrochemistry Communications

      Volume: 68 Pages: 49-53

    • DOI

      10.1016/j.elecom.2016.04.011

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] ダイヤモンド電極の歯科治療への応用2015

    • Author(s)
      落合剛; 藤嶋昭
    • Journal Title

      NEW DIAMOND

      Volume: 31 Pages: 26-28

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 酸化チタン光触媒およびホウ素ドープダイヤモンド電極の環境浄化や医療への応用2015

    • Author(s)
      落合剛; 藤嶋昭
    • Journal Title

      セラミックデータブック

      Volume: 43 Pages: 82-86

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 総説・解説2015

    • Author(s)
      落合剛; 藤嶋昭
    • Journal Title

      NEW DIAMOND

      Volume: 31 Pages: 26-28

    • Related Report
      2014 Research-status Report
    • Acknowledgement Compliant
  • [Presentation] Effective Design for Environmental and Medical Application of TiO2 Photocatalysts and Boron-doped Diamond Electrodes2016

    • Author(s)
      T. Ochiai, A. Fujishima
    • Organizer
      2016 the International Symposium on Energy and Environmental. Photocatalytic Materials (EEPM 2)
    • Place of Presentation
      Wuhan, P.R. China
    • Year and Date
      2016-04-03
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Conductive Diamond-powder/Polymer Composites for Electrochemical Disinfection of Root-canal2016

    • Author(s)
      Tsuyoshi Ochiai, Mio Hayashi, Shoko Tago, Kazuo Hirota, Takeshi Kondo, Kazuhito Satomura, Akira Fujishima
    • Organizer
      2016 AADR/CADR Annual Meeting
    • Place of Presentation
      Los Angels Convention Center, Los Angels
    • Year and Date
      2016-03-18
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Flexible Pinpoint Electrolysis Unit by Using of Boron-doped Diamond Powder (BDDP) Based Polymer Composites for Dental Treatments2015

    • Author(s)
      Tsuyoshi Ochiai, Mio Hayashi, Shoko Tago, Kazuo Hirota, Takeshi Kondo, Kazuhito Satomura, Akira Fujishima
    • Organizer
      66th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Taipei International Convention Center, Taipei
    • Year and Date
      2015-10-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] ダイヤモンド電極を利用した歯科治療用微小電解ユニット開発の試み2015

    • Author(s)
      里村一人、落合剛、田子祥子、林美緒、近藤剛史、広田一男、藤嶋昭
    • Organizer
      第25回日本口腔内科学会学術大会
    • Place of Presentation
      大阪大学吹田キャンパス
    • Year and Date
      2015-09-19
    • Related Report
      2015 Annual Research Report
  • [Presentation] Flexible Pinpoint Electrolysis Unit Coated with Boron-doped Diamond Powder (BDDP) Based Polymer Composites for Dental Treatments2015

    • Author(s)
      T. Ochiai, M. Hayashi, S. Tago, K. Hirota, T. Kondo, K. Satomura, A. Fujishima
    • Organizer
      The 16th Topical Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Vila Gale Eco Resort of Angra dos Reis, Angra dos Reis, Brazil
    • Year and Date
      2015-03-22 – 2015-03-26
    • Related Report
      2014 Research-status Report
  • [Presentation] ホウ素ドープダイヤモンド電極を用いた歯科治療用電解ユニット2015

    • Author(s)
      落合 剛
    • Organizer
      第5回オゾン水研究会
    • Place of Presentation
      星薬科大学
    • Year and Date
      2015-03-06
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Flexible Pinpoint Electrolysis Unit Coated with Boron-doped Diamond (BDD) Based Polymer Composites for Dental Treatments2014

    • Author(s)
      T. Ochiai, S. Tago, K. Hirota, T. Kondo, K. Satomura, A. Fujishima
    • Organizer
      The 65th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      EPFL, Lausanne, Switzerland
    • Year and Date
      2014-08-31 – 2014-09-05
    • Related Report
      2014 Research-status Report
  • [Presentation] 産学公連携でつながる人と人、うまれるアイデア-酸化チタン光触媒と導電性ダイヤモンド電極の、環境・医療技術への応用を例にして2014

    • Author(s)
      落合 剛
    • Organizer
      電気化学会関東支部第32回夏の学校
    • Place of Presentation
      八王子セミナーハウス
    • Year and Date
      2014-08-29
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] 酸化チタン光触媒と導電性ダイヤモンド電極:光電気化学と環境・医療技術との融合が切り拓く次世代社会2014

    • Author(s)
      落合 剛
    • Organizer
      上智大学理工学部物質生命理工学科コロキウム
    • Place of Presentation
      上智大学
    • Year and Date
      2014-07-18
    • Related Report
      2014 Research-status Report
    • Invited
  • [Presentation] Application of Boron-Doped Diamond Microelectrodes for Dental Treatment with Pinpoint Ozone-Water Production

    • Author(s)
      T. Ochiai, S. Tago, K. Hirota, Y. Einaga, A. Fujishima
    • Organizer
      International Symposium on Diamond Electrochemistry
    • Place of Presentation
      Keio University, Japan
    • Related Report
      2013 Research-status Report
    • Invited
  • [Presentation] 光触媒および導電性ダイヤモンド電極の環境浄化や医療への応用に関する研究

    • Author(s)
      落合 剛
    • Organizer
      電気化学会第81回大会、進歩賞受賞記念講演
    • Place of Presentation
      関西大学
    • Related Report
      2013 Research-status Report
    • Invited
  • [Remarks] ResearchGate

    • URL

      https://www.researchgate.net/profile/Tsuyoshi_Ochiai

    • Related Report
      2015 Annual Research Report
  • [Remarks] KAST「光触媒」グループ(材料グループ)紹介ページ

    • URL

      http://www.newkast.or.jp/innovation/labo/fujishima_project.html

    • Related Report
      2015 Annual Research Report
  • [Remarks] (公財) 神奈川科学技術アカデミー「光触媒」グループ(材料グループ)研究紹介ページ

    • URL

      http://www.newkast.or.jp/innovation/labo/fujishima_project.html

    • Related Report
      2014 Research-status Report
  • [Remarks] 落合 剛 サブリーダー・常勤研究員が『電気化学会 進歩賞・佐野賞』を受賞!

    • URL

      http://www.newkast.or.jp/innovation/labo/ec2014.html

    • Related Report
      2013 Research-status Report
  • [Patent(Industrial Property Rights)] Coating material for use in electrode formation which contains electrically conductive diamond powder, electrode, and dental therapy tool2015

    • Inventor(s)
      藤嶋 昭、落合 剛、田子祥子、近藤剛史、里村一人、広田一男
    • Industrial Property Rights Holder
      藤嶋 昭、落合 剛、田子祥子、近藤剛史、里村一人、広田一男
    • Industrial Property Rights Type
      特許
    • Filing Date
      2015-07-29
    • Related Report
      2015 Annual Research Report
    • Overseas
  • [Patent(Industrial Property Rights)] 電極形成用導電性ダイヤモンド粉末含有塗料、電極及び歯科治療器具2014

    • Inventor(s)
      藤嶋 昭、落合 剛、田子祥子、近藤剛史、里村一人、広田一男
    • Industrial Property Rights Holder
      公財)神奈川科学技術アカデミー、東京理科大、鶴見大、株)ジーシー
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2014-154449
    • Filing Date
      2014-07-30
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2019-07-29  

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