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Development of two-dimensional silicon nanosheets having electron conductivity

Research Project

Project/Area Number 25871250
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeMulti-year Fund
Research Field Functional solid state chemistry
Inorganic chemistry
Research InstitutionToyota Central R&D Lab., Inc.

Principal Investigator

Ohashi Masataka  株式会社豊田中央研究所, 戦略先端研究領域 機能性Si低次元材料プログラム, 研究員 (10418436)

Project Period (FY) 2013-04-01 – 2016-03-31
Project Status Completed (Fiscal Year 2015)
Budget Amount *help
¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2014: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsナノシート / シリコン / 導電性 / リチウム化 / 高分子 / 複合化 / 自立膜 / 金属ナノ粒子 / 複合材料 / 導電率 / テラヘルツ分光 / 有機高分子 / 炭素材料 / ナノ複合構造 / 薄膜 / リチウム / メカノケミカル
Outline of Final Research Achievements

In this study, we focused on the preparation of silicon nanosheets (Si-NSs) having electrical conductivity and a self-standing thin film of Si-NSs. As a result, we revealed that the electrical conductivity of Si-NSs was controlled by the lithiation of Si-NSs which proceed by a mechanochemical solid phase reaction of Si-NSs and metallic lithium. In addition, we succeeded to prepare Si-NSs/polystyrene composite (Si-NSs/PS) by the reaction of Si-NSs with styrene. Si-NSs/PS dissolved in organic solvents and formed a self-standing thin film by drying of the Si-NSs/PS slurry on the flat plate.

Report

(4 results)
  • 2015 Annual Research Report   Final Research Report ( PDF )
  • 2014 Research-status Report
  • 2013 Research-status Report
  • Research Products

    (13 results)

All 2016 2015 2014 2013

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Acknowledgement Compliant: 2 results,  Peer Reviewed: 1 results) Presentation (8 results) (of which Int'l Joint Research: 2 results,  Invited: 1 results) Book (1 results)

  • [Journal Article] Soft Chemical Synthesis of Functionalized Silicene2016

    • Author(s)
      Hideyuki Nakano and Masataka Ohashi
    • Journal Title

      Springer Series in Materials Science, Silicene Structure, Properties and Applications

      Volume: 235 Pages: 85-106

    • DOI

      10.1007/978-3-319-28344-9_4

    • ISBN
      9783319283425, 9783319283449
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Journal Article] 4.シリコンナノシートの作製と応用2015

    • Author(s)
      大橋雅卓、中野秀之
    • Journal Title

      Electrochemistry

      Volume: 83 Issue: 8 Pages: 648-652

    • DOI

      10.5796/electrochemistry.83.648

    • NAID

      130005092000

    • ISSN
      1344-3542, 2186-2451
    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] シリコンナノシートの合成技術と電池特性・光学特性2015

    • Author(s)
      板原浩、今川晴雄、大橋雅卓、中野秀之
    • Journal Title

      触媒

      Volume: 57 Pages: 348-354

    • Related Report
      2015 Annual Research Report
    • Acknowledgement Compliant
  • [Journal Article] Mechanochemical lithiation of layered polysilane2014

    • Author(s)
      M. Ohashi, H. Nakano, T. Morishita, M. Spencer, Y. Ikemoto, C. Yogi, T. Ohta
    • Journal Title

      Chemical Communications

      Volume: 50 Issue: 68 Pages: 9761-9764

    • DOI

      10.1039/c4cc03850a

    • Related Report
      2014 Research-status Report
    • Peer Reviewed
  • [Presentation] シリコンナノシートの還元力を利用した金属ナノ粒子の合成2016

    • Author(s)
      大橋雅卓、八百川律子、中野秀之
    • Organizer
      日本化学会 第96春季年会 (2016)
    • Place of Presentation
      同志社大学、京都府京田辺市
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Chemical Modification of Silicon Nanosheet2016

    • Author(s)
      Masataka Ohashi and Hideyuki Nakano
    • Organizer
      2016 Kumamoto Symposium on Two Dimensional Nanomaterials
    • Place of Presentation
      熊本大学、熊本県熊本市
    • Year and Date
      2016-02-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Mechanochemical Lithiation of Layered Polysilane2015

    • Author(s)
      Masataka Ohashi and Hideyuki Nakano
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Hawaii Convention Center, Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] カルシウムシリサイドのスクロース/塩酸 処理による層状シリコン/炭素複合体の合成2015

    • Author(s)
      大橋雅卓, 中野秀之
    • Organizer
      日本化学会 第95春季年会 (2015)
    • Place of Presentation
      日本大学理工学部船橋キャンパス/薬学部
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Research-status Report
  • [Presentation] シリコンナノシートの創製と機能化2014

    • Author(s)
      大橋雅卓, 中野秀之
    • Organizer
      合同シンポジウム2014 ~放射光とレーザーの協働による新産業創成~
    • Place of Presentation
      神戸国際会議場 国際会議室301
    • Year and Date
      2014-11-14
    • Related Report
      2014 Research-status Report
  • [Presentation] 層状ポリシラン/ポリスチレン複合体の合成と薄膜形成2014

    • Author(s)
      大橋雅卓, 中野秀之
    • Organizer
      日本化学会第94春季年会
    • Place of Presentation
      名古屋大学
    • Related Report
      2013 Research-status Report
  • [Presentation] ミリング法による層状ポリシラン/リチウム複合体の合成と性質2013

    • Author(s)
      大橋雅卓, 中野秀之, 小川雅裕, 山中恵介, 与儀千尋, 太田俊明
    • Organizer
      立命館大学SRセンター研究成果報告会
    • Place of Presentation
      立命館大学
    • Related Report
      2013 Research-status Report
  • [Presentation] シリコンナノシート/リチウム複合体の合成と電導性の制御2013

    • Author(s)
      大橋雅卓, 中野秀之, 与儀千尋, 太田俊明
    • Organizer
      錯体化学会第63回討論会
    • Place of Presentation
      琉球大学
    • Related Report
      2013 Research-status Report
  • [Book] CERAMIC DATA BOOK 2014/152014

    • Author(s)
      大橋雅卓、中野秀之
    • Total Pages
      176
    • Publisher
      工業製品技術協会(株式会社テクノプラザ)
    • Related Report
      2014 Research-status Report

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Published: 2014-07-25   Modified: 2023-03-16  

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