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Solubilization and Isolation of Metallofullerenes by the Encapsulation with Novel Macrocyclic Compounds

Research Project

Project/Area Number 25887029
Research Category

Grant-in-Aid for Research Activity Start-up

Allocation TypeSingle-year Grants
Research Field Mathematical analysis
Research InstitutionNagoya University

Principal Investigator

OMACHI Haruka  名古屋大学, 物質科学国際研究センター, 助教 (60711497)

Project Period (FY) 2013-08-30 – 2015-03-31
Project Status Completed (Fiscal Year 2014)
Budget Amount *help
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywordsフラーレン / 環状化合物 / 包接 / 金属内包フラーレン
Outline of Final Research Achievements

We have tackled the solubilization and the isolation of metallofullerene, which is a one of the promising nanocarbon materials, by the encapsulation with novel macrocyclic compounds. We have found that the pi-conjugated macrocycles are effective for the size-selective encapsulation of fullerenes. Using this technology, the size-selective extraction of metallofullerene have been achieved. We have also designed new macrocycles for the encapsulation of fullerenes and revealed the stabilization energies, the collaboration work with theoretical scientists.

Report

(3 results)
  • 2014 Annual Research Report   Final Research Report ( PDF )
  • 2013 Annual Research Report
  • Research Products

    (10 results)

All 2015 2014 2013 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results,  Acknowledgement Compliant: 1 results) Presentation (5 results) (of which Invited: 5 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Nano-Saturn: Energetics of the Inclusion Process of C60 into Cyclohexabiphenylene2015

    • Author(s)
      Shota Kigure, Haruka Omachi, Hisanori Shinohara, Susumu Okada
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 16 Pages: 8931-8936

    • DOI

      10.1021/acs.jpcc.5b00449

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication and Optical Probing of Highly Extended, Ultrathin Graphene Nanoribbons in Carbon Nanotubes2015

    • Author(s)
      H.E. Lim, Y. Miyata, M. Fujihara, S. Okada, Z. Liu, Arifin, K. Sato, H. Omachi, R. Kitaura, S. Irle, K. Suenaga, H. Shinohara
    • Journal Title

      ACS nano

      Volume: 未確定 Issue: 5 Pages: 5034-5040

    • DOI

      10.1021/nn507408m

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] “Size-Selective Complexation and Extraction of Endohedral metallofullerenes with Cycloparaphenylene”2014

    • Author(s)
      Y.Nakanishi
    • Journal Title

      Angew.Chem.Int.Ed.

      Volume: 53 Issue: 12 Pages: 3102-3106

    • DOI

      10.1002/anie.201311268

    • Related Report
      2013 Annual Research Report
    • Peer Reviewed
  • [Presentation] カーボンナノチューブの内部空間を利用した新物質創製2015

    • Author(s)
      大町 遼
    • Organizer
      Reaxys PhD Prizeランチョンセミナー
    • Place of Presentation
      日本大学船橋キャンパス、千葉
    • Year and Date
      2015-03-28
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Smasys 20142014

    • Author(s)
      Haruka Omachi, Mika Tsuboi, Yusuke Sako, Ryo Kitaura, and Hisanori Shinohara
    • Organizer
      Smasys 2014
    • Place of Presentation
      山形大学、山形
    • Year and Date
      2014-10-15 – 2014-10-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 有機合成化学とナノカーボン科学へのアプローチ2014

    • Author(s)
      大町 遼
    • Organizer
      岡田グループセミナー
    • Place of Presentation
      筑波大学、茨城
    • Year and Date
      2014-07-29
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] カーボンナノチューブへの新規修飾反応とその応用2014

    • Author(s)
      大町 遼、坪井 美香、酒向 優佑、北浦 良、篠原 久典
    • Organizer
      統合物質創製化学推進事業第5回若手研究会
    • Place of Presentation
      休暇村支笏湖、北海道
    • Year and Date
      2014-06-20 – 2014-06-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Selective Complexation and Extraction of Endohedral Metallofullerenes with Cycloparaphenylene2013

    • Author(s)
      Haruka Omachi
    • Organizer
      16th IRTG Joint Symposium of University of Munster and Nagoya University
    • Place of Presentation
      University of Munster, Germany
    • Related Report
      2013 Annual Research Report
    • Invited
  • [Book] フラーレン誘導体・内包技術の最前線(監修:松尾豊)1-2. フラーレン・金属内包フラーレンの分子構造と電子物性2014

    • Author(s)
      大町遼、篠原久典
    • Total Pages
      8
    • Publisher
      シーエムシー出版
    • Related Report
      2014 Annual Research Report
  • [Remarks] 化学科の最新論文

    • URL

      http://www3.chem.nagoya-u.ac.jp/wordpress/?p=8711

    • Related Report
      2013 Annual Research Report

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Published: 2013-09-12   Modified: 2019-07-29  

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