| Project/Area Number |
25888011
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| Research Category |
Grant-in-Aid for Research Activity Start-up
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| Allocation Type | Single-year Grants |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Kyoto University |
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Principal Investigator |
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| Project Period (FY) |
2013-08-30 – 2015-03-31
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| Project Status |
Completed (Fiscal Year 2014)
|
| Budget Amount *help |
¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
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| Keywords | 有機化学 / ピロール / 典型元素化学 / ヘテロール / 機能性材料 / 典型元素科学 |
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| Outline of Final Research Achievements |
In this research, we developed novel pyrrole-based pi-conjugated molecules with main group elements. We synthesized the bipyrrole as a key intermediate. In the next step, we attmpted to introduce the main group elements into bipyrroles. While we could not obtained compound with nitrogen atom, we succeeded in the synthesis of compounds containing sulfur, phosphorus, and silicon atoms. We evaluated their properties and revealed that they are the rare examples of radialene-like molecules.
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