Enantioselective synthesis of alpha-aminoboronic acid derivatives through catalytic oxidation and borylation

• Project/Area Number: 25888014
• Research Category: Grant-in-Aid for Research Activity Start-up
• Allocation Type: Single-year Grants
• Research Field: Synthetic chemistry
• Research Institution: Osaka University
• Principal Investigator: KAWAMORITA Soichiro 大阪大学, 基礎工学研究科, 助教 (00708472)
• Project Period (FY): 2013-08-30 – 2015-03-31
• Project Status: Completed (Fiscal Year 2014)
• Budget Amount: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000); Fiscal Year 2014: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2013: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
• Keywords: ホウ素化合物 / 不斉反応 / 不斉ホウ素化 / ロジウム触媒 / αアミノボロン酸 / α-アミノボロン酸

Outline of Final Research Achievements

Enantioselective synthesis of alpha-aminoboronic acid derivatives through catalytic oxidation and borylation has been investigated

Research Products

• [Journal Article] Linker-dependent chromogenic control of the emission of polymethylene-vaulted trans-bis(salicylaldiminato)platinum(II) complexes (2015)
  • Author(s): Naruyoshi Komiya, Minoru Okada, Ngoc Ha-Thu Le, Soichiro Kawamorita, and Takeshi Naota
  • Journal Title: Journal of Luminescence Volume: 161 Pages: 363-367
  • DOI: 10.1016/j.jlumin.2015.01.015
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Flavin-Functionalized Gold Nanoparticles as an Efficient Catalyst for Aerobic Organic Transformations (2015)
  • Author(s): Yasushi Imada, Motonari Ohsaki, Mikiko Noguchi, Takatoshi Maeda, Misa Fujiki, Soichiro Kawamorita, Naruyoshi Komiya, and Takeshi Naota
  • Journal Title: Chem. Cat. Chem. Volume: 7 Issue: 1 Pages: 99-106
  • DOI: 10.1002/cctc.201402619
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ring-expanding metathesis oligomerization of cyclic nitrones (2014)
  • Author(s): Yasushi Imada, Chiaki Okita, Hiroki Maeda, Masayuki Kishimoto, Yoshinori Sugano, Hiroyuki Kaneshiro, Yuri Nishida, Soichiro Kawamorita, Naruyoshi Komiya, and Takeshi Naota
  • Journal Title: European Journal of Organic Chemistry Volume: nothing Issue: 26 Pages: 5670-5674
  • DOI: 10.1002/ejoc.201402859
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] パラジウム触媒を用いた含フッ素燐光性イリジウム錯体への位置選択的アリール化反応 (2015)
  • Author(s): 齊藤駿介, 川守田創一郎, 直田 健
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] アルキルアミドリンカーを有する洗濯ばさみ型パラジウム 2 核錯体の合成と開閉運動の遠隔制御 (2014)
  • Author(s): 井上 僚, 川守田創一郎, 直田 健
  • Organizer: 第4回 CSJ化学フェスタ 2014
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14 – 2014-10-16
• [Presentation] アルキルアミドリンカーを有する洗濯ばさみ型パラジウム 2 核錯体の合成と開閉運動の遠隔制御 (2014)
  • Author(s): 井上 僚, 川守田創一郎, 直田 健
  • Organizer: 第64回錯体化学討論会
  • Place of Presentation: 中央大学
  • Year and Date: 2014-09-18 – 2014-09-20
• [Presentation] アロキサン部位を有する新規フラビンの合成と発光特性 (2014)
  • Author(s): 川守田創一郎, 鈴木陽加, 小宮成義, 今田泰嗣, 直田 健
  • Organizer: 第44回複素環化学討論会
  • Place of Presentation: 札幌市民ホール
  • Year and Date: 2014-09-10 – 2014-09-12
• [Presentation] リンカーにアミド部位を有する洗濯バサミ型パラジウム２核錯体の開発と開閉運動制御 (2014)
  • Author(s): 川守田創一郎, 井上 僚, 直田 健
  • Organizer: 第34回有機合成若手セミナー
  • Place of Presentation: 大阪大学
  • Year and Date: 2014-08-05