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Design of Next-Generation Organocatalysts for the Application to Practical, Fine Organic Synthesis

Research Project

Project/Area Number 26220803
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionKyoto University

Principal Investigator

MARUOKA Keiji  京都大学, 薬学研究科, 研究員(特任教授) (20135304)

Co-Investigator(Kenkyū-buntansha) 加納 太一  京都大学, 理学研究科, 准教授 (40372560)
橋本 卓也  京都大学, 理学研究科, 助教 (20437198)
Project Period (FY) 2014-05-30 – 2019-03-31
Project Status Completed (Fiscal Year 2019)
Budget Amount *help
¥195,000,000 (Direct Cost: ¥150,000,000、Indirect Cost: ¥45,000,000)
Fiscal Year 2018: ¥39,000,000 (Direct Cost: ¥30,000,000、Indirect Cost: ¥9,000,000)
Fiscal Year 2017: ¥39,000,000 (Direct Cost: ¥30,000,000、Indirect Cost: ¥9,000,000)
Fiscal Year 2016: ¥39,000,000 (Direct Cost: ¥30,000,000、Indirect Cost: ¥9,000,000)
Fiscal Year 2015: ¥39,000,000 (Direct Cost: ¥30,000,000、Indirect Cost: ¥9,000,000)
Fiscal Year 2014: ¥39,000,000 (Direct Cost: ¥30,000,000、Indirect Cost: ¥9,000,000)
Keywords高性能有機触媒 / 精密有機合成 / 塩基触媒 / 酸触媒 / 酸塩基複合触媒 / ラジカル触媒 / 環境調和型 / 不斉変換反応 / 次世代型有機触媒 / 有機塩基触媒 / 脱芳香族化反応 / 不斉共役付加反応 / 有機酸塩基触媒 / 有機ラジカル触媒 / NHBI触媒 / アシル化反応 / 有機触媒 / 脱金属触媒 / 次世代型触媒 / ベンゾイロキシ化反応 / 共役付加反応 / 有機ラジカル / ジフルオロメチル化剤 / キラル相間移動触媒 / 二官能性触媒 / ラクトン化反応 / 有機分子触媒 / 精密有機合成反応 / 不斉アルドール反応 / オキシインドール / アシルラジカル / 有機酸職場
Outline of Final Research Achievements

The rational design of high-performance organocatalysts has been performed in the research project, which is divided into four main research items consisting of high-performance base organocatalysts, acid organocatalysts, combined acid-base organocatalysts and radical organocatalysts. By using such high-performance organocatalysts, we succeeded to develop various new synthetic methodologies including environmentally benign and asymmetric organic transformations. In particular, we focused on the design and synthesis of organoradical catalysts and the application to new organoradical reactions, since the development of this area has been significantly delayed. Considering the diversity and the speed of research is extremely important due to the rapidly developing fields around the world, the research areas were divided into several groups, which certainly produced more effective results by maximizing the advantages of the Japanese small group system compared to the Western style system.

Academic Significance and Societal Importance of the Research Achievements

有機分子触媒は、従来の生体触媒や金属触媒に加え、第三の触媒として、その化学安定性・環境調和性ゆえに近年、注目を集めている。この分野において、次世代型有機分子触媒を創製できれば、従来の生体触媒や金属触媒では及びもつかないような反応性や選択性の獲得が可能になるであろう。とくに、これまで著しく発展の遅れていた有機ラジカル化学の分野を大幅に発展させる意義は大きい。各種の新規な次世代型有機分子触媒の誕生によって、従来、合成が難しいと考えられていた新規有機化合物の創製へとつながり、学術のみならず、産学界における関連研究の諸分野の発展に大きな波及効果をもたらすと考えられる。

Assessment Rating
Verification Result (Rating)

A

Assessment Rating
Result (Rating)

A: Progress in the research is steadily towards the initial goal. Expected research results are expected.

Report

(10 results)
  • 2020 Research Progress Assessment (Verification Result) ( PDF )
  • 2019 Final Research Report ( PDF )
  • 2018 Annual Research Report
  • 2017 Annual Research Report   Abstract(Research Progress Assessment) ( PDF )   Research Progress Assessment (Result) ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Abstract ( PDF )   Annual Research Report
  • Research Products

    (116 results)

All 2020 2019 2018 2017 2016 2015 2014 Other

All Journal Article (61 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 61 results,  Open Access: 1 results,  Acknowledgement Compliant: 14 results) Presentation (52 results) (of which Int'l Joint Research: 25 results,  Invited: 52 results) Remarks (3 results)

  • [Journal Article] Construction of a Quaternary Carbon Center by Catalytic Asymmetric Alkylation of 3-Arylpiperidin-2-ones under Phase-Transfer Conditions2020

    • Author(s)
      T. Inukai, T. Kano, and K. Maruoka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 59 Issue: 6 Pages: 2211-2214

    • DOI

      10.1002/anie.201913518

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of New Amino Tf- Amide Organocatalysts: Environmentally Benign Approach to Asymmetric Aldol Synthesis2019

    • Author(s)
      H.-J. Lee, N. Arumugam, A. I. Almansour, R. S. Kumar, and K. Maruoka
    • Journal Title

      Synlett

      Volume: 30 Issue: 04 Pages: 401-404

    • DOI

      10.1055/s-0037-1610408

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Asymmetric Synthesis of α-Amino Acids by Organocatalytic Biomimetic Transamination2019

    • Author(s)
      Q.-K. Kang, S. Selvakumar, and K. Maruoka
    • Journal Title

      Org. Lett.

      Volume: 21 Issue: 7 Pages: 2294-2297

    • DOI

      10.1021/acs.orglett.9b00588

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of Chiral 1,4-Enynes through Organocatalytic Alkenylation of Propargyl Alcohols with Trialkenylboroxines2019

    • Author(s)
      J.-F. Bai, K. Yasumoto, T. Kano, and K. Maruoka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 58 Issue: 26 Pages: 8898-8901

    • DOI

      10.1002/anie.201904520

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Scalable Synthesis of a Chiral Selenium π-Acid Catalyst and Its Use in Enantioselective Iminolactonization of β,γ-Unsaturated Amides2019

    • Author(s)
      Y. Otsuka, Y. Shimazaki, H. Nagaoka, K. Maruoka, and T. Hashimoto
    • Journal Title

      Synlett

      Volume: 30 Issue: 14 Pages: 1679-1682

    • DOI

      10.1055/s-0039-1690109

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Phenylcyclopropane-Based Secondary Amine Catalysts and Their Applications in Enamine Catalysis2019

    • Author(s)
      A. Takeshima, T. Kano, and K. Maruoka
    • Journal Title

      Org. Lett.

      Volume: 21 Issue: 19 Pages: 8071-8074

    • DOI

      10.1021/acs.orglett.9b03070

    • NAID

      120006731151

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Indanol-based Chiral Organoiodine Catalyst for Enantioselective Hydrative Dearomatization2018

    • Author(s)
      Hashimoto Takuya、Shimazaki Yuto、Omatsu Yamato、Maruoka Keiji
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 印刷中 Issue: 24 Pages: 7200-7204

    • DOI

      10.1002/anie.201803889

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase-transfer-catalysed Asymmetric Synthesis of 2,2-Disubstituted 1,4-Benzoxazin-3-ones2018

    • Author(s)
      M. Pawliczek, Y. Shimazaki, H. Kimura, K.M. Oberg, S. Zakpur, T. Hashimoto, and K. Maruoka
    • Journal Title

      Chem. Commun.

      Volume: 54 Issue: 51 Pages: 7078-7080

    • DOI

      10.1039/c8cc03635g

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enantioselective Alkylation of N-Arylhydrazones Derived from α-Keto Esters and Isatin Derivatives through Asymmetric Phase-Transfer Catalysis2018

    • Author(s)
      Q.-K. Kang, S. Selvakumar, N. Arumugam, A. I. Almansour, R. S. Kumar and K. Maruoka
    • Journal Title

      Chem. Asian J.

      Volume: 13 Issue: 14 Pages: 1780-1783

    • DOI

      10.1002/asia.201800652

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of 1-Aminoindenes through Aza-Prins-Type Cyclization2018

    • Author(s)
      J.-F. Bai, K. Yasumoto, T. Kano, and K. Maruoka
    • Journal Title

      Chemistry;Eur. J.

      Volume: 24 Issue: 41 Pages: 10320-10323

    • DOI

      10.1002/chem.201802448

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Radical Acylarylation of N-Arylacrylamides with Aliphatic Aldehydes Using the Photolysis of Hypervalent Iodine(III) Reagents2018

    • Author(s)
      R. Sakamoto, N. Hirama, and K. Maruoka,
    • Journal Title

      Org. Biomol. Chem.

      Volume: 16 Issue: 30 Pages: 5412-5415

    • DOI

      10.1039/c8ob01420e

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Synthesis of Four Different Pseudoenantiomeric Organocatalysts with both cis- and trans-Substituted 1,2-cis-Cyclohexanediamine Structures from a Common Intermediate2018

    • Author(s)
      H.-J. Lee, N. Arumugam, A. I. Almansour, R. S. Kumar, and K. Maruoka
    • Journal Title

      Tetrahedron

      Volume: 74 Issue: 38 Pages: 5263-5269

    • DOI

      10.1016/j.tet.2018.05.035

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of Efficient Chiral Bifunctional Phase-Transfer Catalysts Possessing an Amino Functionality for Asymmetric Aminations2018

    • Author(s)
      Paria Suva、Kang Qi-Kai、Hatanaka Miho、Maruoka Keiji
    • Journal Title

      ACS Catalysis

      Volume: 9 Issue: 1 Pages: 78-82

    • DOI

      10.1021/acscatal.8b03292

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Copper- Catalyzed C(sp) - C(sp3) Coupling of Terminal Alkynes with Alkylsilyl Peroxides via a Radical Mechanism2018

    • Author(s)
      R. Sakamoto, T. Kato, and K. Maruoka
    • Journal Title

      Org. Lett.

      Volume: 20 Issue: 5 Pages: 1400-1403

    • DOI

      10.1021/acs.orglett.8b00173

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alkylative kinetic resolution of vicinal diols under phase-transfer conditions: a chiral ammonium borinate catalysis2018

    • Author(s)
      Pawliczek Martin、Hashimoto Takuya、Maruoka Keiji
    • Journal Title

      Chemical Science

      Volume: 9 Issue: 5 Pages: 1231-1235

    • DOI

      10.1039/c7sc04854h

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Amine-Catalyzed Asymmetric Conjugate Addition of Aldehydes to α-Phenylselenoenones as Formal Z-Allylating Agents2018

    • Author(s)
      T. Kano, H. Maruyama, C. Homma, and K. Maruoka
    • Journal Title

      Chem. Commun.

      Volume: 54 Issue: 2 Pages: 176-179

    • DOI

      10.1039/c7cc08691a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric Synthesis of Less Accessible a-Tertiary Amines from Alkynyl Z-Ketimines2017

    • Author(s)
      Taichi Kano, Yusuke Aota, Keiji Maruoka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 51 Pages: 16293-16296

    • DOI

      10.1002/anie.201710084

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Chiral Tritylpyrrolidine Derivatives and Their Application to Asymmetric Benzoyloxylation2017

    • Author(s)
      Mio Shimogaki, Hiroki Maruyama, Shingo Tsuji, Chihiro Homma, Taichi Kano, Keiji Maruoka
    • Journal Title

      The Journal of Organic Chemistry

      Volume: 82 Issue: 23 Pages: 12928-12932

    • DOI

      10.1021/acs.joc.7b02562

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Design of Environmentally-Benign, High-Performance Organocatalysts for Asymmetric Catalysis2017

    • Author(s)
      R. Sakamoto and K. Maruoka
    • Journal Title

      J. Synth. Org. Chem., Jpn.

      Volume: 75 Pages: 1141-1149

    • NAID

      130006196252

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] The Direct C- H Difluoromethylation of Heteroarenes Based on the Photolysis of Hypervalent Iodine(III) Reagents That Contain Difluoroacetoxy Ligands2017

    • Author(s)
      R. Sakamoto, H. Kashiwagi, and K. Maruoka,
    • Journal Title

      Org. Lett.

      Volume: 19 Issue: 19 Pages: 5126-5129

    • DOI

      10.1021/acs.orglett.7b02416

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hypervalent Iodine(III) Catalyzed Radical Hydroacylation of Chiral Alkylidenemalonates with Aliphatic Aldehydes under Photolysis2017

    • Author(s)
      S. Selvakumar, Q.-K. Kang, N. Arumugam, A. I. Almansour, R. S. Kumar, K. Maruoka
    • Journal Title

      Tetrahedron

      Volume: 73 Issue: 40 Pages: 5841-5846

    • DOI

      10.1016/j.tet.2017.08.018

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Synthesis of Both Enantiomeric Amino Acid, Mannich, and Aldol Derivatives by Asymmetric Organocatalysis2017

    • Author(s)
      Y. Liu, N. Arumugam, A. I. Almansour, R. S. Kumar, and K. Maruoka
    • Journal Title

      Chem. Rec.

      Volume: 17 Issue: 10 Pages: 1059-1069

    • DOI

      10.1002/tcr.201700008

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Synthesis of Two Different Pseudoenantiomeric Organocatalysts with cis-Cyclohexanediamine Structure from a Common Chiral Source2017

    • Author(s)
      H.-J. Lee, S. A. Moteki, N. Arumugam, A. I. Almansour, R. S. Kumar, Y. Liu, and K. Maruoka
    • Journal Title

      Asian J. Org. Chem.

      Volume: 6 Issue: 9 Pages: 1226-1230

    • DOI

      10.1002/ajoc.201700229

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalyst-Controlled, Enantioselective, and Diastereodivergent Conjugate Addition of Aldehydes to Electron-Deficient Olefins2017

    • Author(s)
      S. B. Jennifer Kan, Hiroki Maruyama, Matsujiro Akakura, Taichi Kano, Keiji Maruoka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 56 Issue: 32 Pages: 9487-9491

    • DOI

      10.1002/anie.201705546

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ generation of N-Boc-protected alkenyl imines: controlling the E/Z geometry of alkenyl moieties in the Mukaiyama-Mannich reaction2017

    • Author(s)
      Bai Jian-Fei、Sasagawa Hajime、Yurino Taiga、Kano Taichi、Maruoka Keiji
    • Journal Title

      Chemical Communications

      Volume: 53 Issue: 58 Pages: 8203-8206

    • DOI

      10.1039/c7cc04674j

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Alkylsilyl Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides and Arylamines2017

    • Author(s)
      R. Sakamoto, S. Sakurai, and K. Maruoka,
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Issue: 38 Pages: 9030-9033

    • DOI

      10.1002/chem.201702217

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis(trialkylsilyl) Peroxides as Alkylating Agents in the Copper-Catalyzed Selective Mono-N-Alkylation of Primary Amides2017

    • Author(s)
      R. Sakamoto, S. Sakurai, and K. Maruoka
    • Journal Title

      Chem. Commun.

      Volume: 53 Issue: 48 Pages: 6484-6487

    • DOI

      10.1039/c7cc02910a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ generation of less accessible Boc-imines from aldehydes: construction of a quaternary carbon by the Mannich reaction or unprecedented aldol reaction2017

    • Author(s)
      Taichi Kano, Chihiro Homma, Keiji Maruoka
    • Journal Title

      Organic & Biomolecular Chemistry

      Volume: 15 Issue: 21 Pages: 4527-4530

    • DOI

      10.1039/c7ob01126a

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase-transfer catalyzed asymmetric synthesis of α,β-unsaturated γ,γ-disubstituted γ-lactams2017

    • Author(s)
      A. Arlt, H. Toyama, K. Takada, T. Hashimoto, and K. Maruoka
    • Journal Title

      Chem.Commun.

      Volume: 53 Issue: 35 Pages: 4779-4782

    • DOI

      10.1039/c7cc01058c

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Chiral Tertiary Sulfonium Salts as Effective Catalysts for Asymmetric Base-Free Neutral Phase-Transfer Reactions2017

    • Author(s)
      Shiyao Liu, Keiji Maruoka, Seiji Shirakawa
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 56 Issue: 17 Pages: 4819-4823

    • DOI

      10.1002/anie.201612328

    • NAID

      120006987514

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 2Efficient Photolytic C-H bond Functionalization of Alkylbenzene with Hypervalent Iodine(III) Reagent.2016

    • Author(s)
      R. Sakamoto, T. Inada, S. Selvakumar, S. A. Moteki, K. Maruoka
    • Journal Title

      Chem. Commun.

      Volume: 52 Issue: 19 Pages: 3758-3761

    • DOI

      10.1039/c5cc07647a

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Chiral Electrophilic Selenium Catalyst for Highly Enantioselective Oxidative Cyclization2016

    • Author(s)
      Yu Kawamata, Takuya Hashimoto, Keiji Maruoka
    • Journal Title

      Journal of the American Chemical Society

      Volume: n/a Issue: 16 Pages: 5206-5209

    • DOI

      10.1021/jacs.6b01462

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Diastereoselective Radical Hydroacylation of Alkylidenemalonates with Aliphatic Aldehydes Initiated by Photolysis of Hypervalent Iodine(III) Reagents2016

    • Author(s)
      S. Selmadurai, R. Sakamoto, and K. Maruoka
    • Journal Title

      Chem. Eur. J.

      Volume: 22 Issue: 19 Pages: 6552-6555

    • DOI

      10.1002/chem.201600425

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] N-Boc-aminals as easily accessible precursors for less accessible N-Boc-imines: facile synthesis of optically active propargylamine derivatives using Mannich-type reactions2016

    • Author(s)
      Taiga Yurino, Yusuke Aota, Daisuke Asakawa, Taichi Kano, Keiji Maruoka
    • Journal Title

      Tetrahedron

      Volume: 72 Issue: 26 Pages: 3687-3700

    • DOI

      10.1016/j.tet.2016.03.076

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Efficient Generation of Perfluoroalkyl Radicals from Sodium Perfluoroalkanesulfinates and a Hypervalent Iodine(III) Reagent: Mild, Metal-free Synthesis of Perfluoroalkylated Organic Molecules2016

    • Author(s)
      R. Sakamoto, T. Inada, S. Selmadurai, S. A. Moteki, and K. Maruoka
    • Journal Title

      Org. Biomol. Chem.

      Volume: 14 Issue: 27 Pages: 6417-6421

    • DOI

      10.1039/c6ob01245k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Bulky Thiyl-Radical Catalyst for the [3+2] Cyclization of N-Tosyl Vinylaziridines and Alkenes2016

    • Author(s)
      T. Hashimoto, K. Takino, K. Hato, K. Maruoka
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 28 Pages: 8081-8085

    • DOI

      10.1002/anie.201602723

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogen-Bonding Catalysis of Tetraalkylammonium Salts in an Aza-Diels Alder Reaction2016

    • Author(s)
      Kumatabara, Y.; Kaneko, S.; Nakata, S.; Shirakawa, S.; Maruoka, K.
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 15 Pages: 2126-2129

    • DOI

      10.1002/asia.201600781

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic Asymmetric Synthesis of Axially Chiral 2-Amino-1,10-biaryl Compounds by Phase-transfer-catalyzed Kinetic Resolution and Desymmetrization2016

    • Author(s)
      S. Shirakawa, X. Wu, S. Liu, and K. Maruoka
    • Journal Title

      Tetrahedron

      Volume: 72 Issue: 34 Pages: 5163-5171

    • DOI

      10.1016/j.tet.2015.10.074

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Rate Acceleration of Solid-Liquid Phase-Transfer Catalysis by Rotor-Stator Homogenizer2016

    • Author(s)
      Taichi Kano, Yusuke Aota, Keiji Maruoka
    • Journal Title

      Advanced Synthesis and Catalysis

      Volume: 358 Issue: 18 Pages: 2996-2999

    • DOI

      10.1002/adsc.201600425

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] [2+2] Photocycloadditions between the Carbon-Nitrogen Double Bonds of Imines and Carbon-Carbon Double Bonds2016

    • Author(s)
      R. Sakamoto, T. Inada, S. Sakurai, and K. Maruoka
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 24 Pages: 6252-6255

    • DOI

      10.1021/acs.orglett.6b03003

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design of bifunctional quaternary phosphonium salt catalysts for CO2 fixation reaction with epoxides under mild conditions2016

    • Author(s)
      Liu, S.; Suematsu, N.; Maruoka, K.; Shirakawa, S.
    • Journal Title

      Green Chem.

      Volume: 18 Issue: 17 Pages: 4611-4615

    • DOI

      10.1039/c6gc01630h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis of N‐Boc-Propargylic and Allylic Amines by Reaction of Organomagnesium Reagents with N‐Boc-Aminals and Their Oxidation to N‐Boc-Ketimines2016

    • Author(s)
      加納太一、小林遼平、丸岡啓二
    • Journal Title

      Org. Lett.

      Volume: 18 Issue: 2 Pages: 276-279

    • DOI

      10.1021/acs.orglett.5b03446

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Positive Effect of Water in Asymmetric Direct Aldol Reactions with Primary-Amine Organocatalyst: Experimental and Computational Studies2015

    • Author(s)
      S A. Moteki, K. Nakayama, H.-B. Li, G. Petrova, S. Maeda, K. Morokuma, and K. Maruoka
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 10 Pages: 1-6

    • DOI

      10.1002/asia.201500078

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 11Recent Advances of Catalytic Asymmetric 1,3-Dipolar Cycloadditions2015

    • Author(s)
      T. Hashimoto, K. Maruoka
    • Journal Title

      Chem. Rev.

      Volume: 115 Issue: 11 Pages: 5366-5412

    • DOI

      10.1021/cr5007182

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Regioselectivity Switch in Chiral Amine-catalysed Asymmetric Addition of Aldehydes to Reactive Enals2015

    • Author(s)
      Taichi Kano, Hiroki Maruyama, Ryu Sakamoto, Keiji Maruoka
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 49 Pages: 10062-10065

    • DOI

      10.1039/c5cc02438b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Versatile In Situ Generated N-Boc-Imines: Application to Phase- Transfer-Catalyzed Asymmetric Mannich-Type Reactions2015

    • Author(s)
      加納太一、小林遼平、丸岡啓二
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 29 Pages: 8471-8474

    • DOI

      10.1002/anie.201502215

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Regio- and Stereoselective Conjugate Addition of Aldehydes to β-Tosyl Enones Catalyzed by Binaphthyl-Modified Chiral Amine2015

    • Author(s)
      Taichi Kano, Hisashi Sugimoto, Hiroki Maruyama, Keiji Maruoka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 54 Issue: 29 Pages: 8462-8465

    • DOI

      10.1002/anie.201500225

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanism of Metal-Free C-H Activation of Branched Aldehydes and Acylation of Alkenes Using Hypervalent Iodine Compound: A Theoretical Study2015

    • Author(s)
      Julong Jiang, Romain Ramozzi, Shin Moteki, Asuka Usui, Keiji Maruoka, and Keiji Morokuma
    • Journal Title

      J. Org. Chem.

      Volume: 80 Issue: 18 Pages: 92649271-92649271

    • DOI

      10.1021/acs.joc.5b01695

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Brønsted Acid-catalysed Mannich Reaction Through Dual Activation of Aldehydes and N-Boc-Imines2015

    • Author(s)
      Taichi Kano, Yusuke Aota, Daisuke Asakawa, Keiji Maruoka
    • Journal Title

      Chemical Communications

      Volume: 51 Issue: 92 Pages: 16472-16474

    • DOI

      10.1039/c5cc07290e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tetraalkylammonium Salts as Hydrogen-Bonding Catalysts2015

    • Author(s)
      Shirakawa, S.; Liu, S.; Kaneko, S.; Kumatabara, Y.; Fukuda, A.; Omagari, Y.; Maruoka, K.
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Issue: 52 Pages: 15767-15770

    • DOI

      10.1002/anie.201508659

    • NAID

      120006987196

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 4Boronic Acid-Catalyzed, Highly Enantioselective Aza-Michael Additions of Hydroxamic Acid to Quinone Imine Ketals2015

    • Author(s)
      T. Hashimoto, A. O. Galvez, K. Maruoka
    • Journal Title

      J. Am. Chem. Soc.

      Volume: 137 Issue: 51 Pages: 16016-16019

    • DOI

      10.1021/jacs.5b11518

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Practical Approach for the Oxidation of Unactivated Csp3-H Bonds with o-Nitro(Diacetoxyiodo)Benzene as an Efficient Hypervalent Iodine(III)-Based Oxidizing Agent2014

    • Author(s)
      S.A. Moteki, S. Sermadurai, T. Zhang, A. Usui, K. Maruoka
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 3 Issue: 9 Pages: 932-935

    • DOI

      10.1002/ajoc.201402087

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metal-Free C[n.63743]H Bond Activation of Branched Aldehydes with Hypervalent Iodine(III) Catalyst under Visible-Light Photolysis : Successful Trapping with Electron-Deficient Olefins2014

    • Author(s)
      S.A. Moteki, A. Usui, S. Sermadurai, T. Zhang, K. Maruoka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 41 Pages: 11060-11064

    • DOI

      10.1002/anie.201406513

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] An Organic Thiyl Radical Catalysed Enantioselective Cyclization.2014

    • Author(s)
      Takuya Hashimoto, Yu Kawamata, Keiji Maruoka
    • Journal Title

      Nature Chemistry

      Volume: 6 Issue: 8 Pages: 702-705

    • DOI

      10.1038/nchem.1998

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Effect of Bronsted Acid Co-Catalyst in Asymmetric Conjugate Addition of 3-Aryloxindoles to Maleimide under Base-Free Phase-Transfer Conditions2014

    • Author(s)
      S. Shirakawa, H. Makino, T. Yoshidome, K. Maruoka
    • Journal Title

      Tetrahedron

      Volume: 70 Issue: 40 Pages: 7128-7132

    • DOI

      10.1016/j.tet.2014.06.017

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Asymmetric phase-transfer reactions under base-free neutral conditions2014

    • Author(s)
      Seiji Shirakawa, Keiji Maruoka
    • Journal Title

      Tetrahedron Lett.

      Volume: 55 Issue: 29 Pages: 3833-3839

    • DOI

      10.1016/j.tetlet.2014.05.014

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic Asymmetric Synthesis of 3,3'-Diaryloxindoles as Triarylmethanes with a Chiral All-Carbon Quaternary Center : Phase-Transfer-Catalyzed SNAr Reaction2014

    • Author(s)
      S. Shirakawa, K. Koga, T. Tokuda, K. Yamamoto, K. Maruoka
    • Journal Title

      Angewandte Chemie International Edition

      Volume: 53 Issue: 24 Pages: 6220-6223

    • DOI

      10.1002/anie.201403046

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase-Transfer-Catalyzed Asymmetric α-Arylation of α-Amino Acid Derivatives2014

    • Author(s)
      S. Shirakawa, K. Yamamoto, T. Tokuda, K. Maruoka
    • Journal Title

      Asian Journal of Organic Chemistry

      Volume: 3 Issue: 4 Pages: 433-436

    • DOI

      10.1002/ajoc.201400004

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Base-Free Neutral Phase-Transfer Reaction System2014

    • Author(s)
      S. Shirakawa, L. Wang, R. He, S. Arimitsu, K. Maruoka
    • Journal Title

      Chemistry Asian Journal

      Volume: 9 Issue: 6 Pages: 1586-1593

    • DOI

      10.1002/asia.201402194

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Practical Approach for Asymmetric Hydroxyamination of Aldehydes with in Situ Generated Nitrosocarbonyl Compounds: Application to One-Pot Synthesis of Chiral Allylamines2014

    • Author(s)
      T. Kano, F. Shirozu, K. Maruoka
    • Journal Title

      Organic Letters

      Volume: 16 Issue: 5 Pages: 1530-1532

    • DOI

      10.1021/ol5000742

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Amine-Catalyzed Asymmetric Cross-Aldol Reactions Using Heterofunctionalized Acetaldehydes as Nucleophiles2014

    • Author(s)
      T. Kano, R. Sakamoto, K. Maruoka
    • Journal Title

      Organic Letters

      Volume: 16 Issue: 3 Pages: 944-947

    • DOI

      10.1021/ol4036837

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] New Radical Reactions in Selective Organic Synthesis2019

    • Author(s)
      丸岡啓二
    • Organizer
      Chemical Records Lecture 2019
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] ラジカル化学の新展開:アシルラジカルを活用する精密有機合成2019

    • Author(s)
      丸岡啓二
    • Organizer
      日本薬学会北陸支部特別講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Design of Chiral High-Performance Organocatalysts for Asymmetric Catalysis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      Symposium on Molecular Chirality 2019
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of New, High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      31st International Symposium on Chirality
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      2019 Designing Molecules Workshop and Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機ラジカル触媒で何ができるか?新規有機ラジカル触媒の創製と活用2019

    • Author(s)
      丸岡啓二
    • Organizer
      有機合成夏期セミナー「明日の有機合成化学」
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Design of New, High-Performance Organoradical Catalysts for Selective Organic Synthesis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      The 8th Japanese-Sino Symposium on Organic Chemistry for Young Scientists
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] ラジカル種を活用する精密有機合成2019

    • Author(s)
      丸岡啓二
    • Organizer
      第30回日本プロセス化学会東四国地区フォーラムセミナー
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Design of Organoradical Catalysts for Selective Organic Synthesis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      Israel-Japan Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Selective Organic Synthesis2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      The 19th Tateshina Conference
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Practical Synthesis of Artificial Amino Acids and Peptides2019

    • Author(s)
      Keiji Maruoka
    • Organizer
      5th International Symposium on Middle Molecular Strategy (ISMMS)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Advantage of Chiral Amino Organocatalysts over Proline in Asymmetric Enamine Catalysis: A Good Harmony with Water2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      The Second Japanese-Spanish Symposium on Organic Synthesis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Indanol-Based Chiral Organoiodine Catalyst for Enantioselective Hydrative Dearomatization2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      The 6th International Conference on Hypervalent Iodine Chemistry
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Asymmetric Phase-Transfer Catalysis: Basic Design of Maruoka Catalyst; and the Industrial Application2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      Boehringer-Ingelheim Lectureship
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Asymmetric Enamine Catalysis with Nitroso and Related Compounds Catalyzed by High-Performance Organocatalysts2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      The Organic Chemistry Day in Pavia
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 環境調和型有機分子触媒の創製と精密有機合成への応用2018

    • Author(s)
      丸岡啓二
    • Organizer
      第49回中部化学関係学協会支部連合秋季大会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] Design of New, High-Performance Organoradical Catalysts with Privileged Structures for Asymmetric Catalysis2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      The 13th International Symposium on Organic Reactions (ISOR-13)
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of New, High-Performance Organoradical Catalysts with Privileged Structures for Asymmetric Catalysis2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      6th Japan-UK Symposium on Asymmetric Synthesis
    • Related Report
      2018 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2018

    • Author(s)
      Keiji Maruoka
    • Organizer
      Departmental Organic Seminar, University of Alicante
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      Spanish-Japanese Symposium on Modern Synthetic Methodology, University of Oviedo
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Strategy of Generating Acyl Radicals for Organic Synthesis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      2nd International Conference on Hydrogen Atom Transfer (iCHAT 2017), The University of Rome Tor Vergata
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      4th Elemento-Organic Chemistry Symposium - Asymmetric Synthesis: The Methods and Applications , Nankai University
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Strategy of Generating Carbon Radicals for Organic Synthesis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      8th Pacific Symposium on Radical Chemistry, Queensland University of Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts for Catalytic Asymmetric Synthesis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      Second International Conference on Organic Chemistry at GDUT, Guangdong University of Technology
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Practical Synthesis of Four Different, Bifunctional Organocatalysts for Asymmetric Catalysis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      Singapore Japan Germany Trilateral Symposium on Precision Synthesis & Catalysis, Nanyang Technological University
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高性能有機触媒を活用する触媒的不斉合成の最前線2017

    • Author(s)
      丸岡啓二
    • Organizer
      特別講演会、岡山大学
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] Design of High-Performance Organocatalysts for Catalytic Asymmetric Synthesis2017

    • Author(s)
      Keiji Maruoka
    • Organizer
      8th International Collaborative and Cooperative Chemistry Symposium (8th ICCCS), University of Hyderabad
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] キラル高性能有機触媒の創製と触媒的不斉合成への応用2017

    • Author(s)
      丸岡啓二
    • Organizer
      2016年度高砂香料国際賞「野依賞」受賞講演、如水会館
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 高性能有機触媒の触媒設計と実用化を目指して2017

    • Author(s)
      丸岡啓二
    • Organizer
      日本薬学会137年会特別講演、東北大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] In-Situ Generation and Synthetic Utilityof Less Accessible or Unprecedented N-Boc-Imines2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      5th UK Japan Symposium on Asymmetric Catalysis
    • Place of Presentation
      The University of Manchester, Manchester, UK
    • Year and Date
      2016-03-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機触媒化学分野は何処へ行くのか?2016

    • Author(s)
      丸岡 啓二
    • Organizer
      「有機分子触媒による未来型分子変換」第6回公開シンポジウム
    • Place of Presentation
      大阪科学技術センター、大阪
    • Year and Date
      2016-01-22
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Design of High-Performance Organocatalysts for Practical Asymmetric Catalysis2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      Agora Bayer Lecture, Kyoto University
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 有機触媒化学の最前線2016

    • Author(s)
      丸岡啓二
    • Organizer
      日本化学会近畿支部 2016年研究最前線講演会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Asymmetric Phase Transfer Catalysis: Basic Design of Maruoka Catalyst and the Industrial Application2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      Andrews Lectureship-1, University of New South Wales
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Design of Bifunctional Organocatalysts by Experimental and Computational Studies2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      Andrews Lectureship-2, University of New South Wales
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] New Organoradical Chemistry: Rational Design of New Organoradical Catalysts2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      Andrews Lectureship-3, University of New South Wales
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 有機触媒化学の最前線2016

    • Author(s)
      丸岡啓二
    • Organizer
      第48回有機合成セミナー、大阪市立工業研究所
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 有機触媒化学の新たな展開2016

    • Author(s)
      丸岡啓二
    • Organizer
      物質生命理工学科コロキウム、上智大学
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      2016 International Conference on New Challenges in Organic Synthesis, Guangdong University of Technology
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Design of High-Performance Organocatalysts with Privileged Structures for Asymmetric Catalysis2016

    • Author(s)
      Keiji Maruoka
    • Organizer
      7th International Collaborative and Cooperative Chemistry Symposium (7th ICCCS), Peking University
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機触媒化学の新展開2016

    • Author(s)
      丸岡啓二
    • Organizer
      高選択性反応分科会講演会、新化学技術推進協会
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 環境調和型有機分子触媒反応の開発2015

    • Author(s)
      丸岡 啓二
    • Organizer
      日本薬学会第40回学術講演会
    • Place of Presentation
      長井記念ホール、東京
    • Year and Date
      2015-12-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Design of New Organoradical Catalysts for Selective C-H Activation and Asymmetric Cyclization2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      PACIFICHEM2015
    • Place of Presentation
      Honolulu, U. S. A.
    • Year and Date
      2015-12-17
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Synthetic Utility of In-Situ Generated Reactive Imines for Asymmetric Catalysis2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      International Symposium on Organic Synthesis
    • Place of Presentation
      Guangdong University of Technology, Guangzhou, China
    • Year and Date
      2015-11-27
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] In-Situ Generation and Synthetic Utilityof Less Accessible or Unprecedented N-Boc-Imines2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      6th International Collaborative and Cooperative Chemistry Symposium (6th ICCCS)
    • Place of Presentation
      Seoul National University, Seoul, Korea
    • Year and Date
      2015-11-16
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New Interaction of Asymmetric Organocatalysis with Theoretical Chemistry2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      Departmental Seminor
    • Place of Presentation
      Shanghai Jiao Tong University, Shanghai, China
    • Year and Date
      2015-10-26
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Synthetic Utility of In-Situ Generated Reactive Imines for Asymmetric Catalysis2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      Roche Innovation Center
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] Design of High-Performance Organocatalysts for Asymmetric Catalysis2015

    • Author(s)
      Keiji Maruoka
    • Organizer
      17th National Symposium in Chemistry (NSC-17)
    • Place of Presentation
      Pune, India
    • Year and Date
      2015-02-06 – 2015-02-08
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Challenge in Organocatalytic Chemistry: Design of New Organoradical Catalysts and their Application2014

    • Author(s)
      Keiji Maruoka
    • Organizer
      Science Forum on Catalysis, 4th CSJ Chemistry Festa
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2014-10-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Challenge in Organocatalytic Chemistry: Design of Organoradical Catalysts for Selective C-H Activation2014

    • Author(s)
      Keiji Maruoka
    • Organizer
      5th International Collaborative and Cooperative Chemistry Symposium (ICCCS-5)
    • Place of Presentation
      Kyoto, Japan
    • Year and Date
      2014-09-29 – 2014-09-30
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Design of New Organoradical Reagents for Selective C-H Activation and Asymmetric Cyclization2014

    • Author(s)
      Keiji Maruoka
    • Organizer
      The 14th International Symposium on Advancing the Chemical Sciences (ISACS-14)
    • Place of Presentation
      Shanghai, China
    • Year and Date
      2014-08-07 – 2014-08-10
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] New Challenge on Organocatalytic Chemistry: Synthesis of Organoradical Catalysts and the Application2014

    • Author(s)
      Keiji Maruoka
    • Organizer
      Department of Applied Chemistry, Nagoya University
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2014-06-13
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Remarks] 基盤研究(S)次世代型有機分子触媒の創製と実践的精密有機合成への応用

    • URL

      http://kuchem.kyoto-u.ac.jp/yugo/orgcat/index.html

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
  • [Remarks] 基盤研究(S)「次世代型有機分子触媒の創製と実践的精密有機合成への応用」

    • URL

      http://kuchem.kyoto-u.ac.jp/yugo/orgcat/index.html

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
  • [Remarks] 京都大学大学院理学研究科化学専攻有機合成化学研究室

    • URL

      http://kuchem.kyoto-u.ac.jp/yugo/

    • Related Report
      2014 Annual Research Report

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Published: 2014-06-05   Modified: 2023-03-23  

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