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Atomic level and in-situ observation of battery-related materials by environmental high-voltage electron microscopy

Research Project

Project/Area Number 26246006
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials engineering
Research InstitutionNagoya University

Principal Investigator

Tanaka Nobuo  名古屋大学, 未来材料・システム研究所, 研究員 (40126876)

Co-Investigator(Kenkyū-buntansha) 菊田 浩一  名古屋大学, 工学研究科, 教授 (00214742)
武藤 俊介  名古屋大学, 未来材料・システム研究所, 教授 (20209985)
齋藤 晃  名古屋大学, 未来材料・システム研究所, 教授 (50292280)
Research Collaborator 荒井 重勇  名古屋大学, 未来材料システム研究所, 特任准教授
吉田 要  日本ファインセラミクスセンター, 研究員
Project Period (FY) 2014-06-27 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,120,000 (Direct Cost: ¥32,400,000、Indirect Cost: ¥9,720,000)
Fiscal Year 2017: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2016: ¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2015: ¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Fiscal Year 2014: ¥22,880,000 (Direct Cost: ¥17,600,000、Indirect Cost: ¥5,280,000)
Keywords環境電子顕微鏡 / 電池材料解析 / 非大気露出試料転送 / その場観察 / ナノマイクロ構造解析・評価・試験法 / リチウム電池 / ナノマイクロ構造評価 / その場電顕観察 / 非大気露出
Outline of Final Research Achievements

In the present study, using an environmental high-voltage electron microscope, (1)lithium-related materials were studied under non-exposue-in-air conditions, (2)In-situ observations were performed with heating, applied voltages and various atomspheres in order to study degradation processes of the materials, and (3)various kinds of battery-related compounds were studied by STEM-electron energy loss spectroscopy for analysis of elemental distribution, and nano-probe electron diffraction mapping for study of local strain around interfaces of multi-layered structures.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (26 results)

All 2018 2017 2016 2015 2014

All Journal Article (13 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 13 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (9 results) (of which Int'l Joint Research: 7 results,  Invited: 7 results) Book (4 results)

  • [Journal Article] Catalytic etching of multi-walled carbon nanotubes controlled by oxygen gas pressure2018

    • Author(s)
      K. Yoshida, S. Arai, H. Matsumoto, M. Shirai, N. Tanaka
    • Journal Title

      ChemCatChem

      Volume: 10 Pages: 1-6

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Detection of local chemical states of lithium and their spatial mapping by scanning transmission electron microscopy, electron energy-loss spectroscopy and hyperspectral image analysis2017

    • Author(s)
      S. Muto, K. Tatsumi
    • Journal Title

      Microscopy

      Volume: 66 Pages: 39-49

    • DOI

      10.1093/jmicro/dfw038

    • NAID

      120006305588

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Further development of an environmental HVTEM for reaction science by new non-exposure transfer holder2016

    • Author(s)
      N. Tanaka, K. Higuchi, Y. Yamamoto, S. Arai and S. Ohta
    • Journal Title

      Microscopy and Microanalysis 2016

      Volume: なし Pages: 426-426

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an new non-exposure transfer holder for an environmental HVTEM2016

    • Author(s)
      N. Tanaka, K. Higuchi, Y. Yamamoto, S. Arai and S. Ohta
    • Journal Title

      AMTC Letter

      Volume: 5 Pages: 60-61

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Catalytic behavior of noble metal nanoparticles for the hydrogeneration and oxidation of multiwalled carbon nanotubes2016

    • Author(s)
      K. Yoshida, S. Arai, Y. Sasaki and N. Tanaka
    • Journal Title

      Microscopy

      Volume: 65 Issue: 4 Pages: 1-7

    • DOI

      10.1093/jmicro/dfw007

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Graphen Quantum Dots: Structural Integrity and Oxygen Functional Groups for High Sulfur/Sulfide Utilization in Lithium Sulfur Batteries2016

    • Author(s)
      Y.-E. Sung, J. Park, J. Moon, C. Kim, J.-H. Kang, E. Lim, J. Park, K.-J.-Lee, S.-H.- Yu, J.-H. Seo, J. Lee, J. Heo, Tanaka N., S.-P.Cho, J. Pyun, J. Cabana and B.-H. Hong
    • Journal Title

      Nature Asia Materials

      Volume: 8 Pages: 272-281

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Quantitative evaluation of interfacial fracture strength in micro-scale components combined with high-voltage environmental electron microscopy2015

    • Author(s)
      Y. Takahashi, S. Arai, Y. Yamamoto, K. Higuchi, H. Kondo, Y. Kitagawa, S. Muto, N. Tanaka
    • Journal Title

      Experimental Mechanics

      Volume: 未定 Issue: 6 Pages: 1047-1056

    • DOI

      10.1007/s11340-015-0008-2

    • Description
      accepted in printing
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of Si theomoelectric nanomaterials coating ultrasmall epitaxial Ge nanodots with an ultrahigh density2015

    • Author(s)
      S. Yamasaka, Y. Nakamura, T. Ueda, S. Takeuchi, Y. Yamamoto, S. Arai, T. Tanji, N. Tanaka and A. Sakai
    • Journal Title

      J. Electronic Materials

      Volume: 44 Pages: 2015-2020

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Statistical distribution of single atoms and clusters of supported Au catalyst analyzed by global high-resolusion HAADF-STEM observation with morphological image-processing operation2014

    • Author(s)
      Yamamoto, S. Arai, A. Esaki, J. Ohyama, A. Satsuma and N. Tanaka
    • Journal Title

      Microscopy

      Volume: 63 Issue: 3 Pages: 209-218

    • DOI

      10.1093/jmicro/dfu001

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Whole-cell imaging of the budding yeast Saccharomyces cerevisiae by high-voltage scanning transmission electron tomography.2014

    • Author(s)
      Murata, K., Esaki, M., Ogura, T., Arai, S., Yamamoto, Y., and Tanaka, N.
    • Journal Title

      Ultramicroscopy

      Volume: 146 Pages: 39-45

    • DOI

      10.1016/j.ultramic.2014.05.008

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an environmental high voltage electron microscope and its application to nano and bio-materials2014

    • Author(s)
      N. Tanaka, J. Usukura, M. Kusunoki, Y. Saito, K. Sasaki, T. Tanji, S. Muto, S. Arai
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 522 Pages: 012008-012008

    • DOI

      10.1088/1742-6596/522/1/012008

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] ETEM observation of Pt/C electrode catalysts in a moisturized cathode atmosphere2014

    • Author(s)
      K. Yoshida, X. Zhang, N. Tanaka, E. D. Boyes and P. L. Gai
    • Journal Title

      Journal of Physics: Conference Series

      Volume: 522 Pages: 012007-012007

    • DOI

      10.1088/1742-6596/522/1/012007

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Dynamic observation from continuous to well-controlled pulsed electron beam in Nagoya University2014

    • Author(s)
      N. Tanaka, M. Kuwahara, S. Arai, K. Sasaki and N. Tanaka
    • Journal Title

      AMTC Letters

      Volume: 4 Pages: 58-59

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Future prospects of environmental transmission electron microscopy2017

    • Author(s)
      N. Tanaka
    • Organizer
      Nature Conference in Hangzhou
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development and future directions of environmental high-voltage scanning transmission electron microscopy2017

    • Author(s)
      N. Tanaka
    • Organizer
      International Workshop on Advanced and In-situ Microscopies of Functional Nanomaterials and Devices
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Past and future prospects of Cs-corrected TEM for nanomaterials2017

    • Author(s)
      N. Tanaka
    • Organizer
      International Symposium of SALVE project
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Research direction of environmental TEM for nano-materials2016

    • Author(s)
      Nobuo Tanaka
    • Organizer
      11th Asia-Pacific Microscopy Conference
    • Place of Presentation
      Phuket island, Thai
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Further development of an environmental HVTEM for reaction science by new non-exposure transfer holder2016

    • Author(s)
      Nobuo Tanaka
    • Organizer
      Microscopy & Microanalysis 2016 Meeting
    • Place of Presentation
      Columbus, Ohio, U.S.A.
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] TEMとSTEM:私の研究から2015

    • Author(s)
      田中信夫
    • Organizer
      2014年度 超高分解能顕微鏡法分科会 研究会
    • Place of Presentation
      マホロバ・マインズ三浦
    • Year and Date
      2015-02-20 – 2015-02-21
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Prospects high-voltage ETEM by using blanking or pulsed beams2015

    • Author(s)
      N. Tanaka
    • Organizer
      Symposium on Electron Microscopy for Biological, Enviromental and Energy Research
    • Place of Presentation
      PNNL, USA
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dynamic electron microscopic observation of nanomaterials2015

    • Author(s)
      N. Tanaka
    • Organizer
      12th Multinational Congress on Microscopy
    • Place of Presentation
      Eger, Hungary
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] New possibility of ETEM studies of thick samples by HVEM2014

    • Author(s)
      N. Tanaka, T. Fujita, Y. Takahashi and S. Arai
    • Organizer
      18th International Microscopy Congress (IMC 2014)
    • Place of Presentation
      Prague, Czech
    • Year and Date
      2014-09-07 – 2014-09-12
    • Related Report
      2014 Annual Research Report
  • [Book] Electron Nano-imaging2017

    • Author(s)
      N. Tanaka
    • Total Pages
      333
    • Publisher
      Springer
    • ISBN
      9784431565000
    • Related Report
      2017 Annual Research Report
  • [Book] Electron nano-imaging2017

    • Author(s)
      N. Tanaka
    • Total Pages
      333
    • Publisher
      Springer Publishing Company
    • Related Report
      2016 Annual Research Report
  • [Book] Scanning Transmission Electron Microscopy for Nanomaterials2015

    • Author(s)
      N. Tanaka
    • Total Pages
      571
    • Publisher
      Imperial College Press
    • Related Report
      2015 Annual Research Report
  • [Book] Scanning Transmission Electron Microscopy of Nanomaterials: Basics of Imaging and Analysis2014

    • Author(s)
      N. Tanaka
    • Total Pages
      571
    • Publisher
      Imperial College Press
    • Related Report
      2014 Annual Research Report

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Published: 2014-11-20   Modified: 2019-03-29  

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