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Elucidating structure-property relations under mechanical strain in organic semiconductors for device applications

Research Project

Project/Area Number 26246011
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Applied materials
Research InstitutionThe University of Tokyo

Principal Investigator

TAKEYA Junichi  東京大学, 大学院新領域創成科学研究科, 教授 (20371289)

Co-Investigator(Kenkyū-buntansha) 宍戸 厚  東京工業大学, 資源化学研究所, 准教授 (40334536)
大島 義文  北陸先端科学技術大学院大学, マテリアルサイエンス研究科, 准教授 (80272699)
松井 弘之  東京大学, 新領域創成科学研究科, 助教 (80707357)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥41,990,000 (Direct Cost: ¥32,300,000、Indirect Cost: ¥9,690,000)
Fiscal Year 2016: ¥9,750,000 (Direct Cost: ¥7,500,000、Indirect Cost: ¥2,250,000)
Fiscal Year 2015: ¥10,140,000 (Direct Cost: ¥7,800,000、Indirect Cost: ¥2,340,000)
Fiscal Year 2014: ¥22,100,000 (Direct Cost: ¥17,000,000、Indirect Cost: ¥5,100,000)
Keywords高移動度有機半導体 / 単結晶有機薄膜 / 有機トランジスタ / 有機・分子エレクトロニクス / 有機半導体
Outline of Final Research Achievements

We have found that electrical conductivity (mobility) greatly changes with the application of external force to the organic semiconductor crystal, and proved that this phenomenon depends on crystal structure change due to the external force. The detailed correlation between the external stress and the structural property is analyzed by X-ray structural analysis, Hall effect measurement, temperature dependence measurement and calculation of molecular oscillation amplitude. It turned out that the effect is dominantly attributed to reduced molecular vibration rather than t shrinking the intermolecular distance. Based on the obtained physical property, we developed a technology to build a strain sensor with the single-crystal semiconductor films. We found that the sensitivity is more than one-order-of-magnitude higher than conventional devices, indicating definite advantage of the present organic single-crystal strain sensors.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (26 results)

All 2017 2016 2015 2014 Other

All Journal Article (6 results) (of which Int'l Joint Research: 4 results,  Peer Reviewed: 6 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (17 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Strain-Modulated Charge Transport in Flexible PbS Nanocrystal Field-Effect Transistors2017

    • Author(s)
      M. I. Nugraha, H. Matsui, S. Watanabe, T. Kubo, R. Häusermann, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, and J. Takeya
    • Journal Title

      Adv. Electron. Mater

      Volume: 3 Issue: 1 Pages: 1600360-1600360

    • DOI

      10.1002/aelm.201600360

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Suppressing molecular vibrations in organic semiconductors by inducing strain2016

    • Author(s)
      T. Kubo, R. Haeusermann, J. Tsurumi, J. Soeda, Y. Okada, Y. Yamashita, N. Akamatsu, A. Shishido, C. Mitsui, T. Okamoto, S. Yanagisawa, H. Matsui, and J. Takeya
    • Journal Title

      Nature Communications

      Volume: 7 Issue: 1 Pages: 11156-11156

    • DOI

      10.1038/ncomms11156

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Emergence of charge coherence in soft molecular organic semiconductors by suppressing thermal fluctuations2016

    • Author(s)
      K. Sakai, Y. Okada, T. Uemura, J. Tsurumi, R. Hausermann, H. Matsui, T. Fukami, H. Ishii, N. Kobayashi, K. Hirose and J. Takeya
    • Journal Title

      NPG Asia Materials

      Volume: 8 Issue: 3 Pages: 252-252

    • DOI

      10.1038/am.2016.30

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Mobility Exceeding 10 cm2/(Vs) in Donor–Acceptor Polymer Transistors with Band-like Charge Transport2015

    • Author(s)
      Yu Yamashita, Felix Hinkel, Tomasz Marszalek, Wojciech Zajaczkowski, Wojciech Pisula, Martin Baumgarten, Hiroyuki Matsui, Klaus Mullen, and Jun Takeya
    • Journal Title

      Chemistry of Materials

      Volume: 28 Issue: 2 Pages: 420-424

    • DOI

      10.1021/acs.chemmater.5b04567

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Transition Between Band and Hopping Transport in Polymer Field-Effect Transistors2014

    • Author(s)
      Y. Yamashita, J. Tsurumi, F. Hinkel, Y. Okada, J. Soeda, W. Zajaczkowski, M. Baumgarten, W. Pisula, H. Matsui, K. Mullen, J. Takeya
    • Journal Title

      Advanced Materials

      Volume: 26 Issue: 48 Pages: 8169-8173

    • DOI

      10.1002/adma.201403767

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Highly Oriented Polymer Semiconductor Films Compressed at the Surface of Ionic Liquids for High-Performance Polymeric Organic Field-Effect Transistors2014

    • Author(s)
      J. Soeda, H. Matsui, T. Okamoto, I. Osaka, K. Takimiya, and J. Takeya
    • Journal Title

      Advanced Materials

      Volume: 26 Issue: 37 Pages: 6430-6435

    • DOI

      10.1002/adma.201401495

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 有機半導体の分子間相互作用の圧力効果の第一原理計算2016

    • Author(s)
      前田崇博, 石井宏幸, 広瀬賢二, 竹谷純一, 小林伸彦
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学(泉キャンパス)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] 歪み有機単結晶トランジスタの温度依存性とホール効果測定2016

    • Author(s)
      窪孝祥, 鶴見淳人, Roger H usermann, 渡邉峻一郎, 赤松範久, 宍戸厚, 三津井親彦, 岡本敏宏, 柳澤将, 松井弘之, 竹谷純一
    • Organizer
      日本物理学会第71回年次大会
    • Place of Presentation
      東北学院大学(泉キャンパス)
    • Year and Date
      2016-03-21
    • Related Report
      2015 Annual Research Report
  • [Presentation] High-mobility strained organic semiconductor single crystals2016

    • Author(s)
      J. Takeya
    • Organizer
      ICFPE 2016
    • Place of Presentation
      Yamagata Univ. Yamagata, Japan
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A-few-monolayer organic semiconductor crystals and high-performance transistor circuits on plastic substrates2016

    • Author(s)
      C. Mitsui, J. Takeya, A. Yamamura, and M. Uno
    • Organizer
      IMID 2016
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effects of strain in ultra-thin organic semiconductor crystals2016

    • Author(s)
      T. Kubo, C. Mitsui, A. Yamamura, and J. Takeya
    • Organizer
      MRS Fall Meeting 2016
    • Place of Presentation
      Boston, USA
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 有機半導体単結晶の歪み下における低周波ラマン分光2016

    • Author(s)
      鶴見淳人、窪孝祥、石井宏幸、渡邉峻一郎、三津井親彦、岡本敏宏、竹谷純一
    • Organizer
      日本物理学会2016年秋季大会
    • Place of Presentation
      金沢大学(角間キャンパス)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 高分子電界効果トランジスタによる高移動度の実現とその評価の妥当性2016

    • Author(s)
      山下侑、渡邉峻一郎、竹谷純一
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ(新潟市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] Mechanical analysis of soft materials by a surface labeled grating method2015

    • Author(s)
      Atsushi Shishido
    • Organizer
      2015 International Chemical Congress of Pacific Basin Societies (Pacifichem)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Giant effect of structural deformation on high-mobility organic transistors2015

    • Author(s)
      Jun Takeya
    • Organizer
      The 9th International Conference on Advanced Materials and Devices
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Effect of structural deformation on charge transport in organic single-crystal semiconductors2015

    • Author(s)
      Jun Takeya
    • Organizer
      IMID2015, EXCO
    • Place of Presentation
      Daegu, Korea
    • Year and Date
      2015-08-19
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photoinduced molecular alignment control in liquid crystal systems2015

    • Author(s)
      Atsushi Shishido
    • Organizer
      98th Canadian Chemistry Conference (CSC2015),
    • Place of Presentation
      Shaw Centre, Ottawa, Canada
    • Year and Date
      2015-06-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Hall Effect and High Mobility in Highly Aligned Polymer Semiconductors2015

    • Author(s)
      Y. Yamashita, J. Tsurumi, Y. Okada, J. Soeda,
    • Organizer
      8th International Conference on Molecular Electronics and Bioelectronics (M&BE8)
    • Place of Presentation
      Funabori, Japan
    • Year and Date
      2015-06-06
    • Related Report
      2015 Annual Research Report
  • [Presentation] キャリアコヒーレンスに起因する有機半導体移動度のトランスファー積分符号依存性2015

    • Author(s)
      松井 弘之,岡本 敏宏,三津井 親彦,山岸 正和,佐藤 寛泰,山野 昭人,竹谷 純一
    • Organizer
      応用物理学会
    • Place of Presentation
      東海大学(神奈川県平塚市)
    • Year and Date
      2015-03-11 – 2015-03-14
    • Related Report
      2014 Annual Research Report
  • [Presentation] 有機単結晶トランジスタの圧力・歪効果2015

    • Author(s)
      松井 弘之、鶴見 淳人、窪 孝祥、竹谷 純一
    • Organizer
      分子・物質合成プラットフォーム
    • Place of Presentation
      名古屋大学(愛知県名古屋市)
    • Year and Date
      2015-03-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] Charge transport in small molecule and polymer organic transistors2014

    • Author(s)
      Hiroyuki Matsui
    • Organizer
      MPIP阪大ジョイントシンポジウム
    • Place of Presentation
      マックスプランク(ドイツマインツ)
    • Year and Date
      2014-11-16 – 2014-11-21
    • Related Report
      2014 Annual Research Report
  • [Presentation] Uniaxial orientation of semiconducting polymer films compressed on ionic liquids2014

    • Author(s)
      Hiroyuki Matsui, Junshi Soeda, Yu Yamashita, Jun Takeya
    • Organizer
      EMN OPEN ACCESS WEEK
    • Place of Presentation
      Jinjiang Generation International Hotel(中国四川省)
    • Year and Date
      2014-09-22 – 2014-09-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] High Mobility and Stability in Dual-Gated PbS Nanocrystal Transistors2014

    • Author(s)
      M. I. Nugraha, H. Matsui, S. Z. Bisri, M. Sytnyk, W. Heiss, M. A. Loi, and J. Takeya
    • Organizer
      日本物理学会
    • Place of Presentation
      中部大学(愛知県春日井市)
    • Year and Date
      2014-09-07 – 2014-09-10
    • Related Report
      2014 Annual Research Report
  • [Book] ウェアラブルデバイスの小型、薄型化と伸縮、柔軟性の向上技術2015

    • Author(s)
      赤松 範久・小池 泰徳・藤川 茂紀・宍戸 厚
    • Total Pages
      510
    • Publisher
      技術情報協会
    • Related Report
      2015 Annual Research Report
  • [Remarks] 東大新領域 竹谷研究室

    • URL

      http://www.organicel.k.u-tokyo.ac.jp/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京工業大学化学生命科学研究所宍戸 厚研究室

    • URL

      http://www.polymer.res.titech.ac.jp/

    • Related Report
      2015 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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