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Thick and high quarity InGaN growth by THVPE

Research Project

Project/Area Number 26246018
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Crystal engineering
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KOUKITU Akinori  東京農工大学, 工学(系)研究科(研究院), 理事 (10111626)

Co-Investigator(Kenkyū-buntansha) 村上 尚  東京農工大学, 工学(系)研究科(研究院), 准教授 (90401455)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥42,250,000 (Direct Cost: ¥32,500,000、Indirect Cost: ¥9,750,000)
Fiscal Year 2016: ¥11,180,000 (Direct Cost: ¥8,600,000、Indirect Cost: ¥2,580,000)
Fiscal Year 2015: ¥10,400,000 (Direct Cost: ¥8,000,000、Indirect Cost: ¥2,400,000)
Fiscal Year 2014: ¥20,670,000 (Direct Cost: ¥15,900,000、Indirect Cost: ¥4,770,000)
Keywords窒化物結晶 / THVPE / エピタキシャル成長 / 気相成長 / 三元混晶 / 発光材料 / 受光材料 / HVPE / InGaN三元混晶 / 窒化物半導体 / 発光素子 / 太陽電池 / InGaN / 発光素子材料 / 大陽電池材料
Outline of Final Research Achievements

This is the first study to report InGaN growth by tri-halide vapor phase epitaxy (THVPE) using InCl3 and GaCl3. The influence of the surface orientation of the initial substrate on InGaN THVPE growth was investigated using freestanding GaN (0001) and (000-1). Only a N-polar InGaN epitaxial layer was obtained because of the instability of GaCl3 adsorption on the the Ga-polar surface. We employed the first principle calculation for the adsorption process of GaCl3 on the surface. In addition, we investigated the influence of the group III input pressure on the growth rate and solid composition grown on a (000-1) GaN substrate. The growth rate increased linearly with group III concentration and a maximum growth rate of 15.6 micro/h was achieved at a input partial pressure of the group III precursors, GaCl3 and InCl3.
As a result of this research, by using THVPE, we succeeded in growing thick InGaN layer of 10 microns or more, which was impossible to grow by previous growth method.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (27 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Open Access: 4 results,  Acknowledgement Compliant: 3 results) Presentation (17 results) (of which Int'l Joint Research: 8 results,  Invited: 7 results)

  • [Int'l Joint Research] リンチョーピン大学/ルンド大学(Sweden)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] リンチョーピン大学/ルンド大学(Sweden)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Thick nonpolar m -plane and semipolar (10-1 -1) GaN on an ammonothermal seed by tri-halide vapor-phase epitaxy using GaCl32017

    • Author(s)
      Kenji Iso, Karen Mstsuda, Nao Takekawa, Kazuhiro Hikida, Naoto Hayashida, Hisashi Murakami and Akinori Koukit
    • Journal Title

      Journal of Crystal Growth

      Volume: 461 Pages: 25-29

    • DOI

      10.1016/j.jcrysgro.2017.01.005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improved thermodynamic analysis of gas reactions for compound semiconductor growth by vapor-phase epitaxy2017

    • Author(s)
      Y. Inatomi, Y. Kangawa, K. Kakimoto, A. Koukitu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 56 Issue: 3 Pages: 038002-038002

    • DOI

      10.7567/jjap.56.038002

    • NAID

      210000147493

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Quasiequilibrium crystal shape and kinetic Wulff plot for GaN grown by trihalide vapor phase epitaxy using GaCl32017

    • Author(s)
      Kenji Iso, Karen Matsuda, Nao Takekawa, Hisashi Murakami ans Akinori Koukitu
    • Journal Title

      Phisica Status Solidi B

      Volume: 254 Issue: 8

    • DOI

      10.1002/pssb.201600679

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Temperature-dependent capacitance-voltage and current-voltage characteristics of Pt/Ga2O3 (001) Schottky barrier diodes fabricated on n-Ga2O3 drift layers grown by halide vapor phase epitaxy2016

    • Author(s)
      M. Higashiwaki, K. Konishi, K. Sasaki, K. Goto, K. Nomura, Q. T. Thieu, R. Togashi, H. Murakami, Y. Kumagai, B. Monemar, A. Koukitu, A. Kuramata, S. Yamakoshi
    • Journal Title

      Applied Physics Letters

      Volume: 108 Issue: 13 Pages: 133503-133506

    • DOI

      10.1063/1.4945267

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Growth of thick and high crystalline quality InGaN layers on GaN (000-1) substrate using tri-halide vapor phase epitaxy2016

    • Author(s)
      Takahide Hirasaki, Martin Eriksson, Quang Tu Thieu, Fredrik Karlsson, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar, Per Olof Holtz, Akinori Koukitu
    • Journal Title

      Journal of Crystal Growth

      Volume: 456 Pages: 145-150

    • DOI

      10.1016/j.jcrysgro.2016.08.019

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] LETTER Tri-halide vapor-phase epitaxy of GaN using GaCl3 on polar, semipolar, and nonpolar substrates2016

    • Author(s)
      Kenji Iso, Nao Takekawa, Karen Matsuda, Kazuhiro Hikida, Naoto Hayashida, Hisashi Murakami and Akinori Koukitu
    • Journal Title

      Applied Physics Express

      Volume: 9 Issue: 10 Pages: 105501-105501

    • DOI

      10.7567/apex.9.105501

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Growth of thick InGaN layers by tri-halide vapor phase epitaxy2014

    • Author(s)
      Takahide Hirasaki, Kazuma Asano, Mizuki Banno, Masato Ishikawa, Fumiaki Sakuma, Hisashi Murakami, Yoshinao Kumagai and Akinori Koukitu
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 5S1 Pages: 1-4

    • DOI

      10.7567/jjap.53.05fl02

    • NAID

      210000143862

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Progress in theoretical approach to InGaN and InN epitaxy: In incorporation efficiency and structural stability2014

    • Author(s)
      Yoshihiro Kangawa, Tomonori Ito, Akinori Koukitu, and Koichi Kakimoto
    • Journal Title

      Japanese Journal of Applied Physics

      Volume: 53 Issue: 10 Pages: 1-11

    • DOI

      10.7567/jjap.53.100202

    • NAID

      210000144512

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Recent Progress in Tri-Halide Vapor Phase Epitaxy of Thick GaN and InGaN2016

    • Author(s)
      Hisashi Murakami, Nao Takekawa, Takahide Hirasaki, Yoshinao Kumagai, Kou Matsumoto, Akinori Koukitu
    • Organizer
      International Workshop on Nitride Semiconductors (IWN2016)
    • Place of Presentation
      Hilton Orlando Lake Buena Vista, Orlando, Florida, USA
    • Year and Date
      2016-10-06
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Dependence of GaN Growth on the Substrates with Various Surface Orientations by Tri-Halide Vapor Phase Epitaxy Using GaCl32016

    • Author(s)
      Kenji Iso, Karen Matsuda, Nao Takekawa, Kazuhiro Hikida, Naoto Hayashida, Hisashi Murakami, and Akinori Koukitu
    • Organizer
      International Workshop on Nitride Semiconductors (IWN2016)
    • Place of Presentation
      Hilton Orlando Lake Buena Vista, Orlando, Florida, USA
    • Year and Date
      2016-10-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] High-Speed Growth of Thick InGaN Ternary Alloy by Tri-Halide Vapor Phase Epitaxy2016

    • Author(s)
      H. Murakami, T. Hirasaki, M. Meguro, Q.-T. Thieu, R. Togashi, Y. Kumagai, B. Monemar, A. Koukitu
    • Organizer
      18th International Conference on Crystal Growth and Epitaxy (ICCGE-18)
    • Place of Presentation
      Nagoya Congress Center, Aichi,Japan
    • Year and Date
      2016-08-09
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Growth of GaN and InGaN thick epitaxial layers by tri-halide vapor phase epitaxy2016

    • Author(s)
      Hisashi Murakami, Takahide Hirasaki, Quang Tu Thieu, Rie Togashi, Yoshinao Kumagai, Kou Matsumoto and Akinori Koukitu
    • Organizer
      Workshop on Frontier Photonic and Electronic Materials and Devices
    • Place of Presentation
      Kyoto University, Kyoto, Japan
    • Year and Date
      2016-07-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High Temperature Growth of Thick InGaN Layers using Tri-Halide Vapor Phase Epitaxy2016

    • Author(s)
      M. Meguro, T. Hirasaki, T. Hasegawa, Q. T.Thieu, H. Murakami, Y. Kumagai, B. Monemar, A. Koukitu
    • Organizer
      International Conference on LEDs and their Industrial Applications ’16
    • Place of Presentation
      パシフィコ横浜、神奈川県
    • Year and Date
      2016-05-19
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] HVPE growth of the group III nitrides2015

    • Author(s)
      A. Koukitu, Y. Kumagai, H. Murakami
    • Organizer
      14th Akasaki Research Center Symposium
    • Place of Presentation
      Akasaki Research Center
    • Year and Date
      2015-11-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Thick (10 μm) and High Crystalline Quality InGaN Growth on GaN(000-1) Substrate by Tri-Halide Vapor Phase Epitaxy2015

    • Author(s)
      Takahide Hirasaki, Tomoyasu Hasegawa, Misaki Meguro, Quang Tu Thieu, Hisashi Murakami, Yoshinao Kumagai, Bo Monemar, Akinori Koukitu
    • Organizer
      9th International Workshop on Bulk Nitride Semiconductors (IWBNS-IX)
    • Place of Presentation
      Act City Hamamatsu, Shizuoka, Japan
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Tri-Halide Vapor Phase Epitaxy of Thick GaN and InGaN Layers2015

    • Author(s)
      Hisashi Murakami, Takahide Hirasaki, Quang Tu Thieu, Rie Togashi, Yoshinao Kumagai, Kou Matsumoto, Akinori Koukitu
    • Organizer
      9th International Workshop on Bulk Nitride Semiconductors (IWBNS-IX)
    • Place of Presentation
      Hansol Oak Valley, Wonju, Korea
    • Year and Date
      2015-11-04
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Temperature Dependence of InGaN Growth by Tri-Halide Vapor Phase Epitaxy2014

    • Author(s)
      T. Hirasaki, Y. Watanabe, T. Hasegawa, H. Murakami, Y. Kumagai, and A. Koukitu
    • Organizer
      10th International Symposium on Semiconductor Light Emitting Devices (ISSLED 2014)
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      2014-12-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] Theoretical calculation of thermochemical data for the growth of group-III nitrides2014

    • Author(s)
      N. Takekawa, H. Murakami, Y. Kumagai, and A. Koukitu
    • Organizer
      10th International Symposium on Semiconductor Light Emitting Devices (ISSLED 2014)
    • Place of Presentation
      Kaohsiung, Taiwan
    • Year and Date
      2014-12-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] トリハライド気相成長法によるInGaN成長における成長温度の影響2014

    • Author(s)
      長谷川智康,平崎貴英,渡辺雄太,村上尚,熊谷義直,纐纈明伯
    • Organizer
      応用物理学会第3回結晶工学未来塾(2014)
    • Place of Presentation
      学習院大学, 東京都
    • Year and Date
      2014-11-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] Nitrides by HVPE -current and prospects-2014

    • Author(s)
      A. KOUKITU, Y. KUMAGAI and H. MURAKAMI
    • Organizer
      International Workshop on Nitride Semiconductors(IWN2014)
    • Place of Presentation
      WROCLAW, Poland
    • Year and Date
      2014-08-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 第一原理計算と統計力学を用いたIII族窒化物の成長における熱化学データの算出2014

    • Author(s)
      竹川直,村上尚,熊谷義直,纐纈明伯
    • Organizer
      第6回窒化物半導体結晶成長講演会
    • Place of Presentation
      名城大学, 愛知県
    • Year and Date
      2014-07-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] トリハライド気相成長法を用いたr面サファイヤ基板上へのGaN成長2014

    • Author(s)
      富樫理恵, 小島千恵,藤田直人,斉藤広伸,村上尚,熊谷義直,纐纈明伯 塩野杏奈,竹川直,藤村侑,村上尚,熊谷義直,纐纈明伯
    • Organizer
      第6回窒化物半導体結晶成長講演会
    • Place of Presentation
      名城大学, 愛知県
    • Year and Date
      2014-07-15
    • Related Report
      2014 Annual Research Report
  • [Presentation] Influence of Growth Temperature on InGaN Growth by Tri-Halide Vapor Phase Epitaxy2014

    • Author(s)
      Takahide Hirasaki, Yuta Watanabe, Masato Ishikawa, Hisashi Murakami, Yoshinao Kumagai, and Akinori Koukitu
    • Organizer
      33rd Electronic Materials Symposium (EMS-33)
    • Place of Presentation
      ラフォーレ修善寺, 静岡県
    • Year and Date
      2014-07-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Theoretical investigation of the influence of surface orientation on In-incorporation during InGaN growth using THVPE2014

    • Author(s)
      Yu Fujimura, Hisashi Murakami, Yoshinao Kumagai, and Akinori Koukitu
    • Organizer
      33rd Electronic Materials Symposium (EMS-33)
    • Place of Presentation
      ラフォーレ修善寺, 静岡県
    • Year and Date
      2014-07-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] Estimation of thermochemical data for the growth of group-III nitrides by the combination of first principles and statistical thermodynamic2014

    • Author(s)
      Nao Takekawa, Hisashi Murakami, Yoshinao Kumagai, and Akinori Koukitu
    • Organizer
      33rd Electronic Materials Symposium (EMS-33)
    • Place of Presentation
      ラフォーレ修善寺, 静岡県
    • Year and Date
      2014-07-10
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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