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Development and application of in situ spectromicroscopy using soft X-ray inner-shell excitation

Research Project

Project/Area Number 26248010
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical chemistry
Research InstitutionInstitute for Molecular Science

Principal Investigator

KOSUGI Nobuhiro  分子科学研究所, 光分子科学研究領域, 教授 (20153546)

Co-Investigator(Kenkyū-buntansha) 大東 琢治  分子科学研究所, 極端紫外光研究施設, 助教 (50375169)
繁政 英治  分子科学研究所, 極端紫外光研究施設, 准教授 (90226118)
Co-Investigator(Renkei-kenkyūsha) NAGASAKA Masanari  分子科学研究所, 光分子科学研究領域, 助教 (90455212)
YAMANE Hiroyuki  分子科学研究所, 光分子科学研究領域, 助教 (50402459)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥37,050,000 (Direct Cost: ¥28,500,000、Indirect Cost: ¥8,550,000)
Fiscal Year 2016: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2015: ¥11,310,000 (Direct Cost: ¥8,700,000、Indirect Cost: ¥2,610,000)
Fiscal Year 2014: ¥14,430,000 (Direct Cost: ¥11,100,000、Indirect Cost: ¥3,330,000)
Keywords量子ビーム / 内殻励起 / X線顕微分光 / その場観測 / 薬物伝達
Outline of Final Research Achievements

In order to apply soft X-ray absorption spectroscopy (XAS) to chemical materials with the spatial resolution of 30 nm, we have developed transmission-type in situ cells installed into scanning transmission X-ray microscopy (STXM). By using the spatially-resolved XAS, we have investigated the reaction mechanism of inhomogeneous chemical materials such as phase separation of aqueous triethylamine solutions, electrochemical reactions, and drug delivery systems. The local structure of microfluidics, which realizes highly efficient solution reactions, is also analyzed by using XAS with the spatial resolution of 30 micron.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (42 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (8 results) Journal Article (14 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 12 results,  Open Access: 7 results,  Acknowledgement Compliant: 9 results) Presentation (15 results) (of which Int'l Joint Research: 8 results,  Invited: 10 results) Remarks (5 results)

  • [Int'l Joint Research] ヘルムホルツ協会ベルリン研究センター/ベルリン自由大学(ドイツ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ローレンス・バークレー国立研究所(米国)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] マックマスター大学/カナダ放射光源施設(カナダ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] 国家同歩輻射研究センター/淡江大学(台湾)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] オウル大学(フィンランド)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ベルリン自由大学/ヘルムホルツ協会ベルリン研究センター(HZB)(ドイツ)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] 淡江大学/台湾国立放射光研究センター(NSRRC)(台湾)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] マックマスター大学/カナダ放射光施設(CLS)(カナダ)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Unusual Water Hydrogen Bond Network around Hydrogenated Nanodiamonds2017

    • Author(s)
      T. Petit, L. Puskar, T. Dolenko, S. Choudhury, E. Ritter, S. Burikov, K. Laptinskiy, Q. Brzustowski, U. Schade, H. Yuzawa, M. Nagasaka, N. Kosugi, M. Kurzyp, A. Venerosy, H. Girard, J.-C. Arnault, E. Osawa, N. Nunn, O. Shenderova, E. F. Aziz
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 121 Issue: 9 Pages: 5185-5194

    • DOI

      10.1021/acs.jpcc.7b00721

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Integration of Active Nickel Oxide Clusters by Amino Acids for Water Oxidation2017

    • Author(s)
      M. Yoshida, S. Onishi, Y. Mitsutomi, F. Yamamoto, M. Nagasaka, H. Yuzawa, N. Kosugi, H. Kondoh
    • Journal Title

      Journal of Physical Chemistry C

      Volume: 121 Issue: 1 Pages: 255-260

    • DOI

      10.1021/acs.jpcc.6b08796

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of In-Situ/Operando Sample Cells for Soft X-ray Transmission Spectromicroscopy at UVSOR-III Synchrotron2017

    • Author(s)
      M. Nagasaka, T. Ohigashi, N. Kosugi
    • Journal Title

      Synchrotron Radiation News

      Volume: 30(2) Issue: 2 Pages: 3-7

    • DOI

      10.1080/08940886.2017.1289798

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] X-ray and Electron Spectroscopy of Water2016

    • Author(s)
      T. Fransson, Y. Harada, N. Kosugi, N. A. Besley, B. Winter, J. J. Rehr, L. G. M. Pettersson, A. Nilsson
    • Journal Title

      Chemical Review

      Volume: 116 Issue: 13 Pages: 7551-7569

    • DOI

      10.1021/acs.chemrev.5b00672

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Impacts of Conformational Geometries in Fluorinated Alkanes2016

    • Author(s)
      T. Brandenburg, R. Golnak, M. Nagasaka, K. Atak, S.S.N. Lalithambika, N. Kosugi, E. F. Aziz
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1

    • DOI

      10.1038/srep31382

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Improve Hole Collection by Interfacial Chemical Redox Reaction at a Mesoscopic NiO/CH3NH3PbI3 Heterojunction for Efficient Photovoltaic Cells2016

    • Author(s)
      M.W. Lin, K. C. Wang, J.H. Wang, M. H. Li, Y.L. Lai, T. Ohigashi, N. Kosugi, P. Chen, D.H. Wei, T.F. Guo, Y.J. Hsu
    • Journal Title

      Advanced Materials Interfaces

      Volume: 3 Issue: 17

    • DOI

      10.1002/admi.201600135

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Core-multishell nanocarriers: Transport and release of dexamethasone probed by soft X-ray spectromicroscopy2016

    • Author(s)
      K. Yamamoto, A. Klossek, R. Flesch, T. Ohigashi, E. Fleige, F. Rancan, J. Frombach, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, R. Haag, S. Hedtrich, M. Schaefer-Korting, N. Kosugi, E. Ruehl
    • Journal Title

      Journal of Controlled Release

      Volume: 242 Pages: 64-70

    • DOI

      10.1016/j.jconrel.2016.08.028

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Soft X-ray Absorption Spectroscopy in Transmission Mode: Chemical Shifts and Technical Developments for Chemical State Analysis of Interacting Molecular Systems2016

    • Author(s)
      長坂将成, 小杉信博
    • Journal Title

      Journal of the Vacuum Society of Japan

      Volume: 59 Issue: 11 Pages: 301-306

    • DOI

      10.3131/jvsj2.59.301

    • NAID

      130005282120

    • ISSN
      1882-2398, 1882-4749
    • Related Report
      2016 Annual Research Report
    • Open Access
  • [Journal Article] UVSOR-IIIの走査型透過X線顕微鏡における化学状態分析法の開発2016

    • Author(s)
      大東琢治、小杉信博
    • Journal Title

      日本放射光学会誌

      Volume: 19 Pages: 287-293

    • Related Report
      2016 Annual Research Report
    • Open Access
  • [Journal Article] Observation of DNA and protein distributions in mammalian cell nuclei using STXM2016

    • Author(s)
      T. Ohigashi, A. Ito, K. Shinohara, S. Tone, M. Kado, Y. Inagaki, Y.-F. Wang, N. Kosugi
    • Journal Title

      AIP Conference Proceedings

      Volume: 1696 Pages: 020027-020027

    • DOI

      10.1063/1.4937521

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Development and application of in situ/operando soft X-ray transmission cells to aqueous solutions and catalytic and electrochemical reactions2015

    • Author(s)
      Masanari Nagasaka, Hayato Yuzawa, Nobuhiro Kosugi
    • Journal Title

      J. Electron Spectrosc. Relat. Phenom.

      Volume: 200 Pages: 293-310

    • DOI

      10.1016/j.elspec.2015.05.012

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective Probing of the Penetration of Dexamethasone into Human Skin by Soft X-ray Spectromicroscopy2015

    • Author(s)
      K .Yamamoto, R. Flesch, T. Ohigashi, S. Hedtrich, A. Klossek, P. Patoka, G. Ulrich, S. Ahlberg, F. Rancan, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, M. Schaefer-Korting, N. Kosugi, E. Ruehl
    • Journal Title

      Analytical Chemistry

      Volume: 87 Issue: 12 Pages: 6173-6179

    • DOI

      10.1021/acs.analchem.5b00800

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In situ soft X-ray absorption spectroscopy applied to solid-liquid heterogeneous cyanopyrazine hydration reaction on titanium oxide catalyst2015

    • Author(s)
      Hayato Yuzawa, Masanari Nagasaka, Nobuhiro Kosugi
    • Journal Title

      J. Phys. Chem. C

      Volume: 119 Issue: 14 Pages: 7738-7745

    • DOI

      10.1021/jp512891t

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] 軟X線吸収分光法による電気化学反応の局所構造解析2015

    • Author(s)
      長坂将成、大東琢治、小杉信博
    • Journal Title

      分析化学

      Volume: 64 Pages: 163-172

    • NAID

      130005060602

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 軟X線吸収分光法による液体と液液界面の局所電子状態の解明2017

    • Author(s)
      長坂将成
    • Organizer
      日本化学会第97春季年会・若い世代の特別講演会
    • Place of Presentation
      慶應大学日吉キャンパス、横浜(神奈川県)
    • Year and Date
      2017-03-16
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Liquid and liquid-liquid interface studied by soft X-ray absorption in transmission mode2017

    • Author(s)
      N. Kosugi
    • Organizer
      International Workshop on Liquid X-ray Spectroscopy, LiXS2017
    • Place of Presentation
      SOLEIL, Saclay, France
    • Year and Date
      2017-01-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Scanning Transmission X-ray Microscopy for in situ/operando Chemical Analysis at UVSOR-III2016

    • Author(s)
      T. Ohigashi, Y. Inagaki, N. Kosugi
    • Organizer
      Mechanical Engineering Design of Synchrotron Radiation Equipment and Instrumentation, MEDSI 2016
    • Place of Presentation
      Barcelona, Spain
    • Year and Date
      2016-09-11
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Optimal Energy and Spatial Resolutions for in situ/operando Soft X-ray Absorption Spectroscopy2016

    • Author(s)
      N. Kosugi
    • Organizer
      2nd International Workshop on Soft X-ray Science Opportunities using Diffraction-limited Storage Rings
    • Place of Presentation
      Hefei, China
    • Year and Date
      2016-08-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A QUANTITATIVE 3-DIMENSIONAL OBSERVATION METHOD FOR SCANNING TRANSMISSION X-RAY MICROSCOPY2016

    • Author(s)
      T. Ohigashi, Y. Inagaki, A. Ito, K. Shinohara, N. Kosugi
    • Organizer
      International Conference X-ray Microscopy, XRM 2016
    • Place of Presentation
      Oxford, U.K.
    • Year and Date
      2016-08-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chemical Applications of a Scanning Transmission X-ray Microscope Developed at UVSOR-III Synchrotron2016

    • Author(s)
      T. Ohigashi, Y. Inagaki, N. Kosugi
    • Organizer
      39th International Conference on Vacuum Ultraviolet and X-ray Physics, VUVX 2016
    • Place of Presentation
      Zurich, Switzerland
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Chemical Shifts in Inner-shell Excitations arising from Molecular Interactions2016

    • Author(s)
      N. Kosugi
    • Organizer
      International Conference on The Future of X-ray and Electron Spectroscopies, XRAY-2016
    • Place of Presentation
      Uppsala, Sweden
    • Year and Date
      2016-06-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 軟X線吸収分光法によるチオシアン酸カリウム水溶液の局所構造観察2016

    • Author(s)
      湯沢勇人、長坂将成、小杉信博
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市)
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 分子の内殻励起に関する先導的実験および理論2016

    • Author(s)
      小杉信博
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市)
    • Year and Date
      2016-03-25
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 軟X線吸収分光法と赤外分光法による液体ベンゼンの分子間相互作用の観測2016

    • Author(s)
      長坂将成、湯沢勇人、望月健爾、Ruehl, Eckart, 小杉信博
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学(京都府京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Quantum Chemical Approaches to Molecular X-ray Spectroscopy2015

    • Author(s)
      小杉信博
    • Organizer
      Workshop on Prediction and Interpretation of Core-level (K-, L-edge, etc.) Spectroscopy: PICKLES 2015
    • Place of Presentation
      ローレンスバークレー国立研究所(アメリカ、バークレー)
    • Year and Date
      2015-10-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Soft X-ray Absorption Spectroscopy of Liquid and Application to In Operando Observations2015

    • Author(s)
      長坂将成
    • Organizer
      International Workshop on Soft X-ray in Energy and Time (SWET2015)
    • Place of Presentation
      ヘルムホルツ協会ベルリン研究センター(ドイツ、ベルリン)
    • Year and Date
      2015-08-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 軟X線吸収分光法による溶液の局所構造解析とオペランド観測への展開2014

    • Author(s)
      長坂将成
    • Organizer
      第37回溶液化学シンポジウム
    • Place of Presentation
      アバンセ(佐賀県佐賀市)
    • Year and Date
      2014-11-12 – 2014-11-14
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Energy Shifts in X-ray Absorption and Photoelectron Spectra of Liquid Water2014

    • Author(s)
      Nobuhiro Kosugi
    • Organizer
      NORDITA Conference on Water
    • Place of Presentation
      アルバノヴァ研究センター(スウェーデン・ストックホルム)
    • Year and Date
      2014-10-27 – 2014-10-31
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Advanced spectroscopic studies on molecular electronic states at UVSOR-III facility2014

    • Author(s)
      Hiroyuki Yamane
    • Organizer
      Asia-Oceania Forum for Synchrotron Radiation Research: AOFSRR 2014
    • Place of Presentation
      台湾放射光研究センター(台湾・新竹市)
    • Year and Date
      2014-09-15 – 2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Remarks] Information of UVSOR-III STXM Beamline

    • URL

      https://www.uvsor.ims.ac.jp/staff/BL4U/index.html

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
  • [Remarks] 新装置紹介 走査型透過軟X線顕微鏡(STXM)装置

    • URL

      https://www.ims.ac.jp/publications/letters70/70-14.pdf

    • Related Report
      2016 Annual Research Report
  • [Remarks] 放射光を利用した分子科学:分子間相互作用系の局所解析

    • URL

      https://www.ims.ac.jp/research/group/kosugi/

    • Related Report
      2016 Annual Research Report
  • [Remarks] Local Chemical State Analysis Using Soft X-Rays

    • URL

      https://www.ims.ac.jp/about/publication/ann_rev_2016/2016kosugi.pdf

    • Related Report
      2016 Annual Research Report
  • [Remarks] 新装置紹介 走査型透過軟X線顕微鏡(STXM)装置

    • URL

      http://www.ims.ac.jp/about/publication/70-14.pdf

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report

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Published: 2014-04-04   Modified: 2022-03-01  

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