Precise metal array methods using a template ranged from one atom to biomacromolecules
Project/Area Number |
26248016
|
Research Category |
Grant-in-Aid for Scientific Research (A)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Inorganic chemistry
|
Research Institution | The University of Tokyo |
Principal Investigator |
|
Co-Investigator(Renkei-kenkyūsha) |
TASHIRO Shohei 東京大学, 大学院理学系研究科, 准教授 (80420230)
UBE Hitoshi 東京大学, 大学院理学系研究科, 助教 (00512138)
TAKEZAWA Yusuke 東京大学, 大学院理学系研究科, 助教 (70508598)
|
Project Period (FY) |
2014-04-01 – 2017-03-31
|
Project Status |
Completed (Fiscal Year 2017)
|
Budget Amount *help |
¥41,990,000 (Direct Cost: ¥32,300,000、Indirect Cost: ¥9,690,000)
Fiscal Year 2016: ¥16,250,000 (Direct Cost: ¥12,500,000、Indirect Cost: ¥3,750,000)
Fiscal Year 2015: ¥12,220,000 (Direct Cost: ¥9,400,000、Indirect Cost: ¥2,820,000)
Fiscal Year 2014: ¥13,520,000 (Direct Cost: ¥10,400,000、Indirect Cost: ¥3,120,000)
|
Keywords | 超分子金属錯体 / 金属配列 / 大環状配位子 / 人工DNA / 鋳型分子 / 超分子錯体 / 鋳型合成 / 金属錯体 / 鋳型配位子 |
Outline of Final Research Achievements |
Precise control of metal arrangement in nano-scale is essential to create new electronic structures based on the number, kind, and arrangement of metal ions. In this research, we have developed three types of new template ligands such as “atomic frames”, “synthetic molecules”, and “biomolecules” to flexibly arrange finite or infinite metal ions in lines or circles. Furthermore, we have also demonstrated that such metal array structures or metal complexes can be applied to several functions including catalytic reactions or the control of molecular motions.
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Report
(4 results)
Research Products
(16 results)