Creation of one-direction proton-transport surface MOFs

• Project/Area Number: 26248019
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Inorganic chemistry
• Research Institution: Kyoto University
• Principal Investigator: Kitagawa Hiroshi 京都大学, 理学研究科, 教授 (90234244)
• Co-Investigator(Kenkyū-buntansha): 前里 光彦 京都大学, 理学(系)研究科(研究院), 准教授 (60324604) ; 大坪 主弥 京都大学, 理学(系)研究科(研究院), 助教 (90601005)
• Project Period (FY): 2014-04-01 – 2017-03-31
• Project Status: Completed (Fiscal Year 2016)
• Budget Amount: ¥42,120,000 (Direct Cost: ¥32,400,000、Indirect Cost: ¥9,720,000); Fiscal Year 2016: ¥12,740,000 (Direct Cost: ¥9,800,000、Indirect Cost: ¥2,940,000); Fiscal Year 2015: ¥13,390,000 (Direct Cost: ¥10,300,000、Indirect Cost: ¥3,090,000); Fiscal Year 2014: ¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
• Keywords: 無機化学 / 金属錯体化学 / 無機固体化学 / ナノ化学

Outline of Final Research Achievements

We prepared a nanometer-sized two-dimensional layered-type MOF thin film using a step-by-step approach. Although as-synthesized film possessed poor crystallinity and determination of the structure was unsuccessful, the dehydrated form of the film showed highly oriented crystalline nature as confirmed by synchrotron X-ray diffraction.

Research Products

• [Journal Article] Crystalline coordination framework endowed with dynamic gate-opening behaviour by being downsized to a thin film (2016)
  • Author(s): Shun Sakaida, Kazuya Otsubo, Osami Sakata, Chulho Song, Akihiko Fujiwara, Masaki Takata, Hiroshi Kitagawa
  • Journal Title: Nature Chemistry Volume: 8 Issue: 4 Pages: 377-383
  • DOI: 10.1038/nchem.2469
  • Peer Reviewed
• [Journal Article] Guest-Induced Two-Way Structural Transformation in a Layered Metal-Organic Framework Thin Film (2016)
  • Author(s): T. Haraguchi, K. Otsubo, O. Sakata, A. Fujiwara, H. Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 138 Issue: 51 Pages: 16787-16793
  • DOI: 10.1021/jacs.6b10913
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Ultrafine Metal-Organic Right Square Prism-Shaped Nanowires (2016)
  • Author(s): K. Otake, K. Otsubo, K. Sugimoto, A. Fujiwara, H. Kitagawa
  • Journal Title: Angew. Chem. Int. Ed. Volume: 55 Issue: 22 Pages: 6448-6451
  • DOI: 10.1002/ange.201601678
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] An Electrically Conductive Single-Component Donor-Acceptor-Donor Aggregate with Hydrogen-Bonding Lattice (2016)
  • Author(s): M. Hayashi, K. Otsubo, M. Maesato, T. Komatsu, K. Sugimoto, A. Fujiwara, H. Kitagawa
  • Journal Title: Inorganic Chemistry Volume: 55 Issue: 24 Pages: 13027-13034
  • DOI: 10.1021/acs.inorgchem.6b02301
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] ;Recent Progress in the Structure Control of Pd-Ru Bimetallic Nanomaterials (2016)
  • Author(s): D. Wu, K. Kusada, H. Kitagawa
  • Journal Title: Science and Technology of Advanced Materials Volume: 17 Pages: 583-596
  • NAID: 120006323759
  • Peer Reviewed / Open Access
• [Journal Article] Lithium Ion Diffusion in a Metal-Organic Framework Mediated by an Ionic Liquid (2015)
  • Author(s): K. Fujie, R. Ikeda, K. Otsubo, T. Yamada, H. Kitagawa
  • Journal Title: Chem. Mater. Volume: 27 Issue: 21 Pages: 7355-7361
  • DOI: 10.1021/acs.chemmater.5b02986
  • Peer Reviewed
• [Journal Article] Homochiral Metal Phosphonate Nanotubes (2015)
  • Author(s): X. Liu, S. Bao, J. Huang, K. Otsubo, J. Feng, M. Ren, F. Hu, Z. Sun, L. Zheng, S. Wei, H. Kitagawa
  • Journal Title: Chem. Commun. Volume: 51 Issue: 82 Pages: 15141-15144
  • DOI: 10.1039/c5cc05647k
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Dual Lewis Acidic/Basic Pd0.5Ru0.5-Poly(N-vinyl-2-pyrrolidone) Alloyed Nanoparticle: Outstanding Catalytic Activity and Selectivity in Suzuki-Miyaura Cross-Coupling Reaction (2015)
  • Author(s): M.S. Kutubi, K. Sato, K. Wada, T. Yamamoto, S. Matsumura, K. Kusada, H. Kobayashi, H. Kitagawa , K. Nagaoka
  • Journal Title: ChemCatChem Volume: 7 Issue: 23 Pages: 3887-3894
  • DOI: 10.1002/cctc.201500758
  • Peer Reviewed
• [Journal Article] Proton Conduction Study on Channel/Layer Networks of LaIIIMIII(ox)3∙10H2O (M = Cr, Co, Ru, La) and Related LaIIICoII(ox)2.5∙4H2O (2015)
  • Author(s): Hisashi Okawa, Masaaki Sadakiyo, Kazuya Otsubo, Ko Yoneda, Teppei Yamada, Masaaki Ohba, Hiroshi Kitagawa
  • Journal Title: Inorganic Chemistry Volume: 54 Issue: 17 Pages: 8529-8535
  • DOI: 10.1021/acs.inorgchem.5b01176
  • Peer Reviewed
• [Journal Article] Hybrid Materials of Ni NP@MOF prepared by a Simple Synthetic Method (2015)
  • Author(s): M. Mukoyoshi, H. Kobayashi, K. Kusada, M. Hayashi, T. Yamada, M. Maesato, Jared M. Taylor, Y. Kubota, K. Kato, M. Takata, T. Yamamoto, S. Matsumura, H. Kitagawa
  • Journal Title: Chemical Communications Volume: 51 Issue: 62 Pages: 10169-10172
  • DOI: 10.1039/c5cc04663g
  • Peer Reviewed / Open Access
• [Journal Article] Ｃｏｎｔｒｏｌ ｏｆ Ｃｒｙｓｔａｌｌｉｎｅ Ｐｒｏｔｏｎ－Ｃｏｎｄｕｃｔｉｎｇ Ｐａｔｈｗａｙｓ ｂｙ Ｗａｔｅｒ－Ｉｎｄｕｃｅｄ Ｔｒａｎｓｆｏｒｍａｔｉｏｎｓ ｏｆ Ｈｙｄｒｏｇｅｎ－Ｂｏｎｄｉｎｇ Ｎｅｔｗｏｒｋｓ ｉｎ ａ Ｍｅｔａｌ－Ｏｒｇａｎｉｃ Ｆｒａｍｅｗｏｒｋ (2014)
  • Author(s): Ｍ． Ｓａｄａｋｉｙｏ， Ｔ． Ｙａｍａｄａ， Ｋ． Ｈｏｎｄａ， Ｈ． Ｍａｔｓｕｉ， ａｎｄ Ｈ． Ｋｉｔａｇａｗａ
  • Journal Title: Ｊｏｕｒｎａｌ ｏｆ ｔｈｅ Ａｍｅｒｉｃａｎ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ Volume: 136 Issue: 21 Pages: 7701-7707
  • DOI: 10.1021/ja5022014
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Enhancing Proton Conduction in 2D Co-La Coordination Frameworks by Solid State Phase Transition (2014)
  • Author(s): Song-Song Bao, Kazuya Otsubo, Jared M. Taylor, Zheng Jiang, Li-Min Zheng, Hirohsi Kitagawa
  • Journal Title: J. Am. Chem. Soc. Volume: 136 Issue: 26 Pages: 9292-9295
  • DOI: 10.1021/ja505916c
  • Peer Reviewed
• [Journal Article] Structural Design and Electronic Properties of Halogen-Bridged Mixed-Valence Ladder Systems with Even Numbers of Legs. (2014)
  • Author(s): Kazuya Otsubo and Hiroshi Kitagawa
  • Journal Title: CrystEngComm, Volume: 16 Issue: 28 Pages: 6277-6286
  • DOI: 10.1039/c4ce00634h
  • Peer Reviewed
• [Journal Article] Proton dynamics of two-dimensional oxalate-bridged coordination polymers (2014)
  • Author(s): Satoshi Miyatsu, Maiko Kofu, Atsushi Nagoe, Takeshi Yamada, Masaaki Sadakiyo, Teppei Yamada, Hiroshi Kitagawa, Madhusudan Tyagi, Victoria Garcı´a Sakai and Osamu Yamamuro
  • Journal Title: Phys. Chem. Chem. Phys. Volume: 16 Issue: 32 Pages: 17295-17304
  • DOI: 10.1039/c4cp01432d
  • Peer Reviewed / Open Access
• [Journal Article] Hydrogen storage in Pd nanocrystals covered with a metal–organic framework (2014)
  • Author(s): Guangqin Li, Hirokazu Kobayashi, Jared M. Taylor, Ryuichi Ikeda, Yoshiki Kubota, Kenichi Kato, Masaki Takata, Tomokazu Yamamoto, Shoichi Toh, Syo Matsumura, Hiroshi Kitagawa
  • Journal Title: Nature Mater. Volume: 13 Issue: 8 Pages: 802-806
  • DOI: 10.1038/nmat4030
  • Peer Reviewed
• [Presentation] Electrical Conductive MOFs (2016)
  • Author(s): Hiroshi Kitagawa
  • Organizer: ENERGY MATERIALS NANOTECHNOLOGY(EMN)2016
  • Place of Presentation: Grand Regency Hotel, Quindao China
  • Year and Date: 2016-06-12
  • Int'l Joint Research / Invited
• [Presentation] ナノ物質における状態密度エンジニアリング (2016)
  • Author(s): 北川 宏
  • Organizer: 分子研研究会「触媒の分子科学：理論と実験のインタープレイ最前線」
  • Place of Presentation: 愛知県 岡崎市 岡崎コンファレンスセンター
  • Year and Date: 2016-03-10
  • Invited
• [Presentation] Electrical Conductive MOFs (2016)
  • Author(s): HIroshi Kitagawa
  • Organizer: 5th International Conference on Metal-Organic Frameworks & Open Framework Compounds 2016
  • Place of Presentation: Hilton Long Beach & Executive Meeting Center, Long Beach USA
  • Int'l Joint Research / Invited
• [Presentation] Elements strategy for new nano-materials based on DOS engineering (2016)
  • Author(s): Hiroshi Kitagawa
  • Organizer: European Advanced Materials Congress (EAMC)2016
  • Place of Presentation: M/S Mariella, Stockholm, Sweden
  • Int'l Joint Research / Invited
• [Presentation] Hydrogen Storage in Nano-materials (2016)
  • Author(s): Hiroshi Kitagawa
  • Organizer: 15th International Symposium on Metal-Hydrogen Systems
  • Place of Presentation: Congress Centre Kursaal Interlaken, Interlaken Switzerland
  • Int'l Joint Research / Invited
• [Presentation] Dimensional Crossover in Coordination Chemstry (2016)
  • Author(s): Hiroshi Kitagawa
  • Organizer: 8th International Symposium on Nano & Supramolecular Chemistry(ISNSC)2016
  • Place of Presentation: Mercure Brisbane, Brisbane Australia
  • Int'l Joint Research / Invited
• [Presentation] Solid-state Protonics in Coordination Polymers (2016)
  • Author(s): Hiroshi Kitagawa
  • Organizer: 42th Internatinal Conference on Coordination Chemistry(ICCC)2016
  • Place of Presentation: Le Quartz Congres, Brest France
  • Int'l Joint Research / Invited
• [Presentation] Dimensional crossover in coordination frameworks (2015)
  • Author(s): Hiroshi Kitagawa
  • Organizer: THE INTERNATIONAL CHEMICAL CONGRESS OF PACIFIC BASIN SOCIETIES 2105(Pacifichem 2015)
  • Place of Presentation: Hawaii Convention Center ,Hawaii USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research / Invited
• [Presentation] Dimensional Crossover in Coordination Chemistry (2015)
  • Author(s): HIroshi Kitagawa
  • Organizer: The 2nd Japan-Germany Joint Symposium on Coordination Chemistry (JGJSCC2)
  • Place of Presentation: Nara Women’s University, Nara Japan
  • Year and Date: 2015-09-21
  • Int'l Joint Research / Invited
• [Presentation] Elements strategy for new nano-materials (2015)
  • Author(s): Hiroshi Kitagawa
  • Organizer: Japan-Spain Joint Symposium
  • Place of Presentation: Institute of Chemical Research of Catalonia,Tarragona Spain
  • Year and Date: 2015-06-22
  • Int'l Joint Research / Invited
• [Presentation] Hydrogen Storage in Nano-materials (2015)
  • Author(s): Hiroshi Kitagawa
  • Organizer: EMN Meeting on Droplets
  • Place of Presentation: Holiday Inn Resort Phuket, Phuket Thailand
  • Year and Date: 2015-05-08
  • Int'l Joint Research / Invited
• [Presentation] Elements Strategy for New Nano-Materials (2014)
  • Author(s): Hiroshi Kitagawa
  • Organizer: EMN Fall Meeting
  • Place of Presentation: Double Tree by hilton Hotel Orland, USA
  • Year and Date: 2014-11-22
  • Invited
• [Presentation] プロトニクスと結晶 (2014)
  • Author(s): 北川 宏
  • Organizer: 日本結晶学会
  • Place of Presentation: 東京大学・本郷キャンパス
  • Year and Date: 2014-11-02
  • Invited
• [Presentation] Functional Materials on the Basis of Elemental Strategy (2014)
  • Author(s): Hiroshi Kitagawa
  • Organizer: 97th Canadian Chemistry Conference & Exhibition
  • Place of Presentation: Vancouver Convention Cwntre, Vancouve Canada
  • Year and Date: 2014-06-05
  • Invited
• [Presentation] Functional Materials on the Basis of Elemental Strategy (2014)
  • Author(s): Hiroshi Kitagawa
  • Organizer: E-MRS 2014 Spring Meeting
  • Place of Presentation: Congress Center, Lille France
  • Year and Date: 2014-05-29
  • Invited
• [Presentation] Creation of the Functional Materials on the Basis of the Inter-Element-Fusion Strategy (2014)
  • Author(s): Hiroshi Kitagawa
  • Organizer: The 1st Japan-Italy Joint Symposium on Materials for Efficient Utilization of Elements
  • Place of Presentation: palazzo Vendramin, Venice Italy
  • Year and Date: 2014-05-18
  • Invited