| Budget Amount *help |
¥41,470,000 (Direct Cost: ¥31,900,000、Indirect Cost: ¥9,570,000)
Fiscal Year 2017: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2016: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2015: ¥10,530,000 (Direct Cost: ¥8,100,000、Indirect Cost: ¥2,430,000)
Fiscal Year 2014: ¥9,880,000 (Direct Cost: ¥7,600,000、Indirect Cost: ¥2,280,000)
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| Outline of Final Research Achievements |
Practical and efficient organic synthetic methods are important to access to a variety of valuable compounds without forming a large amount of reaction wastes. During this research project, we developed homogeneous catalysts containing multi-metallic active sites, i.e. homogeneous cluster catalysts, for converting extremely difficult substrates or breaking strong chemical bonds by utilizing the metal-metal cooperative effect in the catalysts. We achieved alcoholysis of amides using an N,O-acyl rearrangement, cleavage of nitrogen-nitrogen multiple bonds at the metal-metal multiply bonded reaction site, and C-C bond activation of simple organic molecules using cooperative reactivity of metal catalyst/organic reductant.
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