| Budget Amount *help |
¥43,810,000 (Direct Cost: ¥33,700,000、Indirect Cost: ¥10,110,000)
Fiscal Year 2017: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2016: ¥3,120,000 (Direct Cost: ¥2,400,000、Indirect Cost: ¥720,000)
Fiscal Year 2015: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
Fiscal Year 2014: ¥34,580,000 (Direct Cost: ¥26,600,000、Indirect Cost: ¥7,980,000)
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| Outline of Final Research Achievements |
Through this research, we tried to clarify the features of the group 6-7 metals, especially unknown and useful reactivities for organic synthesis. We have found the following synthetic reactions by using the metal complexes. (1) Isolation of silyl-substituted gem-dichromiomethane (and gem-dizinciomethane) complexes and examination of the catalytic reactivity of the isolated complexes toward olefins and carbonyl compounds; (2) Intermolecular anti-Markovnivov addition of carbon nucleophiles by generation of rhenium-alkylidene complexes from terminal alkynes; (3) Molybdenum-catalyzed hydrosilylation of allenes and deoxygenation of epoxides; (4) Novel bismuth-catalyzed electrophilic C-C bond formation and etherification of phenolic hydroxy groups.
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