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Synthesis of novel biomass-based plastics from non-edible biomass and high-functionability by structural control

Research Project

Project/Area Number 26248044
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Green/Environmental chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

Iwata Tadahisa  東京大学, 大学院農学生命科学研究科(農学部), 教授 (30281661)

Co-Investigator(Kenkyū-buntansha) 中島 将博  東京理科大学, 理工学部応用生物科学科, 講師 (60580727)
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥42,120,000 (Direct Cost: ¥32,400,000、Indirect Cost: ¥9,720,000)
Fiscal Year 2017: ¥6,760,000 (Direct Cost: ¥5,200,000、Indirect Cost: ¥1,560,000)
Fiscal Year 2016: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Fiscal Year 2015: ¥10,660,000 (Direct Cost: ¥8,200,000、Indirect Cost: ¥2,460,000)
Fiscal Year 2014: ¥16,380,000 (Direct Cost: ¥12,600,000、Indirect Cost: ¥3,780,000)
Keywordsバイオマスプラスチック / グルカル酸 / フェルラ酸 / 微生物産生ポリエステル / 物性 / 繊維 / 構造解析 / バイオベースプラスチック / 高分子多糖類 / フィルム / 生分解性プラスチック / 高分子材料 / 高分子構造 / 成型加工 / 酵素分解性 / 材料物性 / グリーンケミストリー / バイオベースポリマー / プルラン / キチン / キトサン / アルギン酸 / セルロース / エステル誘導体 / グルカル酸アセテート / ポリエステル / ポリアミド / バイオリファイナリー
Outline of Final Research Achievements

The aims of this study are the production of new biomass-based plastics from non-edible biomass and the high-functionability of these plastics. A new crystal agent was developed for poly(lactic acid) stereocomplex. Novel crystalline polyesters and polyamides were succeeded to synthesize from glucalic acid, one of fundamental bio-based monomers. Furthermore, two kinds of copolymers were synthesized from ferulic acid. On the other hand, ultra-high-molecular-weight microbial polyesters have been synthesized and succeeded to process the high tensile strength fibers by blending to normal molecular weight microbial polyesters. The molecular and crystals structures were analyzed by the X-ray diffraction at synchrotron radiation.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (44 results)

All 2017 2016 2015 2014 Other

All Journal Article (18 results) (of which Int'l Joint Research: 9 results,  Peer Reviewed: 17 results,  Open Access: 2 results,  Acknowledgement Compliant: 12 results) Presentation (22 results) (of which Int'l Joint Research: 7 results,  Invited: 11 results) Remarks (4 results)

  • [Journal Article] Synthesis and characterization of regioselectively substituted curdlan hetero esters via an unexpected acyl migration2017

    • Author(s)
      Chien Chih-Ying、Enomoto-Rogers Yukiko、Takemura Akio、Iwata Tadahisa
    • Journal Title

      Carbohydrate Polymers

      Volume: 155 Pages: 440-447

    • DOI

      10.1016/j.carbpol.2016.08.067

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Zero birefringence films of pullulan ester derivatives2017

    • Author(s)
      Takahiro Danjo, Yukiko Enomoto, Hikaru Shimada, Shogo Nobukawa, Masayuki Yamaguchi, Tadahisa Iwata
    • Journal Title

      SCIENTIFIC REPORTS

      Volume: 7 Issue: 1 Pages: 46342-46342

    • DOI

      10.1038/srep46342

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Thermal and mechanical properties of tailor-made unbranched α-1,3-glucan esters with various carboxylic acid chain length2017

    • Author(s)
      Puanglek Sakarin、Kimura Satoshi、Iwata Tadahisa
    • Journal Title

      Scientific Reports

      Volume: 169 Pages: 245-254

    • DOI

      10.1016/j.carbpol.2017.04.015

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] バイオベースプラスチックの最近の進歩2017

    • Author(s)
      岩田 忠久
    • Journal Title

      高分子

      Volume: 2 Pages: 73-78

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 虫歯菌がつくる高分子多糖類からの高耐熱性バイオプラスチック2017

    • Author(s)
      岩田 忠久
    • Journal Title

      Material Stage

      Volume: 10 Pages: 52-54

    • Related Report
      2017 Annual Research Report
  • [Journal Article] Enhanced crystallization of poly(lactide) stereocomplex by xylan propionate2016

    • Author(s)
      Daisuke Ishii, Misaki Kimishima, Katsuto Otake and Tadahisa Iwata
    • Journal Title

      Polymer International

      Volume: 65(3) Issue: 3 Pages: 339-345

    • DOI

      10.1002/pi.5061

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis and enzymatic degradation of randomly substituted 2,3,6-O-cellulose acetate and regioselectively substituted 2,3-O-cellulose acetate2016

    • Author(s)
      Nobuko Takeda, Yukiko Enomoto-Rogers, Akio Takemura and Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 129 Pages: 125-132

    • DOI

      10.1016/j.polymdegradstab.2016.04.008

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Investigating thermal properties of and melting-induced structural changes in cold-drawn P(3HB) films with α- and β-structures using real-time X-ray measurements and high-speed DSC2016

    • Author(s)
      Taizo Kabe, Toshihisa Tanaka, Hironori Marubayashi, Takaaki Hikima, Masaki Tanaka, and Tadahisa Iwata
    • Journal Title

      Polymer

      Volume: 93 Pages: 181-188

    • DOI

      10.1016/j.polymer.2016.04.028

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Conformation analysis of D-glucaric acid in deuterium oxide by NMR based on its JHH and JCH coupling constants2016

    • Author(s)
      Yukiko Enomoto-Rogers, Hisaharu Masaki, Tetsuya Ito, Kazuo Furihata and Tadahisa Iwata
    • Journal Title

      Magnetic Resonance in Chemistry

      Volume: 54(7) Issue: 7 Pages: 561-567

    • DOI

      10.1002/mrc.4396

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Crystal Polymorphism of Curdlan Propionate: 6-Fold versus 5-Fold Helices2016

    • Author(s)
      Hironori Marubayashi, Kazuyori Yukinaka, Yukiko Enomoto-Rogers, Takaaki Hikima, Masaki Takata and Tadahisa Iwata
    • Journal Title

      ACS Macro Letters

      Volume: 5(5) Issue: 5 Pages: 607-611

    • DOI

      10.1021/acsmacrolett.6b00186

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis of Crystalline and amphiphilic Polymers from D-Glucaric Acid2016

    • Author(s)
      Yuxin Wu, Yukiko Enomoto-Rogers, Hisaharu Masaki, and Tadahisa Iwata
    • Journal Title

      ACS Sustainable Chemistry & Engineering

      Volume: 4(7) Issue: 7 Pages: 3812-3819

    • DOI

      10.1021/acssuschemeng.6b00530

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In vitro synthesis of linear α-1,3-glucan and chemical modification to ester derivatives exhibiting outstanding thermal properties2016

    • Author(s)
      Sakarin Puanglek, Satoshi Kimura, Yukiko Enomoto-Rogers, Taizo Kabe, Makoto Yoshida, Masahisa Wada and Tadahisa Iwata
    • Journal Title

      Scientific Reports

      Volume: 6 Issue: 1 Pages: 30479-30479

    • DOI

      10.1038/srep30479

    • NAID

      120006349328

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Soft, tough, and flexible curdlan hydrogels and organogels fabricated by covalent cross-linking2016

    • Author(s)
      Yukiko Enomoto-Rogers, Satoshi Kimura and Tadahisa Iwata
    • Journal Title

      Polymer

      Volume: 100 Pages: 143-148

    • DOI

      10.1016/j.polymer.2016.08.032

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Co-crystallization phenomena in biosynthesized isotactic poly[(R)-lactate-co-(R)-2-hydroxybutyrate]s with various lactate unit ratios2016

    • Author(s)
      Taizo Kabe, Ken'ichiro Matsumoto, Satsuki Terai, Takaaki Hikima, Masaki Takata, Masahiro Miyake, Seiichi Taguchi and Tadahisa Iwata
    • Journal Title

      Polymer Degradation and Stability

      Volume: 132 Pages: 137-144

    • DOI

      10.1016/j.polymdegradstab.2016.03.005

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Synthesis and Characterization of Pullulan Alkyl Esters2015

    • Author(s)
      Yukiko Enomoto-Rogers,Narihiro Iio, Akio Takemura, Tadahisa Iwata
    • Journal Title

      European Polymer Journal

      Volume: 66 Pages: 470-477

    • DOI

      10.1016/j.eurpolymj.2015.03.007

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] High tensile strength fiber of poly[(R)-3-hydroxybutyrate-co-(R)-3-hydroxyhexanoate] processed by two-step drawing with intermediate annealing2015

    • Author(s)
      Taizo Kabe, Chizuru Hongo, Toshihisa Tanaka, Takaaki Hikima, Masaki Takata and Tadahisa Iwata
    • Journal Title

      Journal of Applied Polymer Science

      Volume: 132 Issue: 2 Pages: 41258-41265

    • DOI

      10.1002/app.41258

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of acetylation site on orientation birefringence of cellulose triacetate2015

    • Author(s)
      S. Nobukawa, Y. Enomoto-Rogers, H. Shimada, T. Iwata, M. Yamaguchi
    • Journal Title

      Cellulose

      Volume: 22 Issue: 5 Pages: 3003-3012

    • DOI

      10.1007/s10570-015-0730-z

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Crystal transition from hydrated chitosan and chitosan/monocarboxylic acid complex to anhydrous chitosan investigated by X-ray diffraction;2015

    • Author(s)
      Philip-Kunio Naito, Yu Ogawa, Satoshi Kimura, Tadahisa Iwata and Masahisa Wada
    • Journal Title

      Journal of Polymer Science, Part B: Polymer Physics Edition

      Volume: 53 Issue: 15 Pages: 1065-1069

    • DOI

      10.1002/polb.23748

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Presentation] High performance bio-based plastics from natural and unnatural polysaccharide2017

    • Author(s)
      Tadahisa Iwata
    • Organizer
      Japan-South-East Asia Collaboration Hub of Bioplastics Study
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High Performance Bio-Based Plastics from Microbial Polyester and Polysaccharide Ester Derivatives2017

    • Author(s)
      Tadahisa Iwata
    • Organizer
      CU-JAPAN Southeast Asia Collaboration Hub of Bioplastics Study
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High-Performance Polysaccharide Ester Derivatives2017

    • Author(s)
      Tadahisa Iwata
    • Organizer
      The 6th International Conference of Bio-based Polymers
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 多糖が拓く新しいバイオプラスチックの世界2017

    • Author(s)
      岩田忠久
    • Organizer
      ファインケミカルジャパン
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高分子多糖類の特徴を活かした新しいバイオプラスチック2017

    • Author(s)
      岩田忠久
    • Organizer
      バイオインダストリー協会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 高分子多糖類の特徴を活かした新しいバイオプラスチックの創製と構造制御による高性能化2017

    • Author(s)
      岩田忠久
    • Organizer
      第66回高分子学会年次大会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] 多糖類から高性能なプラスチックはつくれるか?-虫歯菌の酵素から高耐熱性プラスチックをつくる-2017

    • Author(s)
      岩田忠久
    • Organizer
      高分子学会 第116回プラスチックフィルム研究会
    • Related Report
      2017 Annual Research Report
    • Invited
  • [Presentation] High Performance Polysaccharide: From Synthesis to Property Control2016

    • Author(s)
      Tadahisa Iwata
    • Organizer
      The 11th SPSJ International Polymer Conference
    • Place of Presentation
      福岡国際会議場(福岡県福岡市)
    • Year and Date
      2016-12-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] High-performance Microbial Polyesters and Polysaccharide Derivatives2016

    • Author(s)
      Tadahisa Iwata
    • Organizer
      3rd International Symposium on Advances in Sustainable Polymers (ASP-3)
    • Place of Presentation
      京都工芸繊維大学(京都府京都市)
    • Year and Date
      2016-08-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 位置選択的置換基を有するカードランエステルの合成と物性評価2016

    • Author(s)
      錢. 致瑩, ロジャース有希子, 竹村彰夫, 岩田忠久
    • Organizer
      第66回日本木材学会大会
    • Place of Presentation
      名古屋
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] デキストランエステル誘導体の合成とその性質2016

    • Author(s)
      都甲梓, ロジャース有希子, 竹村彰夫, 岩田忠久
    • Organizer
      第66回日本木材学会大会
    • Place of Presentation
      名古屋
    • Year and Date
      2016-03-27
    • Related Report
      2015 Annual Research Report
  • [Presentation] 多糖類の特徴をいかした新しい高性能バイオプラスチック2016

    • Author(s)
      岩田忠久
    • Organizer
      16-2 ポリマーフロンティア21 バイオベースポリマーの開発と実用化
    • Place of Presentation
      積水化学中央研究所(京都府京都市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 生分解性バイオポリエステルの高性能化を見ることから考える2016

    • Author(s)
      岩田忠久
    • Organizer
      日本真空学会関西支部&日本表面科学会関西支部合同セミナー2016
    • Place of Presentation
      京都大学(京都府京都市)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Characterization of α-1,3-glucan esters2015

    • Author(s)
      S. Puanglek, 木村聡, ロジャース有希子, 加部泰三, 吉田誠, 和田昌久, 岩田忠久
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis and characterization of regioselectively substituted curdlan hetero esters2015

    • Author(s)
      錢. 致瑩, ロジャース有希子, 竹村彰夫, 岩田忠久
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 化学架橋による多糖ゲルの調製とその性質2015

    • Author(s)
      ロジャース有希子 and 岩田忠久
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] セルロースアセテートの酵素分解における置換位置の影響2015

    • Author(s)
      竹田展子, ロジャース有希子, 竹村彰夫, 岩田忠久
    • Organizer
      セルロース学会第22回年次大会
    • Place of Presentation
      札幌
    • Year and Date
      2015-07-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] D-グルカル酸を用いたポリアミド及びポリエステルの合成2015

    • Author(s)
      呉. 宇シン, ロジャース有希子, 正. 久晴, 竹村彰夫, 岩田忠久
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2015-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] フェルラ酸とグリシンを用いたポリエステルアミドの合成2015

    • Author(s)
      後藤達也, 石井大輔, 竹村彰夫, 岩田忠久
    • Organizer
      第64回高分子学会年次大会
    • Place of Presentation
      札幌コンベンションセンター(北海道)
    • Year and Date
      2015-05-27
    • Related Report
      2014 Annual Research Report
  • [Presentation] Preparation and characterization of poly(ester-amide)s of ferulic acid and aliphatic amino acids2015

    • Author(s)
      T. Goto, D. Ishii, A. Takemura and T. Iwata
    • Organizer
      Internationl Symposium on Wood Science and Technology 2015 (IAWPS2015)
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2015-03-15
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Plant Biomass-Derived Aromatic Polyesters with Improved Thermal Properties2014

    • Author(s)
      D. Ishii and T. Iwata
    • Organizer
      IUPAC World Polymer Congress Macro
    • Place of Presentation
      チェンマイ(タイ)
    • Year and Date
      2014-07-06
    • Related Report
      2014 Annual Research Report
    • Int'l Joint Research
  • [Presentation] フェルラ酸をモノマー成分とする新規ポリマー合成法の検討2014

    • Author(s)
      後藤達也、石井大輔, 岩田忠久
    • Organizer
      平成26年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京)
    • Year and Date
      2014-06-11
    • Related Report
      2014 Annual Research Report
  • [Remarks] 東京大学大学院農学生命科学研究科生物材料科学専攻高分子材料学研究室

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/index.html

    • Related Report
      2017 Annual Research Report
  • [Remarks] 東京大学大学院農学生命科学研究科生物材料科学専攻高分子材料学研究室HP

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東京大学大学院農学生命科学研究科生物材料科学専攻高分子材料学研究室

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東京大学大学院農学生命科学研究科生物材料科学専攻高分子材料学研究室ホームページ

    • URL

      http://www.fp.a.u-tokyo.ac.jp/lab/polymer/

    • Related Report
      2014 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2019-03-29  

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