Preparation of High Performace (Polymer/Naturai Inorganic Nanotube) Composites by Procise Interfacial Structure Control

• Project/Area Number: 26248053
• Research Category: Grant-in-Aid for Scientific Research (A)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Kyushu University
• Principal Investigator: Takahara Atsushi 九州大学, 先導物質化学研究所, 教授 (20163305)
• Co-Investigator(Renkei-kenkyūsha): Higaki Yuji 九州大学, 先導物質化学研究所, 助教 (40619649) ; Hirai Tomoyasu 九州大学, 先導物質化学研究所, 助教 (60585917)
• Project Period (FY): 2014-04-01 – 2018-03-31
• Project Status: Completed (Fiscal Year 2017)
• Budget Amount: ¥33,670,000 (Direct Cost: ¥25,900,000、Indirect Cost: ¥7,770,000); Fiscal Year 2016: ¥7,410,000 (Direct Cost: ¥5,700,000、Indirect Cost: ¥1,710,000); Fiscal Year 2015: ¥14,560,000 (Direct Cost: ¥11,200,000、Indirect Cost: ¥3,360,000); Fiscal Year 2014: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
• Keywords: イモゴライト / ハロイサイト / ハイブリッド材料 / 界面構造制御 / ハイブリッドゲル / 分離材料 / 難燃性 / 表面修飾 / ヒアルロン酸 / ポリ乳酸 / ハイドロゲル / 結晶化 / 放射光X線回折 / ナノコンポジット / ナノチューブ / ナノハイブリッド / 表面グラフト / 選択的物質透過性 / 無機ナノチューブミセル / 天然無機ナノチューブ / 表面開始重合 / ハイブリッドハイドロゲル / インテリジェントハイブリッド

Outline of Final Research Achievements

Surface functionalization of tubular nano-clays of imogolite and halloysite using the selective surface modified nanotubes in polymer hybrids were studied and precise characterization was carried out. (1) Inorganic micelles were prepared from immobilization of hydrophobic molecule in the lumen of halloysite and grafting of zwitter inonic polymer from the outer surface of halloysite. (2) (Segmented polyurethane/modified halloysite with flameretardant) nanohybrids were prepared. It showed good mechanical properties as well as excellent thermal stability.(3) Electrospun poly(glycolic acid)/halloysite nanotube hybrid fibers was prepared and structure-property relationship has been revealed. (4）Halloysite nanotubes/ polyelectrolyte hybrids as adsorbents for dyes from aqueous solution was designed.(5) Hybrid hydrogels were prepared from imogolite fibrous nanotubular clay and hyaluronic acid. (6) Hybrid hydrogels were also prepared from halloysite and hyaluronic acid.

Research Products

• [Journal Article] 天然無機ナノチューブを用いた（有機/無機）ハイブリッド材料 (2017)
  • Author(s): 高原 淳
  • Journal Title: 繊維学会誌 Volume: 73
  • NAID: 130006865298
• [Journal Article] Design and Characterization of Hybrid Hydrogels Composed of Imogolite Fibrous Nanotubular Clay and Hyaluronic Acid (2016)
  • Author(s): K. L. Park, Y. Higaki, A. Takahara
  • Journal Title: Polymer Volume: 100 Pages: 238-243
  • DOI: 10.1016/j.polymer.2016.08.018
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Halloysite Nanotubes/Polyelectrolyte Hybrids as Adsorbents for Quick Removal of Dyes from Aqueous Solution (2015)
  • Author(s): D. Tao, Y. Higaki, W. Ma, Wei，A. Takahara
  • Journal Title: Chemistry Letters Volume: 44 Issue: 11 Pages: 1572-1574
  • DOI: 10.1246/cl.150727
  • NAID: 130005108091
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Inorganic Nanotube Induced Chain Orientation in Poly(Glycolic Acid)/Halloysite Nanotube Hybrid Electrospun Fiber (2015)
  • Author(s): Di Tao, Yuji Higaki, Wei Ma, Atsushi Takahara,
  • Journal Title: Polymer Volume: 60 Pages: 284-291
  • DOI: 10.1016/j.polymer.2015.01.048
  • Acknowledgement Compliant
• [Journal Article] Chain orientation in poly(glycolic acid)/halloysite nanotube hybrid electrospun fibers (2015)
  • Author(s): Di Tao, Yuji Higaki, Wei Ma, Hui Wu, Takamichi Shinohara, Takahiro Yano, Atsushi Takahara,
  • Journal Title: Polymer Volume: 60 Pages: 284-291
  • Peer Reviewed
• [Presentation] Structure and properties (Imogolite/biopolymer) hybrids (2017)
  • Author(s): Atsushi Takahara
  • Organizer: The 16th International Clay Conference
  • Place of Presentation: Granada, Spain
  • Year and Date: 2017-07-16
  • Int'l Joint Research / Invited
• [Presentation] Design of organic material/tubular clay assemblies through precise interfacial structure control (2016)
  • Author(s): Atsushi Takahara
  • Organizer: The 3rd Asian Clay Conference
  • Place of Presentation: Guangzhou China
  • Year and Date: 2016-11-17
  • Int'l Joint Research / Invited
• [Presentation] Design of Novel Polymer Nanocomposites from Natural Aluminosilicate Nanofiller (2016)
  • Author(s): Atsushi Takahara
  • Organizer: The 10th Asian-Australasian Conference on Composite Materials
  • Place of Presentation: Busan, Korea
  • Year and Date: 2016-10-16
  • Int'l Joint Research / Invited
• [Presentation] Design of (Organic Material/Halloysite Nanotube) Assemblies through Precise Interfacial Structure Control (2016)
  • Author(s): Atsushi Takahara
  • Organizer: The 21st International Symposium on Surfactants in Solution (SIS)
  • Place of Presentation: Jinan, China
  • Year and Date: 2016-06-05
  • Int'l Joint Research / Invited
• [Presentation] Polymer Hybrids from Natoral Inoroganic Nanotubes (2016)
  • Author(s): A.Takahara
  • Organizer: Educational Workshop and Symposium on Polymer Science and Technology
  • Place of Presentation: Kuara lumpur, Malaysia
  • Year and Date: 2016-03-29
  • Int'l Joint Research / Invited
• [Presentation] Crystallization and recrystallization behavior study on biopolymer composites with polymer grafted halloysite nanotubes (2016)
  • Author(s): Ya-ting Hsieh, Ken Kojio, Atsushi Takahara
  • Organizer: APS March Meeting 2016
  • Place of Presentation: Baltimore Convention Center, Baltimore, MD, USA
  • Year and Date: 2016-03-14
  • Int'l Joint Research
• [Presentation] Design and characterization of (organic material/halloysite nanotube) hybrids, (2016)
  • Author(s): A. Takahara
  • Organizer: 251st ACS National Meeting & Exposition,
  • Place of Presentation: SanDiego, USA
  • Year and Date: 2016-03-13
  • Int'l Joint Research / Invited
• [Presentation] Design and characterization of (polymer/ natural inorganic nanotube) assemblies, (2015)
  • Author(s): A. Takahara
  • Organizer: Pacifichem 2015
  • Place of Presentation: Honolulu, Hawaii, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research / Invited
• [Presentation] Effect of Polymer Grafted Halloysite on Crystallization Behavior of Poly(lactic acid) (2015)
  • Author(s): Ya-ting Hsieh, Ken Kojio, Atsushi Takahara
  • Organizer: 5th Asian Symposium on Advanced Materials: Chemistry, Physics & Biomedicine of Functional and Novel Materials (ASAM-5)
  • Place of Presentation: Pusan National University, Busan, Korea
  • Year and Date: 2015-11-02
  • Int'l Joint Research
• [Presentation] Design of (Organic/inorganic) hybrid materials from Surface Modified Halloysite Nanotubes, (2015)
  • Author(s): A. Takahara
  • Organizer: APME2015
  • Place of Presentation: Yokohama, Japan
  • Year and Date: 2015-10-18
  • Int'l Joint Research / Invited
• [Presentation] Characterization and Functional Properties of (Organic Material/Halloysite Nanotube) Hybrids (2015)
  • Author(s): A. Takahara
  • Organizer: The 4th Federation of Asian Polymer Societies International Polymer Congress (4FAPS-IPC2015)
  • Place of Presentation: Kuara lumpur, Malaysia
  • Year and Date: 2015-10-05
  • Int'l Joint Research / Invited
• [Presentation] Organic/Inorganic Hybrid Drug Carriers Based on Halloysite Nanotubes (2014)
  • Author(s): Di Tao, Wei Ma, Yuji Higaki, Atsushi Takahara
  • Organizer: The 10th SPSJ International Polymer Conference (IPC 2014)
  • Place of Presentation: つくば国際会議場/茨城
  • Year and Date: 2014-12-02 – 2014-12-05
• [Presentation] Design and Characterization of (Organic-Inorganic) Nanohybrids from Natural Inorganic Nanotubes (2014)
  • Author(s): A. Takahara
  • Organizer: 2014 Asia Conference on Nanoscience and Nanotechnology
  • Place of Presentation: Jeju, Korea
  • Year and Date: 2014-10-26 – 2014-10-29
  • Invited
• [Presentation] Selectively Modified Halloysite Nanotubes as Inorganic Nanocarriers for Drug Delivery Application (2014)
  • Author(s): Di Tao, Wei Ma, Yuji Higaki, Atsushi Takahara
  • Organizer: 第63回高分子討論会 The 63nd Symposium on Macromolecules
  • Place of Presentation: 長崎大学文教キャンパス
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] Development of Novel Surface Modification Technique for Water/Oil Separation (2014)
  • Author(s): Di Tao, Wei Ma, Yuji Higaki, Takahiro Yano, Atsushi Takahara
  • Organizer: International Symposium on Polymer Chemistry(PC2014)
  • Place of Presentation: Sofitel Hotel， SHANGHAI, CHINA
  • Year and Date: 2014-06-14 – 2015-06-17
• [Presentation] Design and Characterization of Hybrid Materials From Natural Inorganic “Hallosite” (2014)
  • Author(s): 7.A. Takahara, W. Ma, H, Wu, D. Tao, W. O. Yah
  • Organizer: 51st Annual Meeting of The Clay Minerals Society
  • Place of Presentation: Texas A& M University, TX, U.S.A.
  • Year and Date: 2014-05-17 – 2014-05-21
  • Invited
• [Book] Imogolite Polymer Nanocomposites、Chapter 24, Nanosized Tubular Clay Minerals (2016)
  • Author(s): W. Ma, Y. Higaki, A. Takahara
  • Total Pages: 43
  • Publisher: Elsevier
• [Book] Design and Physicochemical Characterization of Novel Organic Inorganic Hybrids from Natural Aluminosilicate Nanotubes, Chapter 4, Functional Polymer Composites with Nanoclays, (2016)
  • Author(s): A. Takahara，Y.Higaki
  • Total Pages: 24
  • Publisher: Royal Society of Chemistry
• [Book] Developments in Clay Science: Imogolite Polymer Nanocomposites (2016)
  • Author(s): W. Ma, Y. Higaki, A. Takahara,
  • Publisher: Elsevier
• [Book] Functional Polymer Composites with Nanoclays: Design and Physicochemical Characterization of Novel Organic/Inorganic Hybrids from Natural Aluminosilicate Nanotubes (2016)
  • Author(s): Y. Higaki, A. Takahara
  • Publisher: Royal Society of Chemistry
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  • URL: http://takahara.ifoc.kyushu-u.ac.jp/
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  • URL: http://takahara.ifoc.kyushu-u.ac.jp/
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  • URL: http://takahara.ifoc.kyushu-u.ac.jp/