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Development of highly efficient formation process of thin film devices based on atmospheric-pressure plasma science

Research Project

Project/Area Number 26249010
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Production engineering/Processing studies
Research InstitutionOsaka University

Principal Investigator

Kakiuchi Hiroaki  大阪大学, 工学研究科, 准教授 (10233660)

Co-Investigator(Kenkyū-buntansha) 押鐘 寧  大阪大学, 工学研究科, 助教 (40263206)
Project Period (FY) 2014-04-01 – 2019-03-31
Project Status Completed (Fiscal Year 2018)
Budget Amount *help
¥33,020,000 (Direct Cost: ¥25,400,000、Indirect Cost: ¥7,620,000)
Fiscal Year 2018: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2017: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2016: ¥5,460,000 (Direct Cost: ¥4,200,000、Indirect Cost: ¥1,260,000)
Fiscal Year 2015: ¥8,320,000 (Direct Cost: ¥6,400,000、Indirect Cost: ¥1,920,000)
Fiscal Year 2014: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
Keywords特殊加工 / 薄膜作製技術 / 大気圧プラズマ / 薄膜デバイス
Outline of Final Research Achievements

We have aimed at reducing the generation of short-lifetime radicals and nanoparticles in atmospheric-pressure (AP) very high-frequency (VHF) plasma by controlling the ON time of pulse-modulated input power, and investigated a highly efficient deposition process of good-quality silicon (Si) and silicon oxide (SiOx) films at low temperatures. The results have demonstrated that the pulse modulation of input power is very effective on generating precursor radicals useful for the creation of high-quality films. As a consequence, we have achieved the deposition of amorphous Si layers with good electrical property at a substrate temperature as low as 120 C. It has also been shown that SiOx layers with reasonably good dielectric property can be formed at a temperature of 120 C. By combining the depositions of both Si and SiOx layers using AP-VHF plasma, highly efficient formation processes of various functional thin film devices on flexible polymer substrates will be strongly expected.

Academic Significance and Societal Importance of the Research Achievements

本研究は,研究代表者ら独自の超高周波励起大気圧プラズマに関する知見・技術を生かし,一般的な減圧プラズマ技術や他の大気圧プラズマ源では困難なSi系高機能薄膜の高能率作製プロセスの創成を目指したものであり,研究代表者の知る限りにおいて他に同様の試みは見られない.低温・高速・高品質成膜に適した大気圧プラズマとはどのようなものかが実質的に明らかになりつつあり,この意味で,本研究の学術的意義は大きいといえる.本研究の成果を大気圧プラズマの実用化に繋げていけば,将来のフレキシブルエレクトロニクスへのみならず,種々の基材上への高能率の機能性コーティング技術開発にも貢献でき,その社会的意義も大きいと考える.

Report

(6 results)
  • 2018 Annual Research Report   Final Research Report ( PDF )
  • 2017 Annual Research Report
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (39 results)

All 2019 2018 2017 2016 2015 2014

All Journal Article (5 results) (of which Peer Reviewed: 5 results,  Acknowledgement Compliant: 3 results) Presentation (34 results) (of which Int'l Joint Research: 5 results,  Invited: 1 results)

  • [Journal Article] Controllability of structural and electrical properties of silicon films grown in atmospheric-pressure very high-frequency plasma2018

    • Author(s)
      H. Kakiuchi, H. Ohmi, and K. Yasutake
    • Journal Title

      J. Phys. D: Appl. Phys.

      Volume: 51 Issue: 35 Pages: 355203-355203

    • DOI

      10.1088/1361-6463/aad47c

    • Related Report
      2018 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of plasma impedance of microwave plasma system by electric field simulation2017

    • Author(s)
      M. Shuto, H. Ohmi, H. Kakiuchi, T. Yamada, and K. Yasutake
    • Journal Title

      J. Appl. Phys.

      Volume: 122 Issue: 4 Pages: 0433031-8

    • DOI

      10.1063/1.4993902

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Atmospheric Pressure Plasmas: Low-Temperature Processes2016

    • Author(s)
      H. Kakiuchi, H. Ohmi, and K. Yasutake
    • Journal Title

      Encyclopedia of Plasma Technology

      Volume: 1 Pages: 82-91

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Characterization of Si and SiOx films deposited in very high-frequency excited atmospheric-pressure plasma and their application to bottom-gate thin film transistors2015

    • Author(s)
      H. Kakiuchi, H. Ohmi, T. Yamada, S. Tamaki, T. Sakaguchi, W. Lin, and K. Yasutake
    • Journal Title

      Phys. Status Solidi A

      Volume: 212 Issue: 7 Pages: 1571-1577

    • DOI

      10.1002/pssa.201532328

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Characterization of Si and SiOx films deposited in very high-frequency excited atmospheric-pressure plasma and their application to bottom-gate thin film transistors2015

    • Author(s)
      H. Kakiuchi, H. Ohmi, T. Yamada, S. Tamaki, T. Sakaguchi, W. Lin, and K. Yasutake
    • Journal Title

      Phys. Stat. Sol. (a)

      Volume: 212

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] 大気圧プラズマCVDを用いたSiOx機能性コーティング技術の開発2019

    • Author(s)
      前川将哉,山崎啓史,大参宏昌,垣内弘章,安武潔
    • Organizer
      2019年度精密工学会春季大会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるプラスチックフィルム上へのSi成膜とその特性評価2019

    • Author(s)
      縄田慈人,前川健史,垣内弘章,大参宏昌,安武潔
    • Organizer
      2019年度精密工学会春季大会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるPENフィルム上へのSiOx薄膜形成とその評価2018

    • Author(s)
      前川将哉,山崎啓史,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2018年度関西地方定期学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧プラズマCVDにより形成したSi薄膜の構造・電気的特性と成膜パラメータの相関2018

    • Author(s)
      縄田慈人,前川健史,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2018年度関西地方定期学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧プラズマ装置の電磁場シミュレーションとプラズマパラメータ解析 -ヘリウム及びヘリウム酸素混合プラズマの内部パラメータ比較-2018

    • Author(s)
      田中恭輔,吉田和史,首藤光利,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2018年度関西地方定期学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧プラズマCVDにより形成した微結晶Siの高品質化の検討2018

    • Author(s)
      前川健史,縄田慈人,垣内弘章,大参宏昌,安武潔
    • Organizer
      2018年度精密工学会秋季大会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] SiOx薄膜のTFTゲート絶縁膜への応用と機能性コーティングプロセスの研究2018

    • Author(s)
      山崎啓史,前川将哉,大参宏昌,垣内弘章,安武潔
    • Organizer
      2018年度精密工学会秋季大会学術講演会
    • Related Report
      2018 Annual Research Report
  • [Presentation] 大気圧下におけるプラズマ生成と薄膜作製プロセスへの応用2018

    • Author(s)
      垣内弘章,大参宏昌,安武潔
    • Organizer
      2018年度精密工学会秋季大会学術講演会
    • Related Report
      2018 Annual Research Report
    • Invited
  • [Presentation] フレキシブルデバイスへの応用を目指した大気圧プラズマCVDによるSiOxゲート絶縁膜形成プロセスの研究2018

    • Author(s)
      山崎啓史,木元雄一朗,寺脇功士,前川健史,大参宏昌,垣内弘章,安武潔
    • Organizer
      2018年度精密工学会春季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるSiOxゲート絶縁膜の低温・高能率形成プロセスの研究2018

    • Author(s)
      木元雄一朗,寺脇功士,山崎啓史,前川健史,大参宏昌,垣内弘章,安武潔
    • Organizer
      第65回応用物理学会春季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Structural and electrical characterization of silicon and silicon oxide films prepared in atmospheric-pressure very high-frequency plasma at low temperatures2017

    • Author(s)
      H. Kakiuchi, H. Ohmi, and K. Yasutake
    • Organizer
      The 21st International Colloquium on Plasma Process
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気圧プラズマCVDによるSi低温成膜プロセスにおける投入電力のパルス変調の効果2017

    • Author(s)
      前川健史,寺脇功士,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会2017年度関西支部定期学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 低温薄膜トランジスタに向けた大気圧プラズマCVDによるSiOxゲート絶縁膜形成プロセスの研究2017

    • Author(s)
      木元雄一朗,寺脇功士,鎌田航平,山崎啓史,大参宏昌,垣内弘章,安武潔
    • Organizer
      2017年度精密工学会秋季大会学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気圧プラズマ装置の電磁場シミュレーションとプラズマパラメータ解析2017

    • Author(s)
      田中恭輔,吉田和史,首藤光利,大参宏昌,垣内弘章,安武潔
    • Organizer
      2017年度精密工学会秋季大会学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Siの大気圧プラズマCVDプロセスにおける投入電力のパルス変調の効果2017

    • Author(s)
      寺脇功士,前川健史,大参宏昌,垣内弘章,安武潔
    • Organizer
      2017年度精密工学会秋季大会学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるSiOxゲート絶縁膜の形成プロセスの開発2017

    • Author(s)
      木元雄一朗,寺脇功士,山崎啓史,前川健史,大参宏昌,垣内弘章,安武潔
    • Organizer
      第78回応用物理学会秋季学術講演会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 大気圧プラズマ装置の電磁場シミュレーションとプラズマパラメータ解析 -酸化パラメータと酸化膜特性の関係-2017

    • Author(s)
      田中恭輔,吉田和史,首藤光利,大参宏昌,垣内弘章,安武潔
    • Organizer
      2018年度精密工学会春季大会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 低温TFTに向けた大気圧プラズマCVDによるSi成膜プロセスの研究2016

    • Author(s)
      田牧祥吾,寺脇功士,木元雄一朗,鎌田航平,大参宏昌,垣内弘章,安武潔
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大気圧プロセスCVDによるSiOxゲート絶縁膜の低温形成と構造・特性評価2016

    • Author(s)
      木元雄一朗,田牧祥吾,寺脇功士,鎌田航平,大参宏昌,垣内弘章,安武潔
    • Organizer
      第77回応用物理学会秋季学術講演会
    • Place of Presentation
      朱鷺メッセ
    • Year and Date
      2016-09-13
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるSiおよびSiOxの高速成膜とTFTの作製・評価2016

    • Author(s)
      寺脇功士,田牧祥吾,木元雄一朗,鎌田航平,大参宏昌,垣内弘章,安武潔
    • Organizer
      2016年度精密工学会秋季大会
    • Place of Presentation
      茨城大学
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大気圧プラズマCVDによるSiの高速成膜とTFTの特性評価2016

    • Author(s)
      寺脇功士,田牧祥吾,木元雄一朗,鎌田航平,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2016年度関西地方定期学術講演会
    • Place of Presentation
      (株)島津製作所
    • Related Report
      2016 Annual Research Report
  • [Presentation] 大気圧プラズマCVDにより形成したSiOx薄膜の構造・電気特性の基板温度依存性2016

    • Author(s)
      鎌田航平,木元雄一朗,田牧祥吾,寺脇功士,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2016年度関西地方定期学術講演会
    • Place of Presentation
      (株)島津製作所
    • Related Report
      2016 Annual Research Report
  • [Presentation] 電磁場解析による高圧力プラズマの電子密度算出手法の開発2016

    • Author(s)
      田中恭輔,鈴木貴之,首藤光利,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2016年度関西地方定期学術講演会
    • Place of Presentation
      (株)島津製作所
    • Related Report
      2016 Annual Research Report
  • [Presentation] Investigation on the deposition characteristics of silicon and silicon oxide thin films in atmospheric-pressure very high-frequency plasma for their application to thin film transistors2015

    • Author(s)
      H. Kakiuchi, H. Ohmi, T. Yamada, W. Lin, T. Sakaguchi, S. Tamaki, K. Yasutake
    • Organizer
      20th Biennial European Conference on Chemical Vapor Deposition (EuroCVD 20)
    • Place of Presentation
      Festhalle Seepark Sempach, Switzerland
    • Year and Date
      2015-07-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Silicon oxide thin films prepared with high rates at room temperature using atmospheric-pressure very high-frequency plasma2015

    • Author(s)
      T. Sakaguchi, S. Tamaki, W. Lin, T. Yamada, H. Ohmi, H. Kakiuchi, K. Yasutake
    • Organizer
      20th Biennial European Conference on Chemical Vapor Deposition (EuroCVD 20)
    • Place of Presentation
      Festhalle Seepark Sempach, Switzerland
    • Year and Date
      2015-07-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Study on the growth of silicon films in very high-frequency plasma under atmospheric pressure2015

    • Author(s)
      S. Tamaki, T. Sakaguchi, W. Lin, T. Yamada, H. Ohmi, H. Kakiuchi, K. Yasutake
    • Organizer
      20th Biennial European Conference on Chemical Vapor Deposition (EuroCVD 20)
    • Place of Presentation
      Festhalle Seepark Sempach, Switzerland
    • Year and Date
      2015-07-13
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Characterization of Si films deposited at 220 C in atmospheric-pressure very high-frequency plasma and their application to thin film transistors2015

    • Author(s)
      H. Kakiuchi, H. Ohmi, S. Tamaki, T. Sakaguchi, W. Lin, and K. Yasutake
    • Organizer
      22nd International Symposium on Plasma Chemistry (ISPC 2015)
    • Place of Presentation
      University of Antwerp, Belgium
    • Year and Date
      2015-07-05
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 大気圧・超高周波プラズマを用いたSiの低温・高速成膜技術の研究2015

    • Author(s)
      寺脇功士,木元雄一朗,田牧祥吾,坂口尭之,大参宏昌,垣内弘章,安武 潔
    • Organizer
      精密工学会 2015年度関西地方定期学術講演会
    • Place of Presentation
      京都工芸繊維大学 松ヶ崎キャンパス
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] HMDSOを原料とした大気圧プラズマCVDによるSiOx薄膜の常温・高速形成とその評価2015

    • Author(s)
      木元雄一朗,寺脇功士,田牧祥吾,坂口尭之,大参宏昌,垣内弘章,安武 潔
    • Organizer
      精密工学会 2015年度関西地方定期学術講演会
    • Place of Presentation
      京都工芸繊維大学 松ヶ崎キャンパス
    • Year and Date
      2015-06-23
    • Related Report
      2015 Annual Research Report
  • [Presentation] 大気圧VHFプラズマによるSiの低温・高速成膜技術の開発-TFT特性に対する電極長さの影響-2015

    • Author(s)
      坂口尭之,林威成,田牧祥吾,山田高寛,大参宏昌,垣内弘章,安武 潔
    • Organizer
      2015年度 精密工学会春季大会学術講演会
    • Place of Presentation
      東洋大学 白山キャンパス
    • Year and Date
      2015-03-17 – 2015-03-19
    • Related Report
      2014 Annual Research Report
  • [Presentation] Room Temperature Deposition of Silicon Oxide Films with High Rates Using Atmosphere-Pressure Very High-Frequency Plasma2014

    • Author(s)
      T. Sakaguchi, S. Tamaki, W. Lin, T. Yamada, H. Ohmi, H. Kakiuchi, and K. Yasutake
    • Organizer
      2nd KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Knowledge Capital Congres Convention Center, Osaka
    • Year and Date
      2014-12-10 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] Low Temperature Deposition of Silicon Films Using Very High-Frequency Plasma under Atmospheric Pressure2014

    • Author(s)
      S. Tamaki, T. Sakaguchi, W. Lin, T. Yamada, H. Ohmi, H. Kakiuchi, and K. Yasutake
    • Organizer
      2nd KANSAI Nanoscience and Nanotechnology International Symposium
    • Place of Presentation
      Knowledge Capital Congres Convention Center, Osaka
    • Year and Date
      2014-12-10 – 2014-12-11
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気圧VHFプラズマによるSi及びSiOx の低温・高速成膜と薄膜トランジスタ特性評価2014

    • Author(s)
      林威成,田牧祥吾,坂口尭之,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      2014年度 精密工学会秋季大会学術講演会
    • Place of Presentation
      鳥取大学 鳥取キャンパス
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] 大気圧VHFプラズマによる低温下(60-120 ℃)でのSi薄膜形成と薄膜トランジスタ特性評価2014

    • Author(s)
      田牧祥吾,坂口尭之,林威成,山田高寛,大参宏昌,垣内弘章,安武潔
    • Organizer
      精密工学会 2014年度関西地方定期学術講演会
    • Place of Presentation
      近畿大学 東大阪キャンパス
    • Year and Date
      2014-07-04
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2020-03-30  

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