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Production of biomass-derived chemicals using intramolecular hydrogen transfer hydrogenolysis

Research Project

Project/Area Number 26249121
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Catalyst/Resource chemical process
Research InstitutionTohoku University

Principal Investigator

TOMISHIGE KEIICHI  東北大学, 工学研究科, 教授 (50262051)

Co-Investigator(Renkei-kenkyūsha) NAKAGAWA YOSHINAO  東北大学, 大学院工学研究科, 准教授 (10436545)
TAMURA MASAZUMI  東北大学, 大学院工学研究科, 助教 (10635551)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥41,730,000 (Direct Cost: ¥32,100,000、Indirect Cost: ¥9,630,000)
Fiscal Year 2016: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2015: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2014: ¥18,590,000 (Direct Cost: ¥14,300,000、Indirect Cost: ¥4,290,000)
Keywordsバイオマス / 水素化分解 / 脱水素 / 水素移行 / 触媒 / 改質 / 化成品
Outline of Final Research Achievements

Organic chemicals including resins and polymers have been produced mainly from petrolium. In order to conduct a sustainable society, one of important subjects is the development of environment-bengin method for the production of chemicals. One of the remarkably efficient methods is the production of various chemicals from biomass is to recude the oxygen content in the biomass-derived substrate. Usually, high pressure hydrogen is used for the reduction. In this research, the purpose is to develop the catalysts for C-O hydrogenolysis using the intramolecular hydrogen transfer, and it is found that MoOx-modified Rh metal catalysts was very effective to this reaction system.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (24 results)

All 2017 2016 2015

All Journal Article (14 results) (of which Peer Reviewed: 14 results,  Acknowledgement Compliant: 9 results) Presentation (10 results) (of which Int'l Joint Research: 4 results,  Invited: 4 results)

  • [Journal Article] Catalytic conversion of sorbitol to gasoline-ranged products without external hydrogen over Pt-modified Ir-ReOx/SiO22016

    • Author(s)
      Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige
    • Journal Title

      Catal. Today

      Volume: 269 Pages: 122-131

    • DOI

      10.1016/j.cattod.2015.10.023

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Hydrogenation of dicarboxylic acids to diols over Re-Pd catalysts2016

    • Author(s)
      Y. Takeda, M. Tamura, Y. Nakagawa, K. Okumura and K. Tomishige
    • Journal Title

      Catal. Sci. Technol.

      Volume: accepted Issue: 14 Pages: 5668-5683

    • DOI

      10.1039/c6cy00335d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deoxydehydration with Molecular Hydrogen over Ceria-Supported Rhenium Catalyst with Gold Promoter2016

    • Author(s)
      Shuhei Tazawa, Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura,Keiichi Tomishige
    • Journal Title

      ACS Catal.

      Volume: 6 Issue: 10 Pages: 6393-6397

    • DOI

      10.1021/acscatal.6b01864

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective hydrodeoxygenation of 2-furancarboxylic acid to valeric acid over molybdenum-oxide-modified platinum catalyst2016

    • Author(s)
      Takehiro Asano, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      ACS Sustainable Chem. Eng.

      Volume: 4 Issue: 12 Pages: 6253-6257

    • DOI

      10.1021/acssuschemeng.6b01640

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Demethoxylation of guaiacol and methoxybenzenes over carbon-supported Ru-Mn catalyst2016

    • Author(s)
      Momoko Ishikawa, Masazumi Tamura, Yoshinao Nakagawa, Keiichi Tomishige
    • Journal Title

      Applied Catalysis B: Environmental

      Volume: 182 Pages: 193-203

    • DOI

      10.1016/j.apcatb.2015.09.021

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Selective transformation of hemicellulose (xylan) into n-pentane, pentanols or xylitol over a rhenium-modified iridium catalyst combined with acids2016

    • Author(s)
      Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige
    • Journal Title

      Green Chem.

      Volume: 18 Issue: 1 Pages: 165-175

    • DOI

      10.1039/c5gc02183a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Production of Renewable Hexanols from Mechanocatalytically Depolymerized Cellulose by Using Ir-ReOx/SiO2 catalyst2015

    • Author(s)
      Sibao Liu, Yasuyo Okuyama, Masazumi Tamura, Yoshinao Nakagawa, Akio Imai, Keiichi Tomishige
    • Journal Title

      ChemSusChem

      Volume: 8 Issue: 4 Pages: 628-635

    • DOI

      10.1002/cssc.201403010

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic Total Hydrodeoxygenation of Biomass-Derived Polyfunctionalized Substrates to Alkanes2015

    • Author(s)
      Yoshinao Nakagawa, Sibao Liu, Masazumi Tamura, Keiichi Tomishige
    • Journal Title

      ChemSusChem

      Volume: 8 Issue: 7 Pages: 1114-1132

    • DOI

      10.1002/cssc.201403330

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective hydrogenation of lactic acid to 1,2-propanediol over highly active Ru-MoOx catalysts2015

    • Author(s)
      Y. Takeda, T. Shoji, H. Watanabe, M. Tamura, Y. Nakagawa, K. Okumura and K. Tomishige
    • Journal Title

      ChemSusChem

      Volume: 8 Issue: 7 Pages: 1170-1178

    • DOI

      10.1002/cssc.201403011

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Characterization of Re-Pd/SiO2 catalysts for hydrogenation of stearic acid2015

    • Author(s)
      Yasuyuki Takeda, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige
    • Journal Title

      ACS Catal.

      Volume: 5 Issue: 11 Pages: 7034-7047

    • DOI

      10.1021/acscatal.5b01054

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Catalytic Conversions of Furfural to Pentanediols2015

    • Author(s)
      Yoshinao Nakagawa, Masazumi Tamura, Keiichi Tomishige
    • Journal Title

      Catal. Surv. Asia

      Volume: 19 Issue: 4 Pages: 249-256

    • DOI

      10.1007/s10563-015-9194-2

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Insight into the Mechanism of Hydrogenation of Amino Acids to Amino Alcohols Catalyzed by a Heterogeneous MoOx-Modified Rh Catalyst2015

    • Author(s)
      M. Tamura, R. Tamura, Y. Takeda, Y. Nakagawa and K. Tomishige
    • Journal Title

      Chem. Eur. J.

      Volume: 21 Issue: 7 Pages: 3097-3107

    • DOI

      10.1002/chem.201405769

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support2015

    • Author(s)
      Nobuhiko Ota, Masazumi Tamura, Yoshinao Nakagawa, Kazu Okumura, Keiichi Tomishige
    • Journal Title

      Angew. Chem.

      Volume: 54 Issue: 6 Pages: 1897-1900

    • DOI

      10.1002/anie.201410352

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Combination of supported bimetallic rhodium-molybdenum catalyst and cerium oxide for hydrogenation of amide2015

    • Author(s)
      Yoshinao Nakagawa, Riku Tamura, Masazumi Tamura, Keiichi Tomishige
    • Journal Title

      Sci. Technol. Adv. Mater.

      Volume: 16 Issue: 1 Pages: 014901-014901

    • DOI

      10.1088/1468-6996/16/1/014901

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Deoxydehydration of vicinal OH groups with H2 catalyzed by metal-modified ReOx/CeO2 catalysts for the production of biomass-derived chemicals2017

    • Author(s)
      Keiichi Tomishige, Masazumi Tamura, Yoshinao Nakagawa
    • Organizer
      7th Asia-Pacific Congress on Catalysis
    • Place of Presentation
      ムンバイ、インド
    • Year and Date
      2017-01-18
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Catalyst development for the production of biomass-derived chemicals by selective C-O hydrogenolysis and hydrodeoxygenation2016

    • Author(s)
      Keiichi Tomishige
    • Organizer
      16th International Congress on Catalysis
    • Place of Presentation
      北京、中国
    • Year and Date
      2016-07-05
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Selective Transformation of Cellulose and Xylan into Alkanes and Mono-Alcohols over Rhenium-Modified Iridium Catalyst Combined with Acids2016

    • Author(s)
      Keiichi Tomishige
    • Organizer
      International Symposium on Catalytic Conversion of Biomass
    • Place of Presentation
      台北、台湾
    • Year and Date
      2016-06-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of heterogeneous metal catalysts for the production of biomass-derived chemicals2015

    • Author(s)
      Keiichi Tomishige
    • Organizer
      Pacifichem 2015
    • Place of Presentation
      ホノルル(アメリカ)
    • Year and Date
      2015-12-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 水素化脱酸素用ReOx-Pd/CeO2触媒のX線分光を用いた構造解析2015

    • Author(s)
      太田 伸彦・田村 正純・中川 善直・冨重 圭一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Selective production of n-hexane from cellulose by using Ir-ReOx/SiO2 + HZSM-5 catalysts2015

    • Author(s)
      SIBAO, Liu; MASAZUMI, Tamura; YOSHINAO, Nakagawa; KEIICHI, Tomishige
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Hydrogenation of lactic acid to 1,2-propanediol over Ru-MoOx/C catalyst2015

    • Author(s)
      TAKEDA, Yauyuki; SHOJI, Tomohiro; TAMURA, Masazumi; NAKAGAWA, Yoshinao; TOMISHIGE, Keiichi
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Mo酸化物修飾Rh触媒を用いた1,4-アンヒドロエリスリトールからのブタノール類合成2015

    • Author(s)
      荒井 貴博・田村 正純・中川 善直・冨重 圭一
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] Partial hydrogenolysis of vicinal cis-diols over Pd-added W catalyst2015

    • Author(s)
      NAKAGAWA, Yoshinao; AMADA, Yasushi; OTA, Nobuhiko; TAMURA, Masazumi; TOMISHIGE, Keiichi
    • Organizer
      日本化学会第95春季年会
    • Place of Presentation
      日大船橋キャンパス(千葉県船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属酸化物修飾Rh触媒によるアミノ酸の水素化2015

    • Author(s)
      田村 正純・中川 善直・冨重 圭一
    • Organizer
      第115回触媒討論会
    • Place of Presentation
      成蹊大学(東京都武蔵野市)
    • Year and Date
      2015-03-23 – 2015-03-24
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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