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Nanofabrication of Organic Molecules by Single Particle Triggered Linear Polymerization

Research Project

Project/Area Number 26249145
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionKyoto University (2015-2017)
Osaka University (2014)

Principal Investigator

SEKI Shu  京都大学, 工学研究科, 教授 (30273709)

Co-Investigator(Kenkyū-buntansha) 櫻井 庸明  京都大学, 工学研究科, 助教 (50632907)
佐伯 昭紀  大阪大学, 工学(系)研究科(研究院), 准教授 (10362625)
Research Collaborator YAMAKI Tetsuya  量子科学技術研究機構, 上席研究員 (10354937)
SUGIMOTO Masaki  量子科学技術研究機構, 上席研究員 (90354943)
SAITO Yuichi  量子科学技術研究機構, 次長 (40360424)
CHIBA Atsuya  量子科学技術研究機構, 主幹研究員 (40370431)
TAKESHITA Yuki  大阪大学, 大学院工学研究科, 大学院生
HORIO Akifumi  大阪大学, 大学院工学研究科, 大学院生
KAYAMA Kazuto  京都大学, 大学院工学研究科, 大学院生
SAKAGUCHI Shugo  京都大学, 大学院工学研究科, 大学院生
Project Period (FY) 2014-04-01 – 2018-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥41,080,000 (Direct Cost: ¥31,600,000、Indirect Cost: ¥9,480,000)
Fiscal Year 2017: ¥6,630,000 (Direct Cost: ¥5,100,000、Indirect Cost: ¥1,530,000)
Fiscal Year 2016: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000)
Fiscal Year 2015: ¥11,570,000 (Direct Cost: ¥8,900,000、Indirect Cost: ¥2,670,000)
Fiscal Year 2014: ¥16,510,000 (Direct Cost: ¥12,700,000、Indirect Cost: ¥3,810,000)
Keywordsナノワイヤー / 粒子線 / 固相重合 / センサー / エネルギー変換 / 単一粒子 / STLiP / SPNT / ナノワイヤ / 線形重合 / クラスター / 昇華 / イオントラック / ナノワイヤ― / 高エネルギー粒子 / 次元制御重合 / イオンビーム / センシング / トラック / 1次元 / ポルフィリン
Outline of Final Research Achievements

In this study, we have established a series of versatile techniques to lead 1-dimensional nanostructures via high energy charged particle induced chemical reactions, particularly the polymerization of organic molecules within nm-sized cylindrical particle tracks. The technique is referred as Single-particle Triggered Linear Polymerization (STLiP). Long chains in polymers that can variously change their conformations dominantly determine the characteristics and advantages of polymer materials such as mechanical property, thermal stability, solubility and processability, and so on. Since the radius of gyration for a polymer chain is in the range of several nanometers, it has been a more suitable target than a small molecule to characterize its conformation and size. The 1-dimensional nanostructures derived from the present study have been successfully demonstrated as the key material platforms for opto-electronic and/or sensing devices, reflecting their extraordinary wide surface area.

Report

(5 results)
  • 2017 Annual Research Report   Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (42 results)

All 2018 2017 2016 2015 2014 Other

All Int'l Joint Research (3 results) Journal Article (20 results) (of which Int'l Joint Research: 7 results,  Peer Reviewed: 20 results,  Open Access: 9 results,  Acknowledgement Compliant: 8 results) Presentation (15 results) (of which Int'l Joint Research: 5 results,  Invited: 8 results) Book (1 results) Remarks (3 results)

  • [Int'l Joint Research] IUAC/Amity University(インド)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] GSI Helmholtzzentrum Darmstadt(ドイツ)

    • Related Report
      2017 Annual Research Report
  • [Int'l Joint Research] Inter University Accelerator Center(India)

    • Related Report
      2016 Annual Research Report
  • [Journal Article] Remarkable Effect of Halogenation of Aromatic Compounds on Efficiency of Nanowire Formation through Polymerization/Crosslinking by High-Energy Single Particle Irradiation2018

    • Author(s)
      Akifumi Horio, Tsuneaki Sakurai, Kazuto Kayama, G. B. V. S. Lakshmi, Devesh Kumar Avasthi, Masaki Sugimoto, Tetsuya Yamaki, Atsuya Chiba, Yuichi Saito, Shu Seki
    • Journal Title

      Radiation Physics and Chemistry

      Volume: 142 Pages: 100-106

    • DOI

      10.1016/j.radphyschem.2017.02.052

    • Related Report
      2017 Annual Research Report 2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fabrication of Au nanoparticles on poly(vinylpyrrolidone) nanowires exhibiting reversible frequency change of localized surface plasmon resonance2018

    • Author(s)
      S. Tsukuda, S. Seki, M Omichi, M. Sugimoto, A. Idesaki, T. Sekino, T. Omata
    • Journal Title

      AIP Advances

      Volume: 8 Issue: 1 Pages: 015314-015314

    • DOI

      10.1063/1.5001553

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Electron-Transporting Foldable Alternating Copolymers of Perylenediimide and Flexible Macromolecular Chains2018

    • Author(s)
      T. Sakurai, N. Orito, S. Nagano, K. Kato, M. Takata, S. Seki
    • Journal Title

      Materials Chemistry Frontiers

      Volume: 2 Issue: 4 Pages: 718-729

    • DOI

      10.1039/c7qm00616k

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Donor/Acceptor Segregated π-Stacking Arrays by Use of Shish-Kebab-Type Polymeric Backbones: Highly Conductive Discotic2017

    • Author(s)
      T. Sakurai, S. Yoneda, S. Sakaguchi, K. Kato, M. Takata, S. Seki
    • Journal Title

      Macromolecules

      Volume: 50 Issue: 23 Pages: 9265-9275

    • DOI

      10.1021/acs.macromol.7b02020

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cooperative Supramolecular Polymerization of a Perylene Diimide Derivative and its Impact on Electron-transporting Property2017

    • Author(s)
      Dipankar Basak, Deep Sankar Pal, Tsuneaki Sakurai, Satoru Yoneda, Shu Seki, Suhrit Ghosh
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 19 Issue: 46 Pages: 31024-31029

    • DOI

      10.1039/c7cp06298b

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Control over differentiation of a metastable supramolecular assembly in one and two dimensions2017

    • Author(s)
      T. Fukui, S. Kawai, S. Fujinuma, Y. Matsushita, T. Yasuda, T. Sakurai, S. Seki, M. Takeuchi, K. Sugiyasu
    • Journal Title

      Nature Chem.

      Volume: 9 Issue: 5 Pages: 493-499

    • DOI

      10.1038/nchem.2684

    • Related Report
      2017 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation of Nanowires by Single Particle-Triggered Linear Polymerization of Solid-State Aromatic Molecules2016

    • Author(s)
      A. Horio, T. Sakurai, G.B.V.S. Lakshmi, D. K. Avasthi, M. Sugimoto, T. Yamaki, S. Seki
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 32 Pages: 14925-14931

    • DOI

      10.1039/c6nr03297d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fabrication of Fluorescent Nanowires via High-Energy Particles-Triggered Polymerization Reactions2016

    • Author(s)
      A. Horio, T. Sakurai, V. S. Padalkar, D. Sakamaki, T. Yamaki, M. Sugimoto, S. Seki
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 29 Issue: 3 Pages: 373-377

    • DOI

      10.2494/photopolymer.29.373

    • NAID

      130005256595

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Anisotropic swelling of hydrogel nanowires based on poly(vinylpyrrolidone) fabricated by single-particle nanofabrication technique2016

    • Author(s)
      S. Tsukuda, M. Omichi, M. Sugimoto, A. Idesaki, V. S. Padalkar, S. Seki
    • Journal Title

      J. Polym. Sci. Polym. Phys.

      Volume: 54 Issue: 19 Pages: 1950-1956

    • DOI

      10.1002/polb.24100

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fabrication of ‘Clickable’ Polyfluorene Nanowires with High Aspect Ratio as Biological Sensing Platforms2016

    • Author(s)
      T. Wasin, K. Enomoto, T. Sakurai, V. Padalkar, H. Cheng, M. Tang, A. Horio, D., Sakamaki, M. Omichi, A. Saeki, K. Kikuchi, Y. Hori, A. Chiba, Y. Saito, T. Kamiya, M. Sugimoto, S. Seki
    • Journal Title

      ACS Sensors

      Volume: 6 Issue: 6 Pages: 766-774

    • DOI

      10.1021/acssensors.6b00070

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Fabrication of Pt nanoparticle incorporated polymer nanowires by high energy ion and electron beam irradiation2016

    • Author(s)
      S. Tsukuda, R. Takahasi, S. Seki, M. Sugimoto, A. Idesaki, M. Yoshikawa, S. Tanaka
    • Journal Title

      Radiation Physics and Chemistry

      Volume: 118 Pages: 16-20

    • DOI

      10.1016/j.radphyschem.2015.05.029

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Polymerization of Room-Temperature Ionic Liquid Monomers by Electron Beam Irradiation with the Aim of Fabricating Three-Dimensional Micropolymer/Nanopolymer Structures2015

    • Author(s)
      H. Minamimoto, H. Irie, T. Uematsu, T. Tsuda, A. Imanishi, S. Seki, S. Kuwabata
    • Journal Title

      Langmuir

      Volume: 31(14) Issue: 14 Pages: 4281-4289

    • DOI

      10.1021/la503252p

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fabrication of Thermoresponsive Nanoactinia Tentacles by a Single Particle Nanofabrication Technique2015

    • Author(s)
      Masaaki Omichi, Hiromi Marui, Vikas Sudam Padalkar, Akifumi Horio, Satoshi Tsukuda, Masaki Sugimoto, Shu Seki
    • Journal Title

      Langmuir

      Volume: 31 Issue: 42 Pages: 11692-11700

    • DOI

      10.1021/acs.langmuir.5b02962

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Fine Patterning of Silver Metal by Electron Beam Irradiation onto Room-temperature Ionic Liquid2015

    • Author(s)
      H. Minamimoto, H. Irie, T. Uematsu, T. Tsuda, A. Imanishi, S. Seki, S. Kuwabata
    • Journal Title

      Chemistry Letters

      Volume: 44 Issue: 3 Pages: 312-314

    • DOI

      10.1246/cl.141037

    • NAID

      130004868383

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Reversible Control of Radius and Morphology of Fluorene-Azobenzene Copolymer Nanowires by Light Exposure2015

    • Author(s)
      Cheng H, Tang M, Washin T, Enomoto K, Chiba A, Saito Y, Kamiya T, Sugimoto M, Saeki A, Sakurai T, Omichi M, Sakamaki D, and Seki S
    • Journal Title

      Advanced Materials Interfaces

      Volume: 2 Issue: 1 Pages: 1400450-1400450

    • DOI

      10.1002/admi.201400450

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Systematic Studies on Side-Chain Structures of Phthalocyaninato-Polysiloxanes: Polymerization and Self-Assembling Behaviors2015

    • Author(s)
      Satoru Yoneda, Tsuneaki Sakurai, Toru Nakayama, Kenichi Kato, Masaki Takata, Shu Seki
    • Journal Title

      Journal of Porphyrins and Phthalocyanines

      Volume: 19 Issue: 01-03 Pages: 160-170

    • DOI

      10.1142/s1088424614501053

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Formation Of Nanowires From Pentacene Derivatives By Single-particle Triggered Linear Polymerization2015

    • Author(s)
      Y. Takeshita, T. Sakurai, A. Asano, K. Takano, M. Omichi, M. Sugimoto, S. Seki
    • Journal Title

      Adv. Mater. Lett.

      Volume: 6 Issue: 2 Pages: 99-103

    • DOI

      10.5185/amlett.2015.5720

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Simple and Rapid Method for High-Resolution Visualization of Single-Ion Tracks2014

    • Author(s)
      M. Omichi, W. Choi, D. Sakamaki, S. Tsukuda, M. Sugimoto, S. Seki
    • Journal Title

      AIP Advances

      Volume: 4 Issue: 11 Pages: 1-8

    • DOI

      10.1063/1.4902164

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Fabrication of enzyme-degradable and size-controlled protein nanowires using the single particle nano-fabrication technique2014

    • Author(s)
      M. Omichi, A. Asano, S. Tsukuda, K. Takano, M. Sugimoto, A. Saeki, D. Sakamaki, A. Onoda, T. Hayashi, S. Seki
    • Journal Title

      Nature Communications

      Volume: 5 Issue: 1 Pages: 1-8

    • DOI

      10.1038/ncomms4718

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Spatial Point Analysis of Ion Track Patterns using Common Polymer Films by Atomic Forced Microscopy2014

    • Author(s)
      M. Omichi, W. Choi, S. Tsukuda, M. Sugimoto, S. Seki
    • Journal Title

      Journal of Photopolymer Science and Technology

      Volume: 27 Issue: 5 Pages: 561-564

    • DOI

      10.2494/photopolymer.27.561

    • NAID

      130004691084

    • ISSN
      0914-9244, 1349-6336
    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access
  • [Presentation] Organic Functional Nanomaterials by Single Particle Triggered Linear Polymerization2017

    • Author(s)
      Shu Seki, Tsuneaki Sakurai
    • Organizer
      International Conference on Accelerators in Materials and Medical Sciences
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Development of Organic Nanowires Formed through Chemical Reactions Triggered by High-Energy Charged Particle Irradiation2017

    • Author(s)
      Tsuneaki Sakurai
    • Organizer
      10th China-Japan Joint Symposium on Functional Supramolecular Systems
    • Related Report
      2017 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 高エネルギー荷電粒子照射が誘起する固相重合反応を用いた垂直配向有機ナノワイヤの形成2017

    • Author(s)
      香山 一登, 櫻井 庸明, 杉本 雅樹, 八巻 哲也, 関 修平
    • Organizer
      第60回放射線化学討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] 高エネルギー荷電粒子照射による有機化合物の固相重合反応とナノ構造体の形成2017

    • Author(s)
      櫻井 庸明, 香山一登, 関 修平
    • Organizer
      第66回高分子討論会
    • Related Report
      2017 Annual Research Report
  • [Presentation] Organic Functional Nanomaterials by Single Particle Triggered Linear Polymerization2016

    • Author(s)
      Shu Seki
    • Organizer
      International Conference on Ion Beams in Materials Engineering and Characterizations (IBMEC 2016)
    • Place of Presentation
      Delhi, India
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Observation of Nanowires via Ion Beam-Triggered Intra-Track Polymerization of π-Conjugated2015

    • Author(s)
      Tsuneaki Sakurai, Akifumi Horio, Yuki Takeshita, Shu Seki
    • Organizer
      25th Annual Meeting of MRS-J (2015)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      2015-12-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low Dimensional Nanostructures Produced by High Energy Single Particle2015

    • Author(s)
      Shu Seki
    • Organizer
      International Conference on Nanostructuring by Ion Beams 2015 (ICNIB2015)
    • Place of Presentation
      Agra, India
    • Year and Date
      2015-11-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 単一粒子固相重合法によるソフトマテリアルとクラスターイオンビームの相互作用の可視化2015

    • Author(s)
      櫻井 庸明, 堀尾 明史, 竹下 友輝, 千葉 敦也, 斎藤 勇一, 関 修平
    • Organizer
      第10回高崎量子応用シンポジウム
    • Place of Presentation
      高崎シティギャラリー, 高崎
    • Year and Date
      2015-10-08
    • Related Report
      2015 Annual Research Report
  • [Presentation] 高エネルギー粒子線照射を利用した低分子重合/高分子架橋反応によるナノ構造体形成技術2015

    • Author(s)
      櫻井 庸明, 竹下 友輝, 堀尾 明史, 関 修平
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] 粒子線による芳香族アミンの線形固相重合とナノワイヤの形成2015

    • Author(s)
      堀尾 明史, 櫻井 庸明, 関 修平
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] Development of Semiconducting Nanowires via Ion Beam-Triggered Intra-Track Polymerization of π-Conjugated Molecules2014

    • Author(s)
      櫻井庸明、竹下友輝、杉本雅樹、関修平
    • Organizer
      第24回日本MRS年次大会
    • Place of Presentation
      横浜市開港記念館(神奈川県横浜市)
    • Year and Date
      2014-12-10 – 2014-12-12
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Control of Morphology of Protein and Photo-Switchable Nanowires2014

    • Author(s)
      Shu Seki
    • Organizer
      International Conference on Swift Heavy Ions in Materials Engineering and Characterization 2014
    • Place of Presentation
      Inter-University Accelerator Centre, New Delhi, India
    • Year and Date
      2014-10-14 – 2014-10-17
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] クラスターイオンビームを用いたナノワイヤの形成とその飛跡の可視化2014

    • Author(s)
      竹下友輝、櫻井庸明、榎本一之、関 修平、千葉敦也、齋藤勇一、出崎 亮、杉本雅樹、大道正明
    • Organizer
      第9回高崎量子応用研究シンポジウム
    • Place of Presentation
      高崎シティギャラリー(群馬県高崎市)
    • Year and Date
      2014-10-09 – 2014-10-10
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高エネルギー単一粒子を用いた低分子材料の一次元固相重合とナノワイヤーの構築2014

    • Author(s)
      竹下 友輝・櫻井庸明・関 修平
    • Organizer
      第63回高分子討論会
    • Place of Presentation
      長崎大学(長崎県長崎市)
    • Year and Date
      2014-09-24 – 2014-09-26
    • Related Report
      2014 Annual Research Report
  • [Presentation] Development of Semiconducting Nanowires via Ion Beam-Triggered Intra-Track Polymerization of π-Conjugated Small Molecules2014

    • Author(s)
      Tsuneaki Sakurai, Yuki Takeshita, Masaki Sugimoto, and Shu Seki
    • Organizer
      The 15th IUMRS-International Conference in Asia (IUMRS-ICA 2014)
    • Place of Presentation
      Fukuoka University(福岡県福岡市)
    • Year and Date
      2014-08-24 – 2014-08-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] “High Energy Charged Particles: Their Chemistry and Use as Versatile Tools for Nanofabrication”2015

    • Author(s)
      Shu Seki, Tsuneaki Sakurai, Masaaki Omichi, Akinori Saeki, Daisuke Sakamaki
    • Total Pages
      74
    • Publisher
      Springer-Verlag GmbH
    • Related Report
      2015 Annual Research Report
  • [Remarks] Lab. Research

    • URL

      http://www.moleng.kyoto-u.ac.jp/~moleng_06/research/index.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 荷電粒子による1次元ナノ空間内固相重合法(STLiP)

    • URL

      http://www.chem.eng.osaka-u.ac.jp/~cmpc-lab/research/index.html

    • Related Report
      2014 Annual Research Report
  • [Remarks] 荷電粒子による1次元ナノ空間内固相重合法(STLiP)

    • URL

      http://www.moleng.kyoto-u.ac.jp/~moleng_06/research/index.html

    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2019-03-29  

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