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Fundamental aspects of photothermal processes arising from interaction of lasers with noble metal nanoparticles

Research Project

Project/Area Number 26286004
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Nanostructural chemistry
Research InstitutionThe University of Tokushima

Principal Investigator

Hashimoto Shuichi  徳島大学, 大学院理工学研究部, 教授 (70208445)

Co-Investigator(Kenkyū-buntansha) 柳谷 伸一郎  徳島大学, ソシオテクノサイエンス研究部, 助教 (40314851)
梶本 真司  東北大学, 理学研究科, 助教 (80463769)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥16,120,000 (Direct Cost: ¥12,400,000、Indirect Cost: ¥3,720,000)
Fiscal Year 2016: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2015: ¥5,590,000 (Direct Cost: ¥4,300,000、Indirect Cost: ¥1,290,000)
Fiscal Year 2014: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Keywordsナノ材料 / 貴金属ナノ粒子 / レーザー / 光熱効果 / プラズモン / 金ナノ粒子
Outline of Final Research Achievements

Gold nanoparticles exhibit strong absorption and scattering by interacting with visible light, kown as surface plasmon resonance (LSPR). LSPR decays nonradiatively resulting in particle heating and heat transfer to the surroundings. This photothermal effect attracted much attension because of potential therapytic appication to cancer. We perfomed fundamental researches on this effect to aquire basic knowledge for possible applications. We measured with transient absorption spectroscopy the dynamics: nucleation, growth and colape of photothermal bubbles. The experinental observation was interpreted by the temperature calculation. We also performed sigle particle spectroscopy to measure the Rayleigh light scattering scectra under continuous laser illumination. We observed the phase transtions of a single gold nanoparticle depending on laser fluence. The single particle spectroscopy revealed the phase separation of thermoresponsive polymers around a gold nanoparticle under illunmination.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (22 results)

All 2017 2016 2015 2014 Other

All Journal Article (4 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 4 results,  Acknowledgement Compliant: 4 results,  Open Access: 2 results) Presentation (17 results) (of which Int'l Joint Research: 4 results,  Invited: 5 results) Remarks (1 results)

  • [Journal Article] Plasmonic-heating-induced nanofabrication on glass substrates2016

    • Author(s)
      Y. Osaka; S. Sugano, S. Hashimoto
    • Journal Title

      Nanoscale

      Volume: 8 Issue: 42 Pages: 18187-18196

    • DOI

      10.1039/c6nr06543k

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Plasmonic-heating-induced nanoscale phase separation of free poly(N-Isopropylacrylamide) molecules.2016

    • Author(s)
      I. Aibara, S. Mukai, S. Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 31 Pages: 17745-17752

    • DOI

      10.1021/acs.jpcc.6b04265

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Laser-driven phase transitions in aqueous colloidal gold nanoparticles under high pressure: Picosecond pump-probe study2016

    • Author(s)
      Shuichi Hashimoto, Tetsuro Katayama, Kenji Setoura, Takayuki Uwada and Hiroshi Miyasaka
    • Journal Title

      Physical Chemistry Chemical Physics

      Volume: 18 Issue: 6 Pages: 4994-5004

    • DOI

      10.1039/c5cp07395b

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Plasmonic Nanofabrication through Optical Heating2016

    • Author(s)
      Matthias Enders, Shinya Mukai, Takayuki Uwada and Shuichi Hashimoto
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 120 Issue: 12 Pages: 6723-6732

    • DOI

      10.1021/acs.jpcc.5b11762

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] ナノ粒子とレーザーの相互作用における光熱変換プロセス2017

    • Author(s)
      橋本 修一
    • Organizer
      レーザー学会学術講演会第37回年次大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市)
    • Year and Date
      2017-01-07
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Plasmonic heating induced phase separation and accumulation of poly(N-isopropylacrylamide) around a single gold nanoparticle.2016

    • Author(s)
      Issei Aibara, Shinya Mukai, Shuichi Hashimoto
    • Organizer
      9th Asian & Oceanian Photochemistry Conference
    • Place of Presentation
      Nanyan Technological University (Singapore)
    • Year and Date
      2016-12-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] 金ナノ粒子とレーザーの相互作用:プラズモン加熱と応用2016

    • Author(s)
      橋本 修一
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学常三島キャンパス(徳島県徳島市
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] 単一金ナノ粒子のレーザー加熱によるポリN-イソプロピルアクリルアミドの相分離と集積2016

    • Author(s)
      相原 一生, 向井 真也, 橋本 修一
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学駒場(東京都目黒区)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] 金ナノ粒子を用いたガラスのレーザー加工2016

    • Author(s)
      大坂 勇貴, 菅野 智士, 橋本 修一
    • Organizer
      2016年光化学討論会
    • Place of Presentation
      東京大学(東京都目黒区)
    • Year and Date
      2016-09-05
    • Related Report
      2016 Annual Research Report
  • [Presentation] Transient extinction spectroscopic study on laser-gold nanoparticle interaction2016

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      4th Conference on Advanced Nanoparticle Generation and Excitation by Lasers in Liquids (ANGEL 2016)
    • Place of Presentation
      Essen, Germany
    • Year and Date
      2016-05-09
    • Related Report
      2016 Annual Research Report
  • [Presentation] レーザー照射による多孔質シリコンのフォトルミネッセンス特性の変化2015

    • Author(s)
      稲田 貴郁, 橋本 修一, 中村 俊博
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単一金ナノ粒子周囲媒体中における熱勾配に沿ったコロイド粒子の移動2015

    • Author(s)
      向井 真也, 瀬戸浦 健仁, 橋本 修一
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単一金ナノ粒子のプラズモンバンド励起による電子移動の観測2015

    • Author(s)
      黒木 菜緒, 手塚 美彦, 橋本 修一
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Plasmonic tunig of single gold nanoparticles by colloidal accretion through nanoscale heating2015

    • Author(s)
      Matthias Enders, Shinya Mukai and Shuichi Hashimoto
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 金ナノ粒子を用いたナノリング構造の作製とその光学特性2015

    • Author(s)
      大坂 勇貴, 橋本 修一
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Pulsed-laser-induced phase transition of aqueous colloidal gold nanoparticles at high pressure: Picosecond pump-probe study2015

    • Author(s)
      Shuichi Hashimoto, Tetsuro Katayama, Kenji Setoura and Hiroshi Miyasaka
    • Organizer
      2015 光化学討論会
    • Place of Presentation
      大阪市立大学(大阪府大阪市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Picosecond time-resolved measurement of bubble and evaporation dynamics induced by photo-excitation of gold nanoparticles2015

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      The 11-th Korea Japan Symopsium on Frontier Photosciences
    • Place of Presentation
      Jeju, Korea
    • Year and Date
      2015-06-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Laser-induced picosecond-to-nanosecond dynamics of aqueous colloidal gold nanoparticles2015

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      Program and Technical Digenst: The 7th International Congress on Laser Advanced Materials Processing
    • Place of Presentation
      福岡県小倉市
    • Year and Date
      2015-05-26
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Plasmonic heating of single gold nanoparticles at multi-interfaces2015

    • Author(s)
      Shuichi Hashimoto
    • Organizer
      Molecular Plasmonics 2015
    • Place of Presentation
      Jena, Germany
    • Year and Date
      2015-05-07
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] プラズモニックバブルの光学顕微鏡とAFMによるハイブリッド観察2015

    • Author(s)
      柳谷伸一郎、堀内加奈、橋本修一、後藤信夫
    • Organizer
      第62回応用物理学会春季学術講演会
    • Place of Presentation
      東海大学湘南キャンパス(神奈川県平塚市)
    • Year and Date
      2015-03-13
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金ナノ粒子のレーザー加熱によるプラズモニックナノバブルの原子間力顕微鏡観察2014

    • Author(s)
      柳谷伸一郎、堀内加奈、橋本修一、後藤信夫
    • Organizer
      2014年光化学討論会
    • Place of Presentation
      北海道大学札幌キャンパス(北海道札幌市)
    • Year and Date
      2014-10-12
    • Related Report
      2014 Annual Research Report
  • [Remarks] レーザーナノサイエンス研究室

    • URL

      http://www.opt.tokushima-u.ac.jp/lab/a-3/hashimoto/index.html

    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2018-03-22  

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