Super ion conductive materials using two dimensional nanospace in polymer assembly

• Project/Area Number: 26286010
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Nanomaterials chemistry
• Research Institution: Yamagata University
• Principal Investigator: Matsui Jun 山形大学, 理学部, 教授 (50361184)
• Co-Investigator(Kenkyū-buntansha): 永野 修作 名古屋大学, 工学研究科, 准教授 (40362264) ; 源明 誠 富山大学, 大学院理工学研究部(工学), 准教授 (70334711)
• Project Period (FY): 2014-04-01 – 2019-03-31
• Project Status: Completed (Fiscal Year 2018)
• Budget Amount: ¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000); Fiscal Year 2017: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000); Fiscal Year 2016: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000); Fiscal Year 2015: ¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000); Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
• Keywords: ２次元空間 / プロトン伝導 / 生体膜 / ラメラ構造 / 二次元プロトン伝導 / ナノ空間 / 高速プロトン伝導 / 二次元ナノ空間 / 階層構造 / 高分子電解質 / 2次元伝導 / ナノプロトニクス / 燃料電池 / 二次元界面

Outline of Final Research Achievements

In this project we prepared high proton conductive polymer electrolytes using two-dimensional (2D) nanospace as a proton conduction channel. The interlayer in lamellar structured polymer films were utilized as the 2D nanospace and proton source such as carboxylic acid and phosphonic acid were incorporated to form the proton conduction channel. The proton conductivities of the films were comparable to the state-of-art Nafion membranes even their acid dissociation constant (pKa) are much smaller (~4 for carboxylic acid and ~2 for phosphonic acid) than Nafion (~-6). The dependency of proton source concentration to the proton conductivity revealed that the high proton conductivity was achieved because the proton sources were arranged at the optimum distance in angstrom level at the two-dimensional nanospace.

Academic Significance and Societal Importance of the Research Achievements

プロトン伝導性高分子電解質は次世代のクリーンエネルギーである水素を利用した固体高分子形燃料電池に必須の部材である。これまでは、高いプロトン伝導性を達成するためには超強酸が必須と考えられ、その結果触媒、セルなどの周辺部材に大きな制限があった。本研究結果により２次元ナノ空間を利用することで、カルボン酸のような弱酸を用いても実用的に十分なプロトン伝導度を達成できることを証明した。これより、固体高分子形燃料電池の普及に寄与できる。さらに、２次元ナノ空間と生体膜界面の構造が類似していることから、生体のエネルギー生産機構解明についても貢献でた成果である。

Research Products

• [Int'l Joint Research] Johannes Kepler University(オーストリア)
• [Journal Article] Biomimetic polyelectrolytes based on polymer nanosheet films and their proton-conduction mechanism (2019)
  • Author(s): Mayu Tsukamoto, Kazuki Ebata, Hiroshi Sakiyama, Shunsuke Yamamoto, Masaya Mitsuishi, Tokuji Miyashita, and Jun Matsui
  • Journal Title: Langmuir Volume: 35 Issue: 9 Pages: 3302-3307
  • DOI: 10.1021/acs.langmuir.8b04079
  • Peer Reviewed
• [Journal Article] Electrochemical Charge Storage Using Layer-by-Layer Deposited Film Composed of Redox Polymer and Inorganic Nanoparticle (2018)
  • Author(s): Kayaba Yuki、Hojyo Kenta、Ono Kenta、Ishizaki Manabu、Kanaizuka Katsuhiko、Kondo Shin-ichi、Kurihara Masato、Mistuishi Masaya、Matsui Jun
  • Journal Title: Journal of Photopolymer Science and Technology Volume: 31 Issue: 3 Pages: 349-352
  • DOI: 10.2494/photopolymer.31.349
  • NAID: 130007481509
  • ISSN: 0914-9244, 1349-6336
  • Year and Date: 2018-06-25
  • Peer Reviewed
• [Journal Article] Synthesis and photochemical response of Ru(ii)-coordinated double-decker silsesquioxane (2018)
  • Author(s): Kucuk Asuman Celik、Matsui Jun、Miyashita Tokuji
  • Journal Title: RSC Advances Volume: 8 Issue: 4 Pages: 2148-2156
  • DOI: 10.1039/c7ra12290j
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Highly Ordered Lamellar Formation in Dodecylacrylate Copolymer by Humid Annealing (2018)
  • Author(s): Matsunaga Kohei、Tanaka Keiko、Matsui Jun
  • Journal Title: Chemistry Letters Volume: 47 Issue: 4 Pages: 500-502
  • DOI: 10.1246/cl.171188
  • NAID: 130006638934
  • Peer Reviewed
• [Journal Article] High-Density and Monolayer-Level Integration of π-Conjugated Units: Amphiphilic Carbazole Homopolymer Langmuir?Blodgett Films (2018)
  • Author(s): Yamamoto Shunsuke、Nishina Nanae、Matsui Jun、Miyashita Tokuji、Mitsuishi Masaya
  • Journal Title: Langmuir Volume: 34 Issue: 36 Pages: 10491-10497
  • DOI: 10.1021/acs.langmuir.8b01694
  • Peer Reviewed
• [Journal Article] Resistive non-volatile memories fabricated with poly(vinylidene fluoride)/poly(thiophene) blend nanosheets (2018)
  • Author(s): Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi.
  • Journal Title: RSC Advances Volume: 8 Issue: 15 Pages: 7963-7968
  • DOI: 10.1039/c8ra01143e
  • Peer Reviewed / Open Access
• [Journal Article] In-plane oriented highly ordered lamellar structure formation of poly(N-dodecylacrylamide) induced by humid annealing (2017)
  • Author(s): Yuki Hashimoto, Takuma Sato, Ryosuke Goto, Yuki Nagao, Masaya Mitsuishi, Shusaku Nagano and Jun Matsui
  • Journal Title: RSC Advances Volume: 7 Issue: 11 Pages: 6631-6635
  • DOI: 10.1039/c6ra27994e
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Supramolecular Polymer of Near-Infrared Luminescent Porphyrin Glass (2017)
  • Author(s): Mitsuhiko Morisue,* Yuki Hoshino, Masaki Shimizu, Takayuki Nakanishi, Yasuchika Hasegawa, Md. Amran Hossain, Shinichi Sakurai, Sono Sasaki, Shinobu Uemura, Jun Matsui
  • Journal Title: Macromolecules Volume: 50 Issue: 8 Pages: 3186-3192
  • DOI: 10.1021/acs.macromol.7b00316
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A metal-lustrous porphyrin foil (2017)
  • Author(s): Morisue Mitsuhiko、Hoshino Yuki、Shimizu Masaki、Tomita Shogo、Sasaki Sono、Sakurai Shinichi、Hikima Takaaki、Kawamura Ayaka、Kohri Michinari、Matsui Jun、Yamao Takeshi
  • Journal Title: Chemical Communications Volume: 53 Issue: 77 Pages: 10703-10706
  • DOI: 10.1039/c7cc06159e
  • Peer Reviewed
• [Journal Article] Amorphous Porphyrin Glasses Exhibit Near-Infrared Excimer Luminescence (2017)
  • Author(s): Mitsuhiko Morisue,* Ikuya Ueno, Takayuki Nakanishil, Takafumi Matsui, Sono Sasaki, Masaki Shimizu, Jun Matsui, Yasuchika Hasegawa
  • Journal Title: RSC Advances Volume: 7 Issue: 37 Pages: 22679-22683
  • DOI: 10.1039/c7ra02752d
  • NAID: 120006309134
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Acid-Group-Content-Dependent Proton Conductivity Mechanisms at the Interlayer of Poly(N-dodecylacrylamide-co-acrylic acid) Copolymer Multilayer Nanosheet Films (2017)
  • Author(s): Sato Takuma、Tsukamoto Mayu、Yamamoto Shunsuke、Mitsuishi Masaya、Miyashita Tokuji、Nagano Shusaku、Matsui Jun
  • Journal Title: Langmuir Volume: 33 Issue: 45 Pages: 12897-12902
  • DOI: 10.1021/acs.langmuir.7b03160
  • Peer Reviewed
• [Journal Article] Liesegang Mechanism with a Gradual Phase Transition (2017)
  • Author(s): Y. Shimizu, J. Matsui, K. Unoura, H. Nabika
  • Journal Title: J. Phys. Chem. B Volume: - Issue: 11 Pages: 2495-2501
  • DOI: 10.1021/acs.jpcb.7b01275
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Organic microboxes prepared by self-assembly of a carge-transfer dye (2017)
  • Author(s): Ayaka Toba, Jun Matsui, Ken-ichi Nakayama, Tsukasa Yoshida, Cigdem Yumusak, Philipp Stadler, Markus Clark Scharber, Matthew Schuette White, Niyazi Serdar Sariciftci, Akito Masuhara
  • Journal Title: Chemistry Letters Volume: 46 Issue: 4 Pages: 557-559
  • DOI: 10.1246/cl.161191
  • NAID: 130005549072
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Size control of CH3NH3PbBr3 perovskite cuboid fine crystals synthesized by ligand-free reprecipitation method (2017)
  • Author(s): Umemoto Kazuki、Pu Yong-Jin、Yumusak Cigdem、Scharber Markus Clark、White Matthew Schuette、Sariciftci Niyazi Serdar、Yoshida Tsukasa、Matsui Jun、Uji-i Hiroshi、Masuhara Akito
  • Journal Title: Microsystem Technologies Volume: 24 Issue: 1 Pages: 619-623
  • DOI: 10.1007/s00542-017-3412-y
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Regioselective Synthesis of Eight-Armed Cyclosiloxane Amphiphile for Functional 2D and 3D Assembly Motifs (2017)
  • Author(s): Zhu Huie、Akkus Buket、Gao Yu、Liu Yida、Yamamoto Shunsuke、Matsui Jun、Miyashita Tokuji、Mitsuishi Masaya
  • Journal Title: ACS Applied Materials & Interfaces Volume: 9 Issue: 34 Pages: 28144-28150
  • DOI: 10.1021/acsami.7b07331
  • Peer Reviewed
• [Journal Article] C60nanocrystals thin film with controlled density. (2016)
  • Author(s): Morizane, S.; Matsukawa, T.; Matsui, J.; Masuhara, A.,
  • Journal Title: Mol. Cryst. Liq. Cryst. Volume: 629 Issue: 1 Pages: 243-247
  • DOI: 10.1080/15421406.2015.1096494
  • Peer Reviewed
• [Journal Article] Proton Conductivities of Lamellae-forming Bio-inspired Block Copolymer Thin Films Containing Silver Nanoparticles (2016)
  • Author(s): H. Yabu, J. Matsui, M. Hara, S. Nagano, Y. Matsuo, Y. Nagao
  • Journal Title: Langmuir Volume: 32 Issue: 37 Pages: 9484-9491
  • DOI: 10.1021/acs.langmuir.6b02521
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Highly Oriented Poly(vinylidene fluoride-co-trifluoroethylene) Ultrathin Films with Improved Ferroelectricity (2016)
  • Author(s): Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, and Masaya Mitsuishi
  • Journal Title: RSC Advances Volume: 6 Issue: 38 Pages: 32007-32012
  • DOI: 10.1039/c6ra03785b
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] High Proton Conductivity in the Molecular Interlayer of a Polymer Nanosheet Multilayer Film (2015)
  • Author(s): T. Sato, Y. Hayasaka, M. Mitsuishi, T. Miyashita, S. Nagano, J. Matsui
  • Journal Title: Langmuir Volume: 31 Issue: 18 Pages: 5174-5180
  • DOI: 10.1021/acs.langmuir.5b00036
  • Peer Reviewed
• [Journal Article] Self-assembly of Amphiphilic POSS Anchoring a Short Organic Tail with Uniform Structure (2015)
  • Author(s): Misaki Takeda, Keita Kuroiwa, Masaya Mitsuishi, and Jun Matsui
  • Journal Title: Chemistry Letters Volume: 44(11) Issue: 11 Pages: 1560-1562
  • DOI: 10.1246/cl.150680
  • NAID: 130005108070
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Solvent dependent properties of poly(vinylidene fluoride) monolayers at the air-water interface (2015)
  • Author(s): Huie Zhu, Shunsuke Yamamoto, Jun Matsui, Tokuji Miyashita, Masaya Mitsuishi
  • Journal Title: Soft Matter Volume: 11 Issue: 10 Pages: 1962-1972
  • DOI: 10.1039/c4sm02800g
  • Peer Reviewed / Acknowledgement Compliant
• [Presentation] Biomimetic proton conductive film prepared by ultra thin polymer self assembly (2018)
  • Author(s): ◯Mayu Tsukamoto, Jun Matsui, Shunsuke Yamamoto, Tokuji Miyashita, and Masaya Mitsuishi
  • Organizer: 18th International Symposium on Advanced Organic Photonics
  • Int'l Joint Research
• [Presentation] Multicolor electrochromism in a single electrode using Layer-by-Layer hybrid film prepared from redox polymer and inorganic nanoparticles (2018)
  • Author(s): ◯Yuki Kayaba, Kenta Hojo, Kenta Ono, Manabu Ishizaki, Katsuhiko Kanaizuka, Shin-ichi Kondo, Masato Kurihara, Masaya Mitsuishi, Jun Matsui
  • Organizer: 18th International Symposium on Advanced Organic Photonics
  • Int'l Joint Research
• [Presentation] Construction of hierarchical structure in block copolymer using nano and micro phase separation (2018)
  • Author(s): Sachiho Ito, Kohei Matsunaga, Jun Matsui, Shunsuke Yamamoto, Masaya Mitsuishi, Shusaku Nagano, Hiroshi Yabu
  • Organizer: 18th International Symposium on Advanced Organic Photonics
  • Int'l Joint Research
• [Presentation] 生体模を倣膜した高分子電解質の２次元プロトン伝導機構 (2018)
  • Author(s): ◯塚本 真由、松井 淳、山本 俊介、三ツ石 方也、宮下 徳治
  • Organizer: 第67回高分子討論会
• [Presentation] ナノおよひ_ミクロ相分離を用いたフ_ロックコホ_リマーの構造作製 (2018)
  • Author(s): ○伊藤 祥穂,松永 康平,松井 淳,山本 俊介,三ツ石 方也,永野 修作, 藪 浩
  • Organizer: 第67回高分子討論会
• [Presentation] レドックス高分子と無機ナノ粒子の階層構造化による単一電極多色エレクトロクロミズム (2018)
  • Author(s): ○萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: 第67回高分子討論会
• [Presentation] Color mixing of electrochromism in a single electrode using Layer-by-Layer hybrid film prepared from redox polymer and inorganic nanoparticles (2018)
  • Author(s): ◯Yuki Kayaba, Kenta Hojo, Kenta Ono, Manabu Ishizaki, Katsuhiko Kanaizuka, Shin-ichi Kondo, Masato Kurihara, Masaya Mitsuishi, Jun Matsui
  • Organizer: KJF-ICOMEP 2018
  • Int'l Joint Research
• [Presentation] Construction of nanophase separation structure in block copolymer thin film using humidifying annealing method (2018)
  • Author(s): ○Sachiho Ito, Kohei Matsunaga, Jun Matsui, Shunsuke Yamamoto, Masaya Mitsuishi, Shusaku Nagano
  • Organizer: KJF-ICOMEP 2018
  • Int'l Joint Research
• [Presentation] Two-Dimensional Proton Conduction in Biomimetic Polymer Electrolytes Prepared the Polymer Nanosheet Multilayer Film (2018)
  • Author(s): ◯Mayu Tsukamoto, Shunsuke Yamamoto, Masaya Mitsuishi, Tokuji Miyashita and Jun Matsui
  • Organizer: First International Conference on 4D Materials and Systems
  • Int'l Joint Research
• [Presentation] Biomimetic proton conductive film using the interlayer of polymer nanosheet assembly (2018)
  • Author(s): ◯Mayu Tsukamoto, Shunsuke Yamamoto, Masaya Mitsuishi, Tokuji Miyashita and Jun Matsui
  • Organizer: 16th International Symposium on Polymer Electrolytes
  • Int'l Joint Research
• [Presentation] ファジーな階層構造による単一電極多色エレクトロクロミズム (2018)
  • Author(s): ○萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: The 35th International Conference of Photopolymer Science and Technology
• [Presentation] 気液界面を用いたカテコール前駆体ブロックコポリマーの構造化とポストトリートメントによるテンプレートへの応用 (2018)
  • Author(s): ○伊藤祥穂・松井淳・永野修作・藪浩
  • Organizer: 第65回応用物理学会 春季学術講演会
• [Presentation] 生体膜を模倣した高分子電解質の2次元プロトン伝導 (2018)
  • Author(s): ○塚本真由1，松井淳2, 山本俊介3, 宮下徳治3, 三ツ石方也3
  • Organizer: 第65回応用物理学会 春季学術講演会
• [Presentation] レドックス高分子と無機ナノ粒子との交互積層膜を利用した単一電極多色エレクトロクロミズム (2018)
  • Author(s): ○萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: 第65回応用物理学会 春季学術講演会
• [Presentation] 束縛場を利用したブロックコポリマーテンプレートの構築 (2018)
  • Author(s): ○伊藤祥穂・松永康平・松井淳・藪浩
  • Organizer: SATテクノロジー・ショーケース2018
• [Presentation] Amorphous Lamellar Film Prepared From Comb-like Polymers Using a Humid Annealing Method (2018)
  • Author(s): Jun Matsui
  • Organizer: The 7th International Symposium of Green MAP Center and LPIC
  • Invited
• [Presentation] 溶媒アニールによるくし形高分子の階層構造化 (2018)
  • Author(s): 松井淳
  • Organizer: ナノマテリアルコロキウム
  • Invited
• [Presentation] 水との相互作用を利用した高分子の階層構造化 (2018)
  • Author(s): 松井淳
  • Organizer: 平成29年度溶液化学勉強会講演会
  • Invited
• [Presentation] ホスホン酸基を導入した高分子ナノシートの二次元界面におけるプロトン伝導 (2017)
  • Author(s): 塚本真由.江端一輝,山本俊介, 三ツ石方也, 松井淳, 宮下徳治
  • Organizer: 第67回高分子学会年次大会
• [Presentation] ポテンシャル勾配制御された交互積層膜を用いた多色エレクトロクロミズム (2017)
  • Author(s): 萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: 第67回高分子学会年次大会
• [Presentation] 加湿アニール法による高配向ラメラ構造膜の構築とイオン伝導材料への応用 (2017)
  • Author(s): 江端一輝, 橋本 侑宜, 後藤 崚介, 長尾 祐樹,, 山本 俊介, 三ツ石 方也, 永野 修作, 松井 淳
  • Organizer: 第67回高分子学会年次大会
• [Presentation] 高分子薄膜の積層構造に基づく多色エレクトロクロミズム (2017)
  • Author(s): 松井淳
  • Organizer: 2017年光化学討論会
  • Invited
• [Presentation] 加湿アニール法を用いた非晶性高分子ブロックからなる両親媒性高分子によるナノ相分離構造薄膜の作製 (2017)
  • Author(s): 松永康平, 松井淳, 山本俊介, 三ツ石方也, 永野修作
  • Organizer: 第78回応用物理学会秋季学術講演会
• [Presentation] Highly oriented lamellar polymer film prepared by humid annealing (2017)
  • Author(s): 松井淳
  • Organizer: 平成29年度化学系学協会東北大会
  • Invited
• [Presentation] 塚本真由.江端一輝,山本俊介, 三ツ石方也, 松井淳, 宮下徳治 (2017)
  • Author(s): Two-Dimensional Proton Conduction Mechanism of Phosphonic Acid Group Contained Polymer Nanosheet?
  • Organizer: 平成29年度化学系学協会東北大会
• [Presentation] 赤塚亜紗美.朱慧娥,山本俊介, 三ツ石方也, 宮下徳治,源明誠,永野修作,松井淳 (2017)
  • Author(s): Structure of hybrid nanoplate composed of amphiphilic polyhedral oligomeric silsesquioxane
  • Organizer: 平成29年度化学系学協会東北大会
• [Presentation] 高分子ナノシート積層体が形成する2次元ナノ空間を利用したプロトン伝導膜の作製 (2017)
  • Author(s): 塚本真由, 松井淳, 永野修作, ,山本俊介, 三ツ石方也, 宮下徳治
  • Organizer: 第66回高分子討論会
• [Presentation] 加湿アニール法を用いた両親媒性高分子の高配向ラメラ構造膜とその異方イオン伝導性 (2017)
  • Author(s): 江端一輝・後藤崚介・長尾祐樹・山本俊介・三ツ石方也・永野修作・松井淳
  • Organizer: 第66回高分子討論会
• [Presentation] 加湿アニール法を用いたpoly(N-dodecyl acrylamide)-b-poly(ethylene glycol) 薄膜におけるナノ相分離構造の構築 (2017)
  • Author(s): 松永康平, 松井淳, 山本俊介, 三ツ石方也, 永野修作
  • Organizer: 第66回高分子討論会
• [Presentation] Humid Annealed Method to Prepare Vertically Oriented Hexagonal Cylinders Film Using Poly(N-dodecyl acrylamide)-b-poly(ethylene glycol) (2017)
  • Author(s): Kohei Matsunaga, Jun Matsui, Shunsuke Yamamoto, Masaya Mitsuishi
  • Organizer: SmaSys 2017
  • Int'l Joint Research
• [Presentation] 交互積層ハイブリッド薄膜を用いた多色エレクトロクロミズム (2017)
  • Author(s): 萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: 2017高分子学会東北支部研究発表会
• [Presentation] ポテンシャル勾配制御された交互積層ハイブリッド膜を用いた多色エレクトロクロミズム (2017)
  • Author(s): 萱場裕貴・北條健太・小野健太・石崎学・金井塚勝彦・近藤慎一・栗原正人・三ツ石方也・松井淳
  • Organizer: 第26回ポリマー材料フォーラム
• [Presentation] 高分子ナノシートを用いた2次元プロトン伝導膜の構築 (2017)
  • Author(s): 塚本真由・江端一輝・松井淳・山本俊介・宮下徳治・三ツ石方也
  • Organizer: 第43回固体イオニクス討論会
• [Presentation] 加湿アニール法により両親媒性高分子が形成する一軸配向ラメラ構造を用いた異方イオン伝導 (2017)
  • Author(s): 江端一輝・後藤崚介・長尾祐樹・山本俊介・三ツ石方也・永野修作・松井淳
  • Organizer: 第43回固体イオニクス討論会
• [Presentation] 高分子による配列，閉じ込めで生み出す電気化学機能 (2017)
  • Author(s): 松井淳
  • Organizer: 高分子学会東北支部会員増強対策講演会
• [Presentation] 水が誘起する poly(N-dodecyl acrylamide)の均一ラメラ構造形成 (2016)
  • Author(s): 橋本侑宜, 佐藤琢磨, 永野修作, 長尾祐樹, 山本俊介, 三ツ石方也, 松井淳
  • Organizer: 第65回高分子学会年次大会
• [Presentation] Poly(N-alkylacrylamide)の水環境下における 一軸配向ラメラ構造形成に対するアルキル側鎖依存性 (2016)
  • Author(s): 江端一輝, 橋本侑宜, 佐藤琢磨, 永野修作, 長尾祐樹, 山本俊介, 三ツ石方也, 松井淳
  • Organizer: 第65回高分子学会年次大会
• [Presentation] 粒子共存制御ラジカル重合法によるプロトン伝導性フィラーを用いた高分子電解質膜 (2016)
  • Author(s): 志藤慶治, 松井淳, 有田稔彦, 増原陽人
  • Organizer: 第67回高分子学会年次大会
• [Presentation] Uniform lamellar structure formation of pDDA-b-PEG by humidty anealing (2016)
  • Author(s): Kohei Matsunaga, Shunsuke Yamamoto, Masaya Mitsuishi , Jun Matsui
  • Organizer: 平成28年度化学系学協会東北大会
• [Presentation] Poly(N-alkylacrylamide)が水中で形成するラメラ構造の 解析とイオニクス材料への展開 (2016)
  • Author(s): 江端一輝, 後藤崚介, 永野修作, 長尾祐樹, 山本俊介, 三ツ石方也, 松井淳
  • Organizer: 第65回高分子討論会
• [Presentation] 加湿アニールによる poly(N-dodecyl acrylamide)のラメラ構造化機構 (2016)
  • Author(s): 橋本侑宜, 後藤崚介, 長尾祐樹, 山本俊介, 三ツ石方也, 永野修作, 松井淳
  • Organizer: 第65回高分子討論会
• [Presentation] High proton conductivity in two-dimenensional nanospace of polymer ultrathin film assembly (2016)
  • Author(s): Jun Matsui
  • Organizer: The 3rd Angel Symposium
  • Int'l Joint Research / Invited
• [Presentation] 水が誘起する両親媒性アモルファスポリマーのラメラ構造化 (2015)
  • Author(s): 橋本侑宜, 江端一輝, 佐藤琢磨, 永野修作, 長尾祐樹, 山本俊介, 三ツ石方也, 松井淳
  • Organizer: 第15回多元物質科学研究所研究発表会
  • Place of Presentation: 東北大学桜ホール
  • Year and Date: 2015-12-22
• [Presentation] C60 nanocrystals thin film by liquid-liquid interface assembly technique (2015)
  • Author(s): Saki Morizane, Masaki Takeda, Jun Matsui, Akito Masuhar
  • Organizer: Pacifichem2015
  • Place of Presentation: Hawaii Convention center, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Enhancement of proton transport in an oriented polypeptide thin film (2015)
  • Author(s): Salinthip Laokroekkiat, Yuki Nagao, Jun Matsui, Takashi Abe, Hirotsugu Hiramatsu, Hitoshi Yamamoto, Tokuji Miyashita
  • Organizer: Pacifichem2015
  • Place of Presentation: Hawaii Convention center, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Organic nanocrystals and these layered structure for organic solar cells (2015)
  • Author(s): Akito Masuhara, Keiji Shito, Saki Morizane, Atsushi Ito, Ken-ichi Nakayama, Tsukasa Yoshida, Jun Matsui
  • Organizer: Pacifichem2015
  • Place of Presentation: Hawaii Convention center, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] Lamellar structure formation in poly(N-dodecylacrylamide) by humidity annealing (2015)
  • Author(s): Jun Matsui, Yuki Hashimoto, Takuma Sato, Shusaku Nagano, Yuki Nagao, Masaya Mitsuishi
  • Organizer: Pacifichem2015
  • Place of Presentation: Hawaii Convention center, USA
  • Year and Date: 2015-12-15
  • Int'l Joint Research
• [Presentation] 加湿アニール法によるアモルファス高分子のラメラ構造化:アルキル側鎖がラメラ構造化に与える影響 (2015)
  • Author(s): 江端一輝, 橋本侑宜, 佐藤琢磨, 松井淳, 永野修作, 長尾祐樹, 三ツ石方也
  • Organizer: 第6回CSJ化学フェスタ-日本化学会秋季事業-
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2015-10-13
• [Presentation] 高分子Langmuir-Blodgett膜を用いた二次元プロトン伝導に及ぼすイオン性基含有率依存性 (2015)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作, 源明誠
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学川内キャンパス
  • Year and Date: 2015-09-15
  • Invited
• [Presentation] 加湿アニール法による両親媒性アモルファスポリマーのラメラ構造化 (2015)
  • Author(s): 橋本侑宜, 佐藤琢磨, 松井淳, 永野修作, 長尾祐樹, 山本俊介, 三ツ石方也
  • Organizer: 第64回高分子討論会
  • Place of Presentation: 東北大学川内キャンパス
  • Year and Date: 2015-09-15
• [Presentation] Lamellar structure formation in an amorphous amphiphilic polymer by humidity annealing (2015)
  • Author(s): Yuki Hashimoto, Takuma Sato, Jun Matsui, Shusaku Nagano, Yuki Nagao, Shunsuke Yamamoto, Masaya Mitsuishi
  • Organizer: 平成27年度化学系学協会東北大会
  • Place of Presentation: 弘前大学文京キャンパス
  • Year and Date: 2015-09-12
• [Presentation] 加湿アニール法による両親媒性高分子のラメラ構造化 (2015)
  • Author(s): 橋本侑宜, 佐藤琢磨, 松井淳, 三ツ石方也, 永野修作, 長尾祐樹
  • Organizer: 第64回高分子学会年次大会
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2015-05-27
• [Presentation] 高分子Langmuir-Blodgett膜を用いた二次元界面におけるプロトン伝導メカニズムの解明 (2015)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作, 源明誠
  • Organizer: 第64回高分子学会年次大会
  • Place of Presentation: 札幌コンベンションセンター
  • Year and Date: 2015-05-27
• [Presentation] 高分子ナノ組織体によるイオニクス材料の創製 (2014)
  • Author(s): 松井淳
  • Organizer: 超分子創製化学セミナー（第52回）
  • Place of Presentation: 立命館大学薬学部薬学科
  • Year and Date: 2014-11-25
  • Invited
• [Presentation] 高分子ナノ組織体界面を用いたプロトン輸送材料 (2014)
  • Author(s): 松井淳
  • Organizer: 高分子材料科学研究グループ第３回講演会
  • Place of Presentation: 京都工芸繊維大学 松ヶ崎キャンパス
  • Year and Date: 2014-11-19
  • Invited
• [Presentation] 高分子Langmuir-Blodgett膜を用いた界面デザインによる超イオン伝導の実現 (2014)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作, 源明誠
  • Organizer: 第4回CSJ化学フェスタ2014-日本化学会秋季事業-
  • Place of Presentation: タワーホール船堀
  • Year and Date: 2014-10-14 – 2014-10-16
• [Presentation] 高分子Langmuir-Blodgett膜を用いた界面デザインによる二次元高速プロトン伝導 (2014)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作, 源明誠
  • Organizer: 第63回高分子討論会
  • Place of Presentation: 長崎大学文教キャンパス
  • Year and Date: 2014-09-24 – 2014-09-26
• [Presentation] 高分子ナノシートを用いた異方的イオン伝導材料の創製 (2014)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作, 源明誠
  • Organizer: 平成26年度化学系学協会東北大会（米沢）
  • Place of Presentation: 山形大学工学部キャンパス
  • Year and Date: 2014-09-20 – 2014-09-21
• [Presentation] カルボキシ基を有する高分子ナノシートの構築とイオン伝導性評価 (2014)
  • Author(s): 佐藤琢磨, 松井淳, 三ツ石方也, 宮下徳治, 永野修作
  • Organizer: 第63回高分子学会年次大会
  • Place of Presentation: 名古屋国際会議場
  • Year and Date: 2014-05-28 – 2014-05-30
• [Patent(Industrial Property Rights)] イオン交換膜及び電池並びにその製造方法 (2017)
  • Inventor(s): 有田 稔彦, 増原 陽人, 松井 淳, 志藤 慶治
  • Industrial Property Rights Holder: 東北大学、山形大学
  • Industrial Property Rights Type: 特許
  • Patent Publication Number: 2017-037762
  • Filing Date: 2017