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Construction of Novel Supramolecular Nanoarrays for Photocatalytic Applications

Research Project

Project/Area Number 26286017
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Nanomaterials chemistry
Research InstitutionKeio University

Principal Investigator

Hasobe Taku  慶應義塾大学, 理工学部, 准教授 (70418698)

Co-Investigator(Renkei-kenkyūsha) SAKAI Hayato  慶應義塾大学, 理工学部, 助教 (60708486)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥15,990,000 (Direct Cost: ¥12,300,000、Indirect Cost: ¥3,690,000)
Fiscal Year 2016: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Fiscal Year 2014: ¥5,980,000 (Direct Cost: ¥4,600,000、Indirect Cost: ¥1,380,000)
Keywords分子集合体 / ナノ細孔 / ナノ細孔体 / 多孔性配位高分子 / 光物理過程 / ポルフィリン / 光エネルギー変換
Outline of Final Research Achievements

One-dimensional supramolecular columnar phases composed of porphyrins (electron donor: D) and benzo[ghi]perylenetriimides (electron acceptor: A) through triple hydrogen bonds have been successfully constructed to perform sequential light-harvesting and electron-transfer processes. A series of benzo[ghi]peryleneimide derivatives have been synthesized to examine the substituent effects such as imide and nitrile groups on the spectroscopic and electrochemical properties. The introduction of substituents onto the benzo[ghi]perylene (Bp) ring successfully enabled control of spectroscopic and electrochemical properties as compared to the non-substituted reference Bp. Then, formation of the 1 : 1 supramolecular complex between zinc porphyrin and benzo[ghi]perylenetriimide derivatives through triple hydrogen bonds was confirmed by Job’s plot of 1H NMR titration. Then, the one-dimensional supramolecular nanoarrays were successfully prepared in a mixed solvent.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (37 results)

All 2016 2015 2014 Other

All Int'l Joint Research (2 results) Journal Article (8 results) (of which Int'l Joint Research: 2 results,  Peer Reviewed: 8 results,  Acknowledgement Compliant: 7 results,  Open Access: 1 results) Presentation (26 results) (of which Int'l Joint Research: 6 results,  Invited: 11 results) Book (1 results)

  • [Int'l Joint Research] タンペレ工科大学(フィンランド)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] Tampere University of Technology(Finland)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Long-Lived Triplet Excited States of Bent-Shaped Pentacene Dimers by Intramolecular Singlet Fission2016

    • Author(s)
      T. Sakuma, H. Sakai, Y. Araki, T. Mori, T. Wada, N. V. Tkachenko, T. Hasobe
    • Journal Title

      J. Phys. Chem. A

      Volume: 120 Issue: 11 Pages: 1867-1875

    • DOI

      10.1021/acs.jpca.6b00988

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] High-Yield Triplet Excited States in Pentacene Self-Assembled Mnolayers on Gold Nanoparticle through Singlet Exciton Fission2016

    • Author(s)
      D. Kato, H. Sakai, N. V. Tkachenko, T. Hasobe
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 55 Issue: 17 Pages: 5230-5234

    • DOI

      10.1002/anie.201601421

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Controlled Excited-State Dynamics and Enhanced Fluorescence Property of Tetrasulfone[9]helicene by a Simple Synthetic Process2016

    • Author(s)
      Yamamoto, Y; Sakai, H ; Yuasa, J ; Araki, Y; Wada, T ; Sakanoue, T ; Takenobu, T ; Kawai, T; Hasobe, T
    • Journal Title

      JOURNAL OF PHYSICAL CHEMISTRY C

      Volume: 120 Issue: 13 Pages: 7421-7427

    • DOI

      10.1021/acs.jpcc.6b01123

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Control of Local Structures and Photophysical Properties of Zinc Porphyrin-Based Molecular Assemblies Structually Organized by Regioselctive Ligand Coordination2016

    • Author(s)
      T. Sakuma, H. Sakai, Y. Araki, T. Wada, T. Hasobe
    • Journal Title

      Phys. Chem. Chem. Phys.

      Volume: 18 Issue: 7 Pages: 5453-5463

    • DOI

      10.1039/c5cp07110k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Near-Infrared Photoelectrochemical Conversion via Photoinduced Charge Separation in Supramolecules of Anionic Phthalocyanines with Li+@C602015

    • Author(s)
      Kawashima, Y.; Ohkubo, K.; Blas-Ferrando, M. V.; Sakai, H.; Font-Sanchis, E.; Ortiz J.; Fernandez-Lazaro, F.; Hasobe, T.; Sastre-Santos, A.; Fukuzumi, S.
    • Journal Title

      J. Phys. Chem. B

      Volume: - Issue: 24 Pages: 7690-7697

    • DOI

      10.1021/jp5123163

    • Related Report
      2015 Annual Research Report 2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives2015

    • Author(s)
      T. Hasobe et al
    • Journal Title

      Chem. Sci.

      Volume: 6 Issue: 2 Pages: 1498-1509

    • DOI

      10.1039/c4sc02787f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Open Access / Acknowledgement Compliant
  • [Journal Article] Supramolecular photovoltaic cells utilizing inclusion complexes composed of Li+@C60 and cyclic porphyrin dimers2015

    • Author(s)
      T. Hasobe et al
    • Journal Title

      J. Porphyrins Phthalocyanines

      Volume: 19 Issue: 01-03 Pages: 242-250

    • DOI

      10.1142/s1088424614501156

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Photoelectrochemical Properties of Supramolecular Composites of an Anionic Zinc Chlorin and Li+@C60 on SnO22014

    • Author(s)
      Ohkubo, K.; Kawashima, Y.; Mase, Kentaro; Sakai, H.; Hasobe, T.; Fukuzumi, S.
    • Journal Title

      J. Porphyrins Phthalocyanines

      Volume: 18 Issue: 10n11 Pages: 982-990

    • DOI

      10.1142/s1088424614500825

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Presentation] Control of Excite-State Dynamics of Functional Supramolecular Architectures for Optical Applications2016

    • Author(s)
      Taku Hasobe
    • Organizer
      TUT University Seminar
    • Place of Presentation
      Tampere (Finland)
    • Year and Date
      2016-11-15
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Photofunctional Supramolecular Architectures Composed of Porphyrin and Polycyclic Aromatic Hydrocarbon2016

    • Author(s)
      Taku Hasobe
    • Organizer
      Ninth International Conference on Porphyrins and Phthalocyanines (ICPP-9)
    • Place of Presentation
      南京(中国)
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] π共役系分子集積体の励起状態ダイナミクス制御と機能発現2016

    • Author(s)
      羽曾部 卓
    • Organizer
      九州地区高分子若手研究会・夏の講演会
    • Place of Presentation
      アルモニーサンク(福岡県・北九州市)
    • Year and Date
      2016-07-01
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Synthesis and Photophysical Properties of Photofunctional Porphyrin Supramolecular Assemblies2016

    • Author(s)
      Taku Hasobe・Hayato Sakai
    • Organizer
      229th The Electrochemical Society Meeting
    • Place of Presentation
      San Diego(USA)
    • Year and Date
      2016-05-29
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] π電子集積構造の光機能化とエネルギー変換系への展開2016

    • Author(s)
      羽曾部 卓
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
    • Invited
  • [Presentation] 歪んだ配向を有するペンタセン二量体における分子内一重項分裂と励起ダイナミクス制御2016

    • Author(s)
      佐久間 高央・酒井 隼人・荒木 保幸・森 直・和田 健彦・TKACHENKO Nikolai・羽曾部 卓
    • Organizer
      日本化学会第96春季年会
    • Place of Presentation
      同志社大学 京田辺キャンパス(京都府・京田辺市)
    • Year and Date
      2016-03-24
    • Related Report
      2015 Annual Research Report
  • [Presentation] Control of Excite-State Dynamics and Optical Applications of Functional Supramolecular Architectures2016

    • Author(s)
      Taku Hasobe
    • Organizer
      University Research Seminar
    • Place of Presentation
      Potsdam (Germany)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 有機低分子材料のナノ・メゾスケール構造体における励起状態ダイナミクス制御と応用2016

    • Author(s)
      羽曾部 卓
    • Organizer
      高分子学会 印刷・情報記録・表示研究会および光反応・電子用材料研究会
    • Place of Presentation
      東京理科大学 森戸記念館(東京都・新宿区)
    • Related Report
      2016 Annual Research Report
    • Invited
  • [Presentation] Photofunctional supramolecular assemblies of polycyclic aromatic hydrocarbon and porphyrin derivatives2015

    • Author(s)
      Taku Hasobe
    • Organizer
      International Symposium for Photo- and Electro-Molecular Machines
    • Place of Presentation
      Toulouse(France)
    • Year and Date
      2015-10-06
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Preparation and Photophysical Properties of Molecular Architectures Composed of Polycyclic Aromatic Hydrocarbon and Porphyrin Derivatives2015

    • Author(s)
      Taku Hasobe
    • Organizer
      227th The electrochemical Society Center Meeting
    • Place of Presentation
      Chicago (USA)
    • Year and Date
      2015-05-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 合成化学的手法によるペンタセン誘導体の配向制御と光物性評 価2015

    • Author(s)
      佐久間高央・酒井隼人・羽曾部 卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ピセン、ベンゾクリセンおよび[5]ヘリセンイミド誘導体の合成 と光物性評価2015

    • Author(s)
      久保田貴 子・酒井隼人・荒木保幸・和田健彦・坂上 知・竹延大志・羽曾部 卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] 円偏光発光発現を目指した Push-Pull 型テトラチア[9]ヘリセン 誘導体の合成と光物性2015

    • Author(s)
      山本勇樹・酒井隼人・荒木保幸・和田健彦・坂上 知・竹延大志・Jatish Kumar・河合 壯・羽曾部 卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] トリアジン骨格を介した水素結合ネットワークによるポルフィ リン集合体の構造制御と光ダイナミクス評価2015

    • Author(s)
      酒井隼 人・荒木保幸・和田健彦・羽曾部卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペリレン骨格を基盤とする含窒素多環芳香族分子の合成と遷移 金属錯体への展開2015

    • Author(s)
      徳尾宏吉・酒井隼人・荒木保幸・坂 上知・和田健彦・竹延大志・羽曾部卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペリレン骨格を基盤としたドナー-アクセプター二分子連結体 の超分子構造制御と光物理過程評価2015

    • Author(s)
      堀ノ内悠希・酒 井隼人・羽曾部卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] ペンタセン修飾金属ナノ粒子の合成と光物性評価2015

    • Author(s)
      ○加藤大貴・酒井隼人・羽曾部卓
    • Organizer
      日本化学会 第95春季年会
    • Place of Presentation
      日大船橋キャンパス(船橋市)
    • Year and Date
      2015-03-26 – 2015-03-29
    • Related Report
      2014 Annual Research Report
  • [Presentation] テトラチア[9]ヘリセン誘導体の励起ダイナミクス 制御と発光特性2014

    • Author(s)
      山本 勇樹・酒井 隼人・荒木 保幸・和田 健彦・坂上 知・竹延 大志・羽曾部 卓
    • Organizer
      第4回CSJ化学フェスタ
    • Place of Presentation
      タワーホール船堀(東京都江戸川区)
    • Year and Date
      2014-10-14 – 2014-10-16
    • Related Report
      2014 Annual Research Report
  • [Presentation] ジアザペリレンおよびジアザベンゾペリレン誘導体の合成と物性評価2014

    • Author(s)
      徳尾宏吉・酒井隼人・荒木保幸・坂上知・和田健彦・竹延 大志・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 高い蛍光量子収率を有するキノキサリン縮環型テトラチア[9]ヘリセンの合成2014

    • Author(s)
      山本勇樹・酒井隼人・荒木保幸・和田健彦・坂上知・竹延 大志・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] ヘキサアザトリフェニレントリイミド―ポルフィリン超分子錯体における超高􏰁光誘起電子移動2014

    • Author(s)
      酒井隼人・青木徹・大久保敬・福住俊一・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 金属架橋型ポルフィリン集合体における構􏰀制御と光物性2014

    • Author(s)
      佐久間高央・酒井隼人・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 超分子構􏰀および励起ダイナミクス制御を目指したペリレンジイミド-フェロセン二分子連結体の合成2014

    • Author(s)
      堀ノ内悠希・酒井隼人・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] 縮環形式の異なる2つのフェナントレン骨格を含む多環芳香族炭化水素誘導体の合成と物性評価2014

    • Author(s)
      久保田貴子・酒井隼人・坂上知・竹延大志・羽曾部卓
    • Organizer
      第25回基礎有機化学討論会
    • Place of Presentation
      東北大学川内北キャンパス(仙台市)
    • Year and Date
      2014-09-07 – 2014-09-09
    • Related Report
      2014 Annual Research Report
  • [Presentation] Supramolecular Nanoarchitectures of Porphyrin Derivatives for Solar Energy Conversion and Molecular Electronics2014

    • Author(s)
      T. Hasobe
    • Organizer
      Eighth International Conference on Porphyrins and Phthalocyanines (ICPP-8)
    • Place of Presentation
      イスタンブール(トルコ)
    • Year and Date
      2014-06-22 – 2014-06-27
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Photophysical and Electrochemical Properties of Functionalized Benzo[ghi]perylene and Coronene Derivatives2014

    • Author(s)
      T. Hasobe
    • Organizer
      225th The Electrochemical Society Center Meeting
    • Place of Presentation
      オーランド(米国)
    • Year and Date
      2014-05-11 – 2014-05-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Book] Handbook of Porphrin Science2015

    • Author(s)
      T. Hasobe
    • Total Pages
      48
    • Publisher
      World Scientific Publishing Co. Pte.
    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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