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Fabrication of functional colloidal crystals containing movable inner cores with their locations controlled by external fields

Research Project

Project/Area Number 26286019
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Nanomaterials engineering
Research InstitutionTohoku University

Principal Investigator

Nagao Daisuke  東北大学, 工学(系)研究科(研究院), 教授 (50374963)

Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥15,600,000 (Direct Cost: ¥12,000,000、Indirect Cost: ¥3,600,000)
Fiscal Year 2016: ¥3,640,000 (Direct Cost: ¥2,800,000、Indirect Cost: ¥840,000)
Fiscal Year 2015: ¥7,540,000 (Direct Cost: ¥5,800,000、Indirect Cost: ¥1,740,000)
Fiscal Year 2014: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Keywordsナノ粒子 / 中空粒子 / 規則配列 / 可動 / ナノ材料
Outline of Final Research Achievements

The field strength in surface enhanced Raman scattering between plasmonic nanoparticles strongly depends on distances between the nanoparticles. Precise control over dispersion-aggregation of particles in a suspension is required to apply the intrinsic surface properties of particles to functional devices. Since unstable particles in a suspension generally aggregate to form large aggregates, it is very difficult to handle aggregates composed of a small number of particles. In the present work where hollow type colloidal crystals incorporating movable cores were fabricated, direct observations of the movable core with an optical microscope experimentally proved that the distance between particles incorporated in the colloidal crystal could be reversibly controlled by application of external field such as AC electric field.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (49 results)

All 2017 2016 2015 2014 Other

All Int'l Joint Research (4 results) Journal Article (13 results) (of which Int'l Joint Research: 1 results,  Peer Reviewed: 13 results,  Acknowledgement Compliant: 5 results) Presentation (24 results) (of which Int'l Joint Research: 6 results,  Invited: 1 results) Book (1 results) Remarks (3 results) Patent(Industrial Property Rights) (4 results)

  • [Int'l Joint Research] ユトレヒト大学(オランダ)

    • Related Report
      2016 Annual Research Report
  • [Int'l Joint Research] ユトレヒト大学(オランダ)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] 上海交通大学(中国)

    • Related Report
      2015 Annual Research Report
  • [Int'l Joint Research] 建国大学(韓国)

    • Related Report
      2015 Annual Research Report
  • [Journal Article] Yolk/Shell Colloidal Crystals Incorporating Movable Cores with Their Motion Controlled by an External Electric Field2017

    • Author(s)
      Kanako Watanabe, Haruyuki Ishii, Mikio Konno, Arnout Imhof , Alfons van Blaaderen, Daisuke Nagao
    • Journal Title

      Langmuir

      Volume: 33 Issue: 1 Pages: 296-302

    • DOI

      10.1021/acs.langmuir.6b03116

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Phosphor-free silica-coating of monodisperse cores for dual functionalization with luminescent and mesoporous shell2017

    • Author(s)
      Haruyuki Ishii, Shunsuke Kawai, Daisuke Nagao, Mikio Konno
    • Journal Title

      Microporous and Mesoporous Materials

      Volume: 241 Pages: 366-371

    • DOI

      10.1016/j.micromeso.2016.12.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimized Thermal Treatment for Preparation of Double Inverse Opals Incorporating Movable Cores2017

    • Author(s)
      Kenta Yamada, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 50 Issue: 1 Pages: 64-67

    • DOI

      10.1252/jcej.16we146

    • NAID

      130005290306

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low-temperature synthesis of water-dispersible magnetic composite particles with high monodispersity2016

    • Author(s)
      Chika Suwabe, Noriko Yamauchi, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Colloid and Polymer Science

      Volume: 294(12) Issue: 12 Pages: 2079-2085

    • DOI

      10.1007/s00396-016-3971-y

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Imprinting dimples on narrowly dispersed polymeric spheres by heterocoagulation between hard polymer particles and soft oil droplets2016

    • Author(s)
      Kanji Kadowaki, Haruyuki Ishii, Daisuke Nagao, Mikio Konno
    • Journal Title

      Langmuir

      Volume: 32(44) Issue: 44 Pages: 11600-11605

    • DOI

      10.1021/acs.langmuir.6b02688

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of phosphor-free luminescent, monodisperse, mesoporous silica nanoparticles in the co-presence of double- and single-chain cationic surfactants2016

    • Author(s)
      Haruyuki Ishii, Shunsuke Kawai, Daisuke Nagao, Mikio Konno
    • Journal Title

      Advanced Powder Technology

      Volume: 27(2) Issue: 2 Pages: 448-453

    • DOI

      10.1016/j.apt.2016.01.010

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Environmentally adaptable pathway to emulsion polymerization for monodisperse polymer nanoparticle synthesis2015

    • Author(s)
      Haruyuki Ishii, Naoto Kuwasaki, Daisuke Nagao, Mikio Konno
    • Journal Title

      Polymer

      Volume: 77 Pages: 64-69

    • DOI

      10.1016/j.polymer.2015.09.002

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic field aligned assembly of nonmagnetic composite dumbbells in nanoparticle-based aqueous ferrofluid2015

    • Author(s)
      Hayato Takahashi, Daisuke Nagao, Kanako Watanabe, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Langmuir

      Volume: 31 Issue: 20 Pages: 5590-5595

    • DOI

      10.1021/acs.langmuir.5b00737

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Rattle-type colloidal crystals composed of spherical hollow particles containing an anisotropic, movable core2015

    • Author(s)
      Kanako Watanabe, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Langmuir

      Volume: 31 Issue: 19 Pages: 5306-5310

    • DOI

      10.1021/acs.langmuir.5b01148

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Fabrication of Double Inverse Opals via Binary Colloidal Crystals of Inorganic-Organic Core-Shell Particles and Inorganic Nanoparticles2015

    • Author(s)
      Kenta Yamada, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

      Volume: 48 Issue: 11 Pages: 933-936

    • DOI

      10.1252/jcej.15we047

    • NAID

      130005110447

    • ISSN
      0021-9592, 1881-1299
    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Chemical bonding heterocoagulation of nanoparticles onto polymeric spheres by two-step addition of polymerizable coupling agent2015

    • Author(s)
      Chika Suwabe, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Colloid and Polymer Science

      Volume: 293 Issue: 7 Pages: 2095-2100

    • DOI

      10.1007/s00396-015-3603-y

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Monodisperse polymer particles2014

    • Author(s)
      Mikio Konno, Daisuke Nagao
    • Journal Title

      Encyclopedia of Polymer Science and Technology

      Volume: 4th Edition Pages: 1-26

    • DOI

      10.1002/0471440264.pst617

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Advanced synthesis for monodisperse polymer nanoparticles in aqueous media with sub-millimolar surfactants2014

    • Author(s)
      Haruyuki Ishii, Motohiro Ishii, Daisuke Nagao, Haruyuki Ishii, Mikio Konno
    • Journal Title

      Polymer

      Volume: (in press) Issue: 12 Pages: 2772-2779

    • DOI

      10.1016/j.polymer.2014.04.011

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] 磁場応答特性向上のための磁性複合粒子の液中分散性制御2017

    • Author(s)
      小濵奈月、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都・江東区)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 単分散粒子を鋳型としたポリマーインバースオパールの作製プロセスについて2017

    • Author(s)
      八幡あゆみ、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第82年会
    • Place of Presentation
      芝浦工業大学(東京都・江東区)
    • Year and Date
      2017-03-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] ナノ粒子担持状態を制御可能なポリマー層形成プロセスに関する検討2017

    • Author(s)
      重田望、石井治之、長尾大輔
    • Organizer
      第19回化学工学会学生発表会【東日本】
    • Place of Presentation
      東京農工大学(東京都・小金井市)
    • Related Report
      2016 Annual Research Report
  • [Presentation] 重合性シリコーン油滴とのヘテロ凝集を利用したポリマー粒子表面の凹凸制御2016

    • Author(s)
      田島優衣、門脇侃志、石井治之、今野幹男、長尾大輔
    • Organizer
      高分子ミクロスフェア討論会
    • Place of Presentation
      千葉大学(千葉県・千葉市)
    • Year and Date
      2016-11-07
    • Related Report
      2016 Annual Research Report
  • [Presentation] Synthesis of golf ball-like particles using monodisperse oil droplets2016

    • Author(s)
      Y. Tajima、H. Ishii、M. Konno、D. Nagao
    • Organizer
      12th Japan-Korea Symposium on Materials & Interfaces
    • Place of Presentation
      Gotemba Kogen Resort-Toki No Sumika(Shizuoka・Japan)
    • Year and Date
      2016-11-02
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] シリコーン油滴を利用したヘテロ凝集による粒子表面凹凸制御2016

    • Author(s)
      田島優衣、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県・徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] メソポーラスシリカ粒子の単分散化と細孔径制御2016

    • Author(s)
      奈良光展、石井治之、今野幹男、長尾大輔
    • Organizer
      化学工学会第48回秋季大会
    • Place of Presentation
      徳島大学(徳島県・徳島市)
    • Year and Date
      2016-09-06
    • Related Report
      2016 Annual Research Report
  • [Presentation] 可動性コアを内包した3次元中空粒子配列体の作成2016

    • Author(s)
      田中恵理、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] ソープフリー乳化重合を利用した単分散ポリマーナノ粒子の高純度合成2016

    • Author(s)
      田島優衣、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第81年会
    • Place of Presentation
      関西大学(大阪府・吹田市)
    • Year and Date
      2016-03-13
    • Related Report
      2015 Annual Research Report
  • [Presentation] Synthesis of highly monodisperse composite particles for field-induced colloidal assembly2015

    • Author(s)
      D. Nagao, M. Konno
    • Organizer
      The 5th Asian Symposium on Emulsion Polymerization and Functional Polymeric Microspheres
    • Place of Presentation
      Jinji Lake Shilla Hotel(China)
    • Year and Date
      2015-10-24
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] 非球形コアを内包した球形中空シリカ粒子の合成2015

    • Author(s)
      渡部花奈子、石井治之、長尾大輔、今野幹男
    • Organizer
      第64回高分子討論会
    • Place of Presentation
      東北大学(宮城県・仙台市)
    • Year and Date
      2015-09-15
    • Related Report
      2015 Annual Research Report
  • [Presentation] シリコーン油滴とポリマー粒子のヘテロ凝集を利用したゴルフボール型粒子の合成2015

    • Author(s)
      門脇侃志、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 水相析出重合へのイオン性界面活性剤微量添加による単分散ポリマーナノ粒子の合成2015

    • Author(s)
      桑﨑直人、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 単分散ポリマー小粒子への磁場応答性付与のためのヘテロ凝集とシリカ被覆2015

    • Author(s)
      諏訪部千佳、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 2成分粒子の自己組織化を利用した可動体内包型コロイド結晶の作製2015

    • Author(s)
      山田健太、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] 電場応答性コア内包型中空粒子の構造制御に関する検討2015

    • Author(s)
      渡部花奈子、石井治之、長尾大輔、今野幹男
    • Organizer
      化学工学会第47回秋季大会
    • Place of Presentation
      北海道大学(北海道・札幌市)
    • Year and Date
      2015-09-09
    • Related Report
      2015 Annual Research Report
  • [Presentation] Electric and magnetic field assisted self-assembly of monodisperse composite particles: Finding new assembled structures of colloidal building blocks2015

    • Author(s)
      D. Nagao, M. Konno
    • Organizer
      5th INTERNATIONAL COLLOIDS CONFERENCE
    • Place of Presentation
      Amsterdam(The Netherlands)
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Synthesis of submicron-sized yolk/shell particles for rattle-type colloidal crystals2015

    • Author(s)
      K. Watanabe, D. Nagao, H. Ishii, M. Konno
    • Organizer
      5th INTERNATIONAL COLLOIDS CONFERENCE
    • Place of Presentation
      Amsterdam(The Netherlands)
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Preparation of raspberry particles firmly fixing inorganic nanoparticles onto polymer particles2015

    • Author(s)
      C. Suwabe, D. Nagao, H. Ishii, M. Konno
    • Organizer
      5th INTERNATIONAL COLLOIDS CONFERENCE
    • Place of Presentation
      Amsterdam(The Netherlands)
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Fabrication of regularly arranged hollow architectures compartmentalized by nanoparticle walls2015

    • Author(s)
      K. Yamada, D. Nagao, H. Ishii, M. Konno
    • Organizer
      5th INTERNATIONAL COLLOIDS CONFERENCE
    • Place of Presentation
      Amsterdam(The Netherlands)
    • Year and Date
      2015-06-21
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Creation of non-close-packed structures of multicomponent colloidal crystals by self-assembling inorganic-organic composite particles2014

    • Author(s)
      K. Yamada, D. Nagao, H. Ishii, M. Konno
    • Organizer
      11th Korea-Japan Symposium on Materials and Interfaces
    • Place of Presentation
      Jeju(Korea)
    • Year and Date
      2014-11-06
    • Related Report
      2014 Annual Research Report
  • [Presentation] 単分散粒子をコアとした多孔性発光シリカ粒子合成に関する研究2014

    • Author(s)
      河合駿介, 石井治之, 長尾大輔, 今野幹男
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学(福岡県・福岡市)
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] ナノ粒子流体中での粒子配列制御を利用した非最密充填コロイド結晶の創製2014

    • Author(s)
      山田健太, 石井治之, 長尾大輔, 今野幹男
    • Organizer
      化学工学会第46回秋季大会
    • Place of Presentation
      九州大学(長崎県・長崎市)
    • Year and Date
      2014-09-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Synthesis of Hollow Particles Containing a Movable Inner Core for Reconfiguration of Cores by External Fields2014

    • Author(s)
      D. Nagao, A. Okada, H. Ishii, M. Konno
    • Organizer
      78th Frontiers of Polymer Colloids: From Synthesis to Macro-Scale and Nano-Scale Applications
    • Place of Presentation
      Prague(Czech)
    • Year and Date
      2014-07-21
    • Related Report
      2014 Annual Research Report
  • [Book] ゲルテクノロジーハンドブック2014

    • Author(s)
      長尾大輔, 今野幹男
    • Total Pages
      5
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2014 Annual Research Report
  • [Remarks] 東北大学大学院工学研究科 化学工学専攻 長尾研究室HP

    • URL

      https://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2016 Annual Research Report
  • [Remarks] 東北大学大学院工学研究科 化学工学専攻 長尾研究室 HP

    • URL

      http://www.che.tohoku.ac.jp/~mpe/

    • Related Report
      2015 Annual Research Report
  • [Remarks] 東北大学大学院工学研究科化学工学専攻 今野研究室HP

    • URL

      http://www.che.tohoku.ac.jp/~mickey/

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] 磁性体複合粒子およびその製造方法、並びに免疫測定用粒子2017

    • Inventor(s)
      長尾大輔、石井治之、小濱奈月、後藤昌大、上山俊彦
    • Industrial Property Rights Holder
      国立大学法人東北大学、DOWAエレクトロニクス株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2017-028302
    • Filing Date
      2017-02-17
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 光学素子、光学素子を用いたデバイスおよび光学素子の製造方法2016

    • Inventor(s)
      長尾大輔、今野幹男、渡部花奈子
    • Industrial Property Rights Holder
      国立大学法人東北大学
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-098658
    • Filing Date
      2016-05-17
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] 磁性体複合粒子およびその製造方法、並びに免疫測定用粒子2016

    • Inventor(s)
      長尾大輔、今野幹男、石井治之
    • Industrial Property Rights Holder
      国立大学法人東北大学、DOWAエレクトロニクス株式会社
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-171157
    • Filing Date
      2016-09-01
    • Related Report
      2016 Annual Research Report
  • [Patent(Industrial Property Rights)] コアシェル型多孔質シリカ粒子の製造方法2016

    • Inventor(s)
      今野幹男、長尾大輔、石井治之、菅野新
    • Industrial Property Rights Holder
      東北大学、株式会社ダイセル
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-030260
    • Filing Date
      2016-02-19
    • Related Report
      2015 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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