| Budget Amount *help |
¥16,900,000 (Direct Cost: ¥13,000,000、Indirect Cost: ¥3,900,000)
Fiscal Year 2016: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2015: ¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2014: ¥6,500,000 (Direct Cost: ¥5,000,000、Indirect Cost: ¥1,500,000)
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| Outline of Final Research Achievements |
We have investigated synthetic applications of photoinduced carbene formation from acylsilanes to explore novel synthetic methodologies for construction of synthetically useful cyclic molecules.
For example, we have succeeded in developing new methodology for construction of trans-fused carbocycles by photoinduced intramolecular coupling between acylsilanes and boronate esters by using nucleophilic character of photochemically-generated siloxycarbenes. Furthermore, we also examined various applications of this photochemical carbene generation process to carbon-carbon bond forming reactions and succeeded to explore several useful and original synthetic reactions.
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