Development of New Functional Materials by Nano-scale Molecular Design and Expansion of Multinuclear Metal Systems
| Project/Area Number |
26288025
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Nara Women's University |
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Principal Investigator |
TANASE Tomoaki 奈良女子大学, 自然科学系, 教授 (50207156)
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| Co-Investigator(Kenkyū-buntansha) |
中島 隆行 奈良女子大学, 自然科学系, 准教授 (80322676)
久禮 文章 奈良女子大学, 自然科学系, 助教 (30572557)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2014: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
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| Keywords | 金属クラスター / ナノ分子素子 / 多座ホスフィン / 金属錯体化学 / 分子細線 / パラジウム / 白金 / 金，銀，銅 / 銅 |
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| Outline of Final Research Achievements |
This project intended development of new functional materials by expanding multinuclear metal systems which are designed in fine tunable fashion as metal chains, rings, and cages, etc. with an aid of systematically synthesized linear polyphosphine ligands. In particular, rigid-rod platinum and palladium wires (Pt6, Pd8), flexible gold and silver chains (Au4, Au6, Ag6), gold-silver-copper rings (Au4Ag2Cu2), and multinuclear copper hydride complexes (Cu2, Cu4, Cu8, Cu9, Cu16) were synthesized and characterized, and their properties and reactivity as well as expansion by using metal and organic linkers were examined.
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Report
(4 results)
Research Products
(37 results)
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[Journal Article] Electron-Deficient Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands2014
Author(s)
E. Goto, R. A. Begum, C. Ueno, A. Hosokawa, C. Yamamoto, K. Nakamae, B. Kure, T. Nakajima, T. Kajiwara, and T. Tanase
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Journal Title
Organometallics
Volume: ３３
Issue: 8
Pages: 1893-1904
DOI
Related Report
Peer Reviewed
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[Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands2014
Author(s)
○T. Nakajima, K. Seto, F. Hosokawa, I. Shimizu, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, T. Tanase
Organizer
41th International Conference on Coordination Chemistry (ICCC41)
Place of Presentation
Singapore
Year and Date
2014-07-21 – 2014-07-25
Related Report
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