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Development of New Functional Materials by Nano-scale Molecular Design and Expansion of Multinuclear Metal Systems

Research Project

Project/Area Number 26288025
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionNara Women's University

Principal Investigator

TANASE Tomoaki  奈良女子大学, 自然科学系, 教授 (50207156)

Co-Investigator(Kenkyū-buntansha) 中島 隆行  奈良女子大学, 自然科学系, 准教授 (80322676)
久禮 文章  奈良女子大学, 自然科学系, 助教 (30572557)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2016)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2016: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2015: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2014: ¥10,790,000 (Direct Cost: ¥8,300,000、Indirect Cost: ¥2,490,000)
Keywords金属クラスター / ナノ分子素子 / 多座ホスフィン / 金属錯体化学 / 分子細線 / パラジウム / 白金 / 金,銀,銅 / 銅
Outline of Final Research Achievements

This project intended development of new functional materials by expanding multinuclear metal systems which are designed in fine tunable fashion as metal chains, rings, and cages, etc. with an aid of systematically synthesized linear polyphosphine ligands. In particular, rigid-rod platinum and palladium wires (Pt6, Pd8), flexible gold and silver chains (Au4, Au6, Ag6), gold-silver-copper rings (Au4Ag2Cu2), and multinuclear copper hydride complexes (Cu2, Cu4, Cu8, Cu9, Cu16) were synthesized and characterized, and their properties and reactivity as well as expansion by using metal and organic linkers were examined.

Report

(4 results)
  • 2016 Annual Research Report   Final Research Report ( PDF )
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (37 results)

All 2017 2016 2015 2014 Other

All Journal Article (20 results) (of which Peer Reviewed: 20 results,  Acknowledgement Compliant: 10 results) Presentation (14 results) (of which Int'l Joint Research: 7 results,  Invited: 6 results) Remarks (3 results)

  • [Journal Article] Chiral Self-Recognition between Stereogenic Tetrapalladium Units Affording Pd8 Chains Supported by Homochiral Tetraphosphines2017

    • Author(s)
      T. Tanase, K. Morita, R. Otaki, K. Yamamoto, Y. Kaneko, K. Nakamae, B. Kure, and T. Nakajima
    • Journal Title

      Chem. Eur. J

      Volume: 23 Pages: 524-528

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Planar PtPd3 Complexes Stabilized by Three Bridging Silylene Ligands2017

    • Author(s)
      M. Tanabe, R. Yumoto, T. Yamada, T. Fukuta, T. Hoshino, K. Osakada, and T. Tanase
    • Journal Title

      Chem. Eur. J.

      Volume: 23 Pages: 1386-1392

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Linear Triplatinum Tetrahydride Complex Supported by Triphosphine Ligands, [Pt3(m-H)2(H)2(m-dpmp)2](BF4)2 {dpmp = bus(diphenylphosphinomethyl)phenylphosphine}2017

    • Author(s)
      T. Tanase, K. Yamamoto, R. Hatano, K. Nakamae, B. Kure, Y. Ura, and T. Nakajima
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: - Pages: 1422-1426

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] A Fluxional Cu8H6 Cluster Supported by Bus(diphenylphosphino)methane and Its Facile Reaction with CO22017

    • Author(s)
      K. Nakamae, M. Tanaka, B. Kure, T. Nakajima, Y. Ura, and T. Tanase
    • Journal Title

      Chem. Eur. J.

      Volume: 23

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Structure of Trihydride Hexaplatinum Complex Supported by Triphosphine Ligands, [Pt6(mu-H)(H)2(mu-dpmp)4]BH4 (dpmp = bis(diphenylphosphinomethyl)phenylphosphine)2016

    • Author(s)
      T. Tanase, K. Yamamoto, K. Nakamae, B. Kure, and T. Nakajima
    • Journal Title

      J. Organomet. Chem.

      Volume: asap Pages: 35-41

    • DOI

      10.1016/j.jorganchem.2016.04.031

    • Related Report
      2016 Annual Research Report 2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Homo- and Heterodinuclear Rh and Ir Complexes Supported by SNn Mixed-Donor Ligands (n = 2-4): Stereochemistry and Coordination-Site-Exchange Reactions of Cp*M (M = Rh, Ir)2016

    • Author(s)
      T. Nakajima, Y. Kawasaki, B. Kure, and T. Tanase
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: - Issue: 28 Pages: 4701-4710

    • DOI

      10.1002/ejic.201600722

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Oxidative Addition of an Aromatic ortho C-H bond of Tetraphosphine to Asymmetric Diiridium(I) Centers2016

    • Author(s)
      Nakajima, T.; Noda, S.; Sakamoto, M.; Matsui, A.; Nakamae, K.; Kure, B.; Ura, Y.; Tanase, T.
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 11 Pages: 4747-4761

    • DOI

      10.1039/c5dt04725k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-rich Linear Triplatinum Complexes Stabilized by a Spinning Tetraphosphine, Tris(diphenylphosphinomethyl)phosphine2016

    • Author(s)
      Tanase, T.; Koike, K.; Uegaki, M.; Hatada, S.; Nakamae, K.; Kure, B.; Ura, Y.; Nakajima, T.
    • Journal Title

      Dalton Trans.

      Volume: 45 Issue: 17 Pages: 7209-7214

    • DOI

      10.1039/c6dt00624h

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic Synthesis of Di-, Tri-, and Tetranuclear Homo- and Heterometal Complexes Using a Mononuclear Copper Synthon with a Tetradentate Amino Alcohol Ligand2016

    • Author(s)
      T. Nakajima, C. Yamashiro, M. Taya, B. Kure, and T. Tanase
    • Journal Title

      Eur. J. Inorg. Chem.

      Volume: asap Issue: 17 Pages: 2764-2777

    • DOI

      10.1002/ejic.201600142

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Synthesis and Structures of Binuclear RhIII and IrIII Complexes Supported by a Tetraphosphine, meso- or ran- bis{[(diphenylphosphinomethyl)phenyl]phosphino}methane2015

    • Author(s)
      Tanase, T.; Yoshii, A.; Otaki, R.; Nakamae, K.; Mikita, Y.; Kure, B.; Nakajima, T.
    • Journal Title

      J. Organomet. Chem.

      Volume: 797 Pages: 37-45

    • DOI

      10.1016/j.jorganchem.2015.07.033

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Stepwise Expansion of Pd Chains from Binuclear Palladium(I) Complexes Supported by Tetraphosphine Ligands2015

    • Author(s)
      Tanase, T.; Hatada, S.; Noda, S.; Takenaka, H.; Nakamae, K.; Kure, B.; Nakajima, T.
    • Journal Title

      Ignore. Chem.

      Volume: 54 Issue: 17 Pages: 8298-8309

    • DOI

      10.1021/acs.inorgchem.5b00950

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Gold and Silver Chains Supported by Linear Hexaphosphine Ligands2015

    • Author(s)
      Tanse, T.; Chikanishi, M.; Morita, K.; Nakamae, K.; Kure, B.; Nakajima, T.
    • Journal Title

      Chem. Asian J.

      Volume: 10 Issue: 12 Pages: 2619-2623

    • DOI

      10.1002/asia.201500876

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Alignment of Low-Valent Octanuclear Palladium Atoms2015

    • Author(s)
      K. Nakamae, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, and T. Tanase
    • Journal Title

      Angew. Chem. Int. Ed.

      Volume: 54 Pages: 1016-1021

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Strongly Luminous Tetranuclear Gold(I) Complexes Supported by Tetraphosphine Ligands, meso- or rac-Bis[(diphenylphosphinomethyl)phenylphosphino]methane2014

    • Author(s)
      T. Tanase, R. Otaki, T. Nishida, H. Takenaka, Y. Takemura, B. Kure, T. Nakajima, Y. Kitagawa, T. Tsubomura
    • Journal Title

      Chem. Euro. J.

      Volume: 20 Issue: 6 Pages: 1577-1596

    • DOI

      10.1002/chem.201303729

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron-Deficient Pt2M2Pt2 Hexanuclear Metal Strings (M = Pt, Pd) Supported by Triphosphine Ligands2014

    • Author(s)
      E. Goto, R. A. Begum, C. Ueno, A. Hosokawa, C. Yamamoto, K. Nakamae, B. Kure, T. Nakajima, T. Kajiwara, and T. Tanase
    • Journal Title

      Organometallics

      Volume: 33 Issue: 8 Pages: 1893-1904

    • DOI

      10.1021/om401211d

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] One-dimensional Anisotropic Metal Organic Module Containing a Pt6 Chain Terminated with Redox Active Ferrocenyl Units2014

    • Author(s)
      T. Tanase, C. Yamamoto, B. Kure, and T. Nakajima
    • Journal Title

      Chem. Lett.

      Volume: 43 Issue: 6 Pages: 913-915

    • DOI

      10.1246/cl.140161

    • NAID

      130004868205

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tetranuclear Nickel and Cobalt Complexes with an Incomplete Double-Cubane Structure - Homo- and Heterometallic Complexes and Their 1D Coordination Polymers2014

    • Author(s)
      T. Nakajima, K. Seto, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, H. Sakiyama
    • Journal Title

      Eur. J. Inorg. Chem

      Volume: 2014 Issue: 29 Pages: 5021-5033

    • DOI

      10.1002/ejic.201402536

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Systematic Heterodinuclear Complexes with MM′(μ-meppp) Centers that Tune the Properties of a Nesting Hydride (M = Ni, Pd, Pt; M′ = Rh, Ir; H2meppp = meso -1,3-Bis[(mercaptoethyl)phenylphosphino]propane)2014

    • Author(s)
      B. Kure, M. Sano, T. Nakajima, T. Tanase
    • Journal Title

      Organometallics

      Volume: 33 Issue: 15 Pages: 3950-3965

    • DOI

      10.1021/om500410f

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Structures of Pd2M2 (M = Cu, Au) and Pd2M (M = Cu, Ag) Mixed-metal Complexes Supported by NPPN Tetradentate Ligands2014

    • Author(s)
      T. Nakajima, M. Tsuji, N. Hamada, Y. Fukushima, B. Kure, T. Tanase
    • Journal Title

      J. Organomet. Chem.

      Volume: 768 Pages: 61-67

    • DOI

      10.1016/j.jorganchem.2014.06.022

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed / Acknowledgement Compliant
  • [Journal Article] Facile Insertion of Carbon Dioxide into Cu2(μ-H) Dinuclear Units Supported by Tetraphosphine Ligands2014

    • Author(s)
      Kanako Nakamae, Bunsho Kure, Takayuki Nakajima, Yasuyuki Ura, Tomoaki Tanase
    • Journal Title

      Chem. Asian J.

      Volume: 9 Issue: 11 Pages: 3106-3110

    • DOI

      10.1002/asia.201402900

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Systematic Synthesis of Heterodinuclear Complexes with NiM(m-SR)2 (M = Rh, Ir) and Their Reactivity toward Organic Substrates2016

    • Author(s)
      B. Kure, M. Sano, N. Watanabe, K. Nakamae, T. Nakajima, T, Tanase
    • Organizer
      27th International Conference on Organometallic Chemistry
    • Place of Presentation
      Melbourne (Australia)
    • Year and Date
      2016-07-17
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Multinuclear Metal Centers Constrained by Linear Polyphosphines2016

    • Author(s)
      T. Tanase
    • Organizer
      The 3rd Japan-Taiwan-Singapore-Hong Kong Quadrilateral Symposium on Coordination Chemistry
    • Place of Presentation
      Taipei (Taiwan)
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Self-alignment of Low-Valent Palladium Chains2015

    • Author(s)
      ○T. Tanase
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies Congress (Pacifichem 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] A Linear Hexanuclear Platinum Trihydride Complex Supported by Triphosphine Ligands2015

    • Author(s)
      ○K. Yamamoto, B. Kure, T. Nakajima, T. Tanase
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies Congress (Pacifichem 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Redox Properties of Linear Octanuclear Palladium Complexes Supported by Tetraphosphine Ligands2015

    • Author(s)
      ○K. Nakamae, B. Kure, T. Nakajima, T. Tanase
    • Organizer
      The 2015 International Chemical Congress of Pacific Basin Societies Congress (Pacifichem 2015)
    • Place of Presentation
      Honolulu (USA)
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Low-Valent Extended Metal Atom Chains Supported by Polyphosphines2015

    • Author(s)
      ○T. Tanase
    • Organizer
      10th China-Japan Join Symposium on Metal Cluster Compounds
    • Place of Presentation
      Fuzhou (China)
    • Year and Date
      2015-10-23
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low-Valent Extended Metal Atom Chains Supported by Polyphosphines2015

    • Author(s)
      ○T. Tanase
    • Organizer
      The 2nd Japan- Singapore-Taiwan Trilateral Symposium in Coordination Chemistry
    • Place of Presentation
      National University of Singapore (Singapore)
    • Year and Date
      2015-08-08
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Low-Valent Extended Metal Atom Chains Supported by Polyphosphines, A Possibility of Self-Alignment2014

    • Author(s)
      ○T. Tanase
    • Organizer
      The 2nd Japan-UK Joint Symposium on Coordination Chemistry
    • Place of Presentation
      Tokyo (Japan)
    • Year and Date
      2014-09-16 – 2014-09-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Low-Valent Extended Metal Atom Chains Supported by Polyphosphines2014

    • Author(s)
      ○T. Tanase
    • Organizer
      41th International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Wheel-Shaped Icosanuclear Homo- and Heterometallic Complexes of NiII, CoII, and CuII Ions Supported by Unsymmetrical Aminoalcohol Ligands2014

    • Author(s)
      ○T. Nakajima, K. Seto, F. Hosokawa, I. Shimizu, A. Scheurer, B. Kure, T. Kajiwara, T. Tanase, M. Mikuriya, T. Tanase
    • Organizer
      41th International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Cage-Type Copper Hydride Clusters Supported By Tetraphosphine Ligands2014

    • Author(s)
      ○K. Nakamae, B. Kure, T. Nakajima, T. Tanase
    • Organizer
      41th International Conference on Coordination Chemistry (ICCC41)
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-21 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reversible Dioxygen Binding on Asymmetric Dinuclear Rhodium Centers2014

    • Author(s)
      ○T, Nakajima, M. Sakamoto, S. Noda, B. Kure, T. Tanase
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Sapporo (Japan)
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Heterodinuclear Complexes with MM’(m-meppp) Cores (M = Ni, Pd, Pt; M’ = Rh, Ir) That Tune the Properties of a Nesting Hydride2014

    • Author(s)
      ○B. Kure, M. Sano, T. Nakajima, T. Tanase
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Sapporo (Japan)
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Presentation] Reduction of Carbon Dioxide with Copper Hydride Complexes Supported by Tetraphosphine2014

    • Author(s)
      ○K. Nakamae, B. Kure, T. Nakajima, Y. Ura, T. Tanase
    • Organizer
      The XXVI International Conference on Organometallic Chemistry (ICOMC 2014)
    • Place of Presentation
      Sapporo (Japan)
    • Year and Date
      2014-07-13 – 2014-07-18
    • Related Report
      2014 Annual Research Report
  • [Remarks] Tanase Research Group Homepage

    • URL

      http://www.chem.nara-wu.ac.jp/~tanase/TanaseGroup/

    • Related Report
      2016 Annual Research Report
  • [Remarks] http://www.chem.nara-wu.ac.jp/~tanase/TanaseGroup/

    • Related Report
      2015 Annual Research Report
  • [Remarks] Tanase Group Home Page

    • URL

      http://www.chem.nara-wu.ac.jp/~tanase/TanaseGroup/

    • Related Report
      2014 Annual Research Report

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Published: 2014-04-04   Modified: 2018-03-22  

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