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Development of Synchronized Multi Functions Based on Graphene Hybrid

Research Project

Project/Area Number 26288026
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypePartial Multi-year Fund
Section一般
Research Field Inorganic chemistry
Research InstitutionKumamoto University

Principal Investigator

Hayami Shinya  熊本大学, 大学院先端科学研究部(理), 教授 (30321912)

Co-Investigator(Renkei-kenkyūsha) MATSUDA Masaki  熊本大学, 大学院先端科学研究部, 教授 (80376649)
Research Collaborator KUROIWA Keita  崇城大学, 工学部, 教授 (70336006)
Project Period (FY) 2014-04-01 – 2017-03-31
Project Status Completed (Fiscal Year 2017)
Budget Amount *help
¥12,610,000 (Direct Cost: ¥9,700,000、Indirect Cost: ¥2,910,000)
Fiscal Year 2016: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2015: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2014: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Keywords酸化グラフェン / ハイブリッド / プロトン伝導 / 半導体 / ナノ材料 / 金属錯体
Outline of Final Research Achievements

In this study, we succeeded to develop GO-metal complex hybrids and rGO-metal complex hybrids with hybridizing graphene oxide (GO) and its reduced form (rGO), which have interesting unique properties. It was revealed that GO which is a precursor of rGO shows high proton conductivity and that rGO in which GO is variously reduced exhibits properties of p type semiconductor or n type semiconductor. We have also found the property as a photocatalyst that decomposes water by light irradiation for rGO.

Report

(4 results)
  • 2017 Final Research Report ( PDF )
  • 2016 Annual Research Report
  • 2015 Annual Research Report
  • 2014 Annual Research Report
  • Research Products

    (44 results)

All 2016 2015 2014 Other

All Journal Article (23 results) (of which Int'l Joint Research: 13 results,  Peer Reviewed: 23 results,  Acknowledgement Compliant: 9 results,  Open Access: 2 results) Presentation (18 results) (of which Int'l Joint Research: 11 results,  Invited: 10 results) Remarks (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis of mesoporous materials as nano-carriers for an antimalarial drug2016

    • Author(s)
      S. A. Amolegbe, H. Ohmagari, K. Wakata, H. Takehira, R. Ohtani, M. Nakamura, C. Yu, S. Hayami
    • Journal Title

      J. Mater. Chem. B

      Volume: 4 Issue: 6 Pages: 1040-1043

    • DOI

      10.1039/c5tb02200b

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Magnetic and Liquid Crystalline Property of Long-Alkyl Chain Appended Iron(II) Imidazole Complexes2016

    • Author(s)
      M. R. Karim, H. Takehira, M. M. Rahman, A. M. Asiri, M. K. Abdullah, R. Ohtani, S. Hayami
    • Journal Title

      J. Organomet. Chem.

      Volume: 808 Pages: 42-47

    • DOI

      10.1016/j.jorganchem.2016.02.014

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Photocurrent Generation of Graphene Oxide Hybrid with Ru(II) Complex2016

    • Author(s)
      T. Matsui, M. R. Karim, H. Takehira, M. Nakamura, R. Ohtani, M. Koinuma, S. Hayami
    • Journal Title

      Chem. Lett.

      Volume: 45 Issue: 3 Pages: 365-367

    • DOI

      10.1246/cl.151123

    • NAID

      130005132153

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Metal dilution effects on the reverse spin transition in mixed-crystals of type [Co1-xZnx(C16-terpy)2](BF4)2 (x = 0.1-0.7)2016

    • Author(s)
      R. Ohtani, S. Egawa, M. Nakaya, H. Ohmagari, M. Nakamura, L. F. Lindoy, S. Hayami
    • Journal Title

      Inorg. Chem.

      Volume: 55 Issue: 7 Pages: 3332-3337

    • DOI

      10.1021/acs.inorgchem.5b02582

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Reduced Graphene Oxide-Transition Metal Hybrids as p-Type Semiconductors for Acetaldehyde Sensing2016

    • Author(s)
      Y. Murashima, M. R. Karim, R. Furue, T. Matsui, H. Takehira, K. Wakata, K. Toda, R. Ohtani, M. Nakamura, S. Hayami
    • Journal Title

      Inorg. Chem. Front.

      Volume: 3 Issue: 6 Pages: 842-848

    • DOI

      10.1039/c6qi00058d

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Thermally Stable Super Ionic Conductor from Carbon Sphere Oxide2016

    • Author(s)
      M. S. Islam, M. R. Karim, K. Hatakeyama, H. Takehira, R. Ohtani, M. Nakamura, M. Koinuma, S. Hayami
    • Journal Title

      Chem. Asian J.

      Volume: 11 Issue: 16 Pages: 2322-2327

    • DOI

      10.1002/asia.201600835

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Effect of Interlayer Distance and Oxygen Content on Proton Conductivity of Graphite Oxide2016

    • Author(s)
      M. R. karim, M. S. Islam, K. Hatakeyama, M. Nakamura, R. Ohtani, M. Koinuma, S. Hayami
    • Journal Title

      J. Phys. Chem. C

      Volume: 120 Issue: 38 Pages: 21976-21982

    • DOI

      10.1021/acs.jpcc.6b06301

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Water-dependent charge-transfer-induced spin transition of a prussian blue analog2016

    • Author(s)
      H. Ohmagari, R. Ohtani, M. Nakaya, M. Ohba, M. Nakamura, L. F. Lindoy, S. Hayami
    • Journal Title

      Dalton Transactions

      Volume: 45 Issue: 42 Pages: 16784-16788

    • DOI

      10.1039/c6dt03474h

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] In Situ Generation of Silicon Oxycarbide Phases on Reduced Graphene Oxide for Li Ion Battery Anode2016

    • Author(s)
      M. S. Islam, M. R. Karim, S. Islam, J. Kim, N. N. rabin, R. Ohtani, M. Nakamura, S. Hayami
    • Journal Title

      Chemistry Select

      Volume: 1 Issue: 20 Pages: 6429-6433

    • DOI

      10.1002/slct.201601363

    • Related Report
      2016 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Coexistence of Electrical Conductivity and Ferromagnetism in a Hybrid Material Formed from Reduced Graphene Oxide and Manganese Oxide2015

    • Author(s)
      Y. Murashima, R. Ohtani, T. Matsui, H. Takehira, R. Yokota, M. Nakamura, L. F. Lindoy, S. Hayami
    • Journal Title

      Dalton Trans.

      Volume: 44 Issue: 11 Pages: 5049-5052

    • DOI

      10.1039/c5dt00299k

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Recent progress in applications of graphene oxide for gas analysis: a review2015

    • Author(s)
      K. Toda, R. Furue, S. Hayami
    • Journal Title

      Analytica Chimica Acta

      Volume: - Pages: 43-53

    • DOI

      10.1016/j.aca.2015.02.002

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Open Access
  • [Journal Article] Graphene oxide and reduced graphene oxide hybrids with spin crossover iron(III) complexes2015

    • Author(s)
      Y. Murashima, M. R. Karim, N. Saigo, H. Takehira, R. Ohtani, M. Nakamura, M. Koinuma, L. F. Lindoy, K. Kuroiwa, S. Hayami
    • Journal Title

      Inorg. Chem. Front.

      Volume: 2 Issue: 10 Pages: 886-892

    • DOI

      10.1039/c5qi00097a

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Coal Oxide as a Thermally Robust Carbon-Based Proton Conductor2015

    • Author(s)
      Hatakeyama, K.; Ogata, C.; Koinuma, M.; Taniguchi, T.; Hayami, S.; Kuroiwa, K.; Matsumoto, Y.
    • Journal Title

      ACS Appl. Mater. Int.

      Volume: 7 Issue: 41 Pages: 23041-23046

    • DOI

      10.1021/acsami.5b06470

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Super proton/electron mixed conduction in graphene oxide hybrids by intercalating sulfate ions2015

    • Author(s)
      K. Hatakeyama, Md. S. Islam, M. Koinuma C. Ogata, T. Taniguchi, A. Funatsu, T. Kida, S. Hayami, Y. Matsumoto
    • Journal Title

      J. Mater. Chem. A, 3, 20892-20895 (2015)

      Volume: 3 Issue: 42 Pages: 20892-20895

    • DOI

      10.1039/c5ta05653e

    • Related Report
      2015 Annual Research Report
    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Impaired Proton Conductivity of Metal Doped Graphene Oxide2014

    • Author(s)
      Y. Ikeda, M. R. Karim, H. Takehira, T. Matsui, K. Hatakeyama, Y. Murashima, T. Taniguchi, M. Koinuma, M. Nakamura, Y. Matsumoto, S. Hayami
    • Journal Title

      Bull. Chem. Soc. Jp.

      Volume: 87 Pages: 639-641

    • NAID

      130004153295

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] In situ oxygenous functionalization of a graphite electrode for enhanced affinity towards charged species and a reduced graphene oxide mediator2014

    • Author(s)
      M. R. Karim, Y. Ikeda, T. Ide, S. Sugimoto, K. Toda, Y. Kitamura, T. Ihara, T. Matsui, T. Taniguchi, M. Koinuma, Y. Matsumoto, S. Hayami
    • Journal Title

      New J. Chem.

      Volume: 38 Pages: 2120-2127

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Hydrogen generation by graphene oxide-alkylamine hybrids through photocatalytic water splitting2014

    • Author(s)
      Y. Ikeda, M. R. Karim, H. Takehira, K. Hatakeyama, T. Matsui, T. Taniguchi, M. Koinuma, Y. Matsumoto, S. Hayami
    • Journal Title

      Chem. Lett.

      Volume: 43 Pages: 486-488

    • NAID

      130004868052

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Proton Conductivities of Graphene Oxide Nanosheets: Single, Multilayer, and Modified Nanosheets2014

    • Author(s)
      K. Hatakeyama, M. R. Karim, C. Ogata, H. Tateishi, A. Funatsu, T. Taniguchi, M. Koinuma, S. Hayami, Y. Matsumoto
    • Journal Title

      Angew. Chem., Int. Ed.

      Volume: 53 Pages: 6997-7000

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures and Magnetic Properties of Iron(III) Complexes with Long Alkyl Chains2014

    • Author(s)
      M. Nakaya, K. Shimayama, K. Takami, K. Hirata, S. A. Amolegbe, M. Nakamura, L. F. Lindoy, S. Hayami
    • Journal Title

      Crystals

      Volume: 4 Pages: 104-112

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spin-crossover and LIESST Effect for Iron(III) Complex Based on π-π Stacking by Coordination Programming2014

    • Author(s)
      M. Nakaya, K. Shimayama, K. Takami, K. Hirata, S. A. Amolegbe, M. Nakamura, L. F. Lindoy, S. Hayami
    • Journal Title

      Chem. Lett.

      Volume: 43 Pages: 1058-1060

    • NAID

      130004868259

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tunable Graphene Oxide Proton/Electron Mixed Conductor that Functions at Room Temperature2014

    • Author(s)
      K. Hatakeyama, H. Tateishi, T. Taniguchi, M. Koinuma, T. Kida, S. Hayami, H. Yokoi, Y. Matsumoto
    • Journal Title

      Chem. Mater.

      Volume: 26 Pages: 5598-5604

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Graphene and Graphene Oxide as Super Materials2014

    • Author(s)
      M. R. Karim, H. Takehira, T. Matsui, Y. Murashima, R. Ohtani, M. Nakamura, S. Hayami
    • Journal Title

      Current. Inorg. Chem.

      Volume: 4 Pages: 191-219

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Optimization of proton conductivity in graphene oxide by filling sulfate ions2014

    • Author(s)
      K. Hatakeyama, M. R. Karim, C. Ogata, H.Tateishi, T. Taniguchi, M. Koinuma, S. Hayami, Y. Matsumoto
    • Journal Title

      Chemical Communications

      Volume: 50 Pages: 14527-14530

    • Related Report
      2014 Annual Research Report
    • Peer Reviewed
  • [Presentation] Co(II) Spin Crossover Compounds2016

    • Author(s)
      Shinya Hayami
    • Organizer
      PDSTM 2016
    • Place of Presentation
      Valencia, Spain
    • Year and Date
      2016-11-28
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids with Spin Crossover Materials2016

    • Author(s)
      Shinya Hayami
    • Organizer
      日豪シンポジウム
    • Place of Presentation
      Fukuoka
    • Year and Date
      2016-09-10
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids with Spin Crossover Materials2016

    • Author(s)
      Shinya Hayami
    • Organizer
      ICMM 2016
    • Place of Presentation
      Sendai, Miyagi
    • Year and Date
      2016-09-04
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids with Spin Crossover Materials2016

    • Author(s)
      Shinya Hayami
    • Organizer
      ISNSC 2016
    • Place of Presentation
      Brisbane, Australia
    • Year and Date
      2016-07-13
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids with Spin Crossover Materials2016

    • Author(s)
      Shinya Hayami
    • Organizer
      ICCC 2016
    • Place of Presentation
      Brest, France
    • Year and Date
      2016-07-03
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] スーパーマテリアルとしての酸化グラフェン2016

    • Author(s)
      速水真也
    • Organizer
      成形加工学会
    • Place of Presentation
      船堀, 東京
    • Year and Date
      2016-06-14
    • Related Report
      2016 Annual Research Report
  • [Presentation] Graphene oxide and reduced graphene oxide hybrids2016

    • Author(s)
      Shinya Hayami
    • Organizer
      Royal Society of Chemistry Inorganic Chemistry Journal Symposium
    • Place of Presentation
      Fukuoka
    • Related Report
      2016 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      PacificChem 2015
    • Place of Presentation
      Hawaii
    • Year and Date
      2015-12-15
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      MRS-J
    • Place of Presentation
      横浜
    • Year and Date
      2015-12-07
    • Related Report
      2015 Annual Research Report
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      錯体化学討論会
    • Place of Presentation
      奈良
    • Year and Date
      2015-09-20
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      ISNSC
    • Place of Presentation
      Busan
    • Year and Date
      2015-08-14
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research / Invited
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      ACCC
    • Place of Presentation
      Hong Kong
    • Year and Date
      2015-07-12
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphene Oxide and Reduced Graphene Oxide Hybrids2015

    • Author(s)
      Shinya Hayami
    • Organizer
      NT15
    • Place of Presentation
      名古屋
    • Year and Date
      2015-06-29
    • Related Report
      2015 Annual Research Report
    • Int'l Joint Research
  • [Presentation] Graphene oxide hybrids2015

    • Author(s)
      S. Hayami
    • Organizer
      2D15
    • Place of Presentation
      Adelaide
    • Year and Date
      2015-03-10 – 2015-03-11
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] 酸化グラフェンハイブリッド2014

    • Author(s)
      速水真也
    • Organizer
      酸化グラフェン研究会
    • Place of Presentation
      東京
    • Year and Date
      2014-12-18
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene oxide hybrids2014

    • Author(s)
      S. Hayami
    • Organizer
      NMS-X
    • Place of Presentation
      Zhengzhou, China
    • Year and Date
      2014-10-12 – 2014-10-16
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene oxide hybrids2014

    • Author(s)
      S. Hayami
    • Organizer
      ISNSC
    • Place of Presentation
      Bali
    • Year and Date
      2014-08-10 – 2014-08-15
    • Related Report
      2014 Annual Research Report
    • Invited
  • [Presentation] Graphene oxide hybrids2014

    • Author(s)
      S. Hayami
    • Organizer
      ICCC
    • Place of Presentation
      Singapore
    • Year and Date
      2014-07-20 – 2014-07-25
    • Related Report
      2014 Annual Research Report
  • [Remarks] 最近の研究成果

    • URL

      http://www.sci.kumamoto-u.ac.jp/~hayami/recent%20research.html

    • Related Report
      2016 Annual Research Report
  • [Remarks] 研究業績

    • URL

      http://www.sci.kumamoto-u.ac.jp/~hayami/index.html

    • Related Report
      2014 Annual Research Report
  • [Patent(Industrial Property Rights)] グラフェン及び化学修飾グラフェンの製造方法2016

    • Inventor(s)
      真下 茂、速水真也、竹平 裕
    • Industrial Property Rights Holder
      真下 茂、速水真也、竹平 裕
    • Industrial Property Rights Type
      特許
    • Industrial Property Number
      2016-119006
    • Filing Date
      2016-06-15
    • Related Report
      2016 Annual Research Report

URL: 

Published: 2014-04-04   Modified: 2019-03-29  

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