Development of Novel Phase Transition Mechanisms for Molecular Conductors by Applying Multiplicity of Electronic State Determinant Factors

• Project/Area Number: 26288035
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Partial Multi-year Fund
• Section: 一般
• Research Field: Functional solid state chemistry
• Research Institution: Kyoto University
• Principal Investigator: 矢持 秀起 京都大学, 理学研究科, 教授 (20182660)
• Project Period (FY): 2014-04-01 – 2019-03-31
• Project Status: Granted (Fiscal Year 2018)
• Budget Amount: ¥16,770,000 (Direct Cost: ¥12,900,000、Indirect Cost: ¥3,870,000); Fiscal Year 2018: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2017: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2016: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2015: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2014: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
• Keywords: 有機導体 / 分子性固体 / 強相関電子系 / 多重不安定性 / 外場応答 / 分子性導体 / 強電子相関系 / 結晶工学 / 磁性 / 有機動体

Outline of Annual Research Achievements

多重不安定性物質(EDO-TTF)2XF6 (X = Sb) の低温相への光照射に対する挙動について昨年度からの検討をまとめ、論文発表を行った。X = Pの場合、低温相へのパルス光照射により準安定状態(光誘起相)を経由した後、高温相と同等の状態に移行するのに対し、X = Sbの場合はX = Pの時とは異なる結晶構造を持つ光誘起相に変化し、高温相類似の状態に移ることなく長時間にわたってそこに留まったままになる事が判った。
(TMTTF)3[TTF(CO2)4H2]について、TTF核部分の電荷を{}内に併記すると、(TMTTF{+1}) (TMTTF{0}) (TMTTF{+1}) [TTF{0}(CO2)4H2] で示されるTMTTFの3量体と分子全体としては-2価の電荷を持つ[TTF(CO2)4H2]が交互に積層したカラム構造を持つことを昨年度の段階で明らかにしていた。本物質のRamanスペクトルについては、昨年度段階で測定に使用していた試料に不具合があることが判ったが、本年度測定を行い直しTTF核について電荷秩序状態にあることを確認した。さらに、100 K以下ではTMTTF上の電荷が均一化していることが判った。磁化率の温度変化はsinglet-triplet模型で示される挙動を示し、本物質中のTMTTFの3量体部分について、室温で形成されていた電荷秩序状態が低温では融解することが判った。
他の導電性成分分子を用いた研究の成果として、(BEDO-TTF)4(ReF6)(H2O)6が低温で高い導電性(4.2 Kで30-50 Scm-1)を持ったまま単分子磁石挙動を示す多重機能性を持つ分子性固体であることを明らかにした。また、比較的大きなサイズを持つ中性分子を組込むことによって、C60の-2価イオンが低温でも2量化しない塩を作製できることを示すなどの成果を得た。

Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

本研究の目的である、電子相転移に関して新規機構を発現させることは、分子性物質の機能性を引出し、遍歴電子系の基礎科学を進展させ、同時に相転移に伴う物性変化を利用した応用技術の基礎を与える課題である。
この研究目的の達成に向け、本研究課題申請書に記した研究計画に沿って多重不安定性物質の相転移挙動の実験的検討と閉殻陰イオン部位を含むTTF誘導体を用いた新規錯体の開拓研究を行っている。前者については、EDO-TTF塩の光誘起相転移挙動が対イオンに依存することを見出した。後者については、4個のカルボキシレート基を持つTTF誘導体の-2価陰イオンを用いることにより、第2のTTF誘導体との錯体を得ている。上述の通り、TTF核について電荷秩序化状態が形成された錯体を得ており、さらにその秩序が低温で部分的に融解することを見出している。
並行して検討している、他の導電性成分分子を用いた新規物質開拓においても興味ある物性を示す錯体を得ている。

Strategy for Future Research Activity

第2の課題である、閉殻陰イオン部位を含むTTF誘導体を用いた錯体について新規物質の開拓と構造・物性の検討に重点を置いて研究を進める。[TTF(CO2)4H2]だけではなく、他の負電荷を持つTTF誘導体を用いた物質開拓を行う。
また、予備実験段階ではあるが、(TMTTF)3[TTF(CO2)4H2]を酸性水溶液に浸漬した状態で通電すると導電性が増大する事を見出しており、その機構解明を含めた研究を行いたい。
置換基として閉殻陰イオン部位を持たない導電性成分分子を用いた物質開拓も継続する予定である。

Research Products

• [Int'l Joint Research] Institute/of Problems of Chemical Physics/RAS(Russia)
• [Int'l Joint Research] Institute/of Solid State Physics/RAS(Russia)
• [Int'l Joint Research] Department of Chemistry/University of Toronto(Canada)
• [Int'l Joint Research] Max Planck Institute/for the Structure and Dynamics of Matter(Germany)
• [Int'l Joint Research] Institute of Problems of Chem. Phys./Russian Academy of Sciences/Chernogolovka(Russia)
• [Int'l Joint Research] Institute of Solid State Physics/Russian Academy of Sciences/Chernogolovka(Russia)
• [Journal Article] Synthesis and properties of N-methylimidazole solvates of vanadium(II), chromium(II) and iron(II) phthalocyanines. Strong NIR absorption in VII(MeIm)2(Pc2－) (2018)
  • Author(s): Konarev Dmitri V.、Kuzmin Alexey V.、Nakano Yoshiaki、Khasanov Salavat S.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Dalton Trans. Volume: 47 Pages: 4661-4671
  • DOI: 10.1039/c8dt00459e
  • NAID: 120006416216
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range (2018)
  • Author(s): Kushch Nataliya D.、Buravov Lev I.、Kushch Pavel P.、Shilov Gennadii V.、Yamochi Hideki、Ishikawa Manabu、Otsuka Akihiro、Shakin Alexander A.、Maximova Olga V.、Volkova Olga S.、Vasiliev Alexander N.、Yagubskii Eduard B.
  • Journal Title: Inorganic Chemistry Volume: 57 Pages: 2386-2389
  • DOI: 10.1021/acs.inorgchem.7b03152
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Solid State Structure, and Optical and Magnetic Properties, of Free Base Tetra(4-pyridyl)porphyrin {H2T(4-Py)P}・- Radical Anions (2018)
  • Author(s): Konarev Dmitri V.、Kuzmin Aleksey V.、Khasanov Salavat S.、Shestakov Alexander F.、Yudanova Evgeniya I.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: The Journal of Organic Chemistry Volume: 83 Pages: 1861-1866
  • DOI: 10.1021/acs.joc.7b02791
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc・3-)}・-・2C6H4Cl2 (2018)
  • Author(s): Konarev Dmitri V.、Troyanov Sergey I.、Shestakov Alexander F.、Yudanova Evgeniya I.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Dalton Transactions Volume: 47 Pages: 1243-1250
  • DOI: 10.1039/c7dt03807k
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Interligand Charge Transfer in a Complex of Deprotonated cis-Indigo Dianions and Tin(II) Phthalocyanine Radical Anions with Cp*IrIII (2017)
  • Author(s): Konarev Dmitri V.、Zorina Leokadiya V.、Khasanov Salavat S.、Shestakov Alexander F.、Fatalov Alexey M.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Inorganic Chemistry Volume: 57 Pages: 583-589
  • DOI: 10.1021/acs.inorgchem.7b02351
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] cis-Thioindigo (TI) ? a new ligand with accessible radical anion and dianion states. Strong magnetic coupling in the {[TI-(μ2-O),(μ-O)]Cp*Cr}2 dimers (2017)
  • Author(s): Konarev Dmitri V.、Khasanov Salavat S.、Shestakov Alexander F.、Fatalov Alexey M.、Batov Mikhail S.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Dalton Trans. Volume: 46 Pages: 14365-14372
  • DOI: 10.1039/c7dt02878d
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Coordination Complexes of Fullerene C60 with Rhodium {Cp*RhII(μ-Cl)}2(η2,η2-C60) and (Bu4N+){Cp*RhICl(η2-C60)}-. Temperature-Induced Charge Transfer from RhI to η2-C60 (2017)
  • Author(s): Konarev Dmitri V.、Kuzmin Alexey V.、Khasanov Salavat S.、Troyanov Sergey I.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Organometallics Volume: 36 Pages: 4032-4037
  • DOI: 10.1021/acs.organomet.7b00660
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Solid state structures and properties of free-base 5,10,15-triphenylcorrole (TPCor) anions obtained by deprotonation and reduction. Effective magnetic coupling of spins in (Cp*2Cr+)(H+)(H2TPCor・2-)・C6H4Cl2 (2017)
  • Author(s): Konarev Dmitri V.、Karimov Dmitri R.、Khasanov Salavat S.、Shestakov Alexander F.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: Dalton Trans. Volume: 46 Pages: 13994-14001
  • DOI: 10.1039/c7dt02901b
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] The Concentration Control of Magnetic Fullerene C60・- Radical Anions in a Crystal Lattice of the (Bu4N+)2{(C60・-)・C6H4Cl2}x{[CpMo(CO)2C60]-}2-x (x=1, 0.74) Complexes (2017)
  • Author(s): Konarev Dmitri V.、Khasanov Salavat S.、Troyanov Sergey I.、Otsuka Akihiro、Yamochi Hideki、Kitagawa Hiroshi、Lyubovskaya Rimma N.
  • Journal Title: ChemistrySelect Volume: 2 Pages: 6640-6644
  • DOI: 10.1002/slct.201701083
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Design and Preparation of a Quantum Spin Liquid Candidate <i>κ</i>-(ET)₂Ag₂(CN)₃ Having a Nearby Superconductivity (2017)
  • Author(s): T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, M . Maesato, Y. Shimizu, H. Ito, Y. Nakamura, H. Kishida, M. Watanabe, R. Kumai
  • Journal Title: Bull. Chem. Soc. Jpn. Volume: 90 Issue: 9 Pages: 1073-1082
  • DOI: 10.1246/bcsj.20170167
  • Peer Reviewed / Open Access
• [Journal Article] Crystalline salts of metal phthalocyanine radical anions [M(Pc・3－)]・－ (M = CuII, PbII, VIVO, SnIVCl2) with cryptand(Na+) cations: structure, optical and magnetic propertie (2017)
  • Author(s): Konarev Dmitri V.、Faraonov Maxim A.、Kuzmin Alexey V.、Khasanov Salavat S.、Nakano Yoshiaki、Norko Semen I.、Batov Mikhail S.、Otsuka Akihiro、Yamochi Hideki、Saito Gunzi、Lyubovskaya Rimma N.
  • Journal Title: New J. Chem. Volume: 41 Pages: 6866-6874
  • DOI: 10.1039/c7nj00530j
  • NAID: 120006406844
  • Peer Reviewed / Open Access / Int'l Joint Research
• [Journal Article] Ultrafast electron diffraction study of single-crystal (EDO-TTF)2SbF6: Counterion effect and dimensionality reduction (2017)
  • Author(s): Liu Lai Chung、Jiang Yifeng、Mueller-Werkmeister Henrike M.、Lu Cheng、Moriena Gustavo、Ishikawa Manabu、Nakano Yoshiaki、Yamochi Hideki、Miller R.J. Dwayne
  • Journal Title: Chem. Phys. Lett. Volume: 683 Pages: 160-165
  • DOI: 10.1016/j.cplett.2017.05.007
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Racemic charge-transfer complexes of a helical polycyclic aromatic hydrocarbon molecule (2017)
  • Author(s): Yoshida Yukihiro、Nakamura Yuto、Kishida Hideo、Hayama Hiromi、Nakano Yoshiaki、Yamochi Hideki、Saito Gunzi
  • Journal Title: CrystEngComm Volume: 19 Pages: 3626-3632
  • DOI: 10.1039/c7ce00763a
  • NAID: 120006414194
  • Peer Reviewed / Open Access
• [Journal Article] Fullerene C60 dianion salt, (Me4N+)2(C60 2-)・(TPC)2・2C6H4Cl2, where TPC is triptycene, obtained by a multicomponent approach (2017)
  • Author(s): Konarev Dmitri V.、Troyanov Sergey I.、Otsuka Akihiro、Yamochi Hideki、Saito Gunzi、Lyubovskaya Rimma N.
  • Journal Title: New Journal of Chemistry Volume: 41 Pages: 4779-4782
  • DOI: 10.1039/c7nj01096f
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Tetrabutylammonium Salts of Aluminum(III) and Gallium(III) Phthalocyanine Radical Anions Bonded with Fluoren-9-olato? Anions and Indium(III) Phthalocyanine Bromide Radical Anions (2017)
  • Author(s): D. V. Konarev, S. S. Khasanov, M. Ishikawa, Y. Nakano, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Chemistry - An Asian Journal Volume: 12 Pages: 910-919
  • DOI: 10.1002/asia.201700138
  • NAID: 120006221992
  • Peer Reviewed / Open Access / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Charge transfer complexes of metal-free phthalocyanine radical anions with decamethylmetallocenium cations: (Cp*2Co+)(H2Pc・-)・solvent and (Cp*2Cr+)(H2Pc・-)・4C6H4Cl2 (2017)
  • Author(s): D.V. Konarev, S.S. Khasanov, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 46 Pages: 3492-3499
  • DOI: 10.1039/c7dt00336f
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] The Salts of Copper Octafluoro- and Hexadecafluorophthalocyanines Containing [CuII(F8Pc)4－]2－ Dianions and [CuF16Pc]－ Monoanions (2017)
  • Author(s): D.V. Konarev, S.I. Troyanov, A.V. Kuzmin, Y. Nakano, M. Ishikawa, M.A. Faraonov, S.S. Khasanov, A.L. Litvinov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Inorg. Chem. Volume: 56 Pages: 1804-1813
  • DOI: 10.1021/acs.inorgchem.6b01932
  • NAID: 120006406834
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Magnetic and optical properties of layered (Me4P+)[M(IV)O(Pc・3－)]・－ (TPC)0.5・C6H4Cl2 salts (M = Ti and V) composed of π-stacking dimers of titanyl and vanadyl phthalocyanine radical anions (2017)
  • Author(s): D.V. Konarev, Y. Nakano, S.S. Khasanov, A.V. Kuzmin, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Cryst. Growth Des. Volume: 17 Pages: 753-762
  • DOI: 10.1021/acs.cgd.6b01612
  • NAID: 120006406836
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl-)(μ2-η2,η2-C60)2 Dimers (2016)
  • Author(s): D.V. Konarev, S.S. Khasanov, A.F. Shestakov, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: J. Am. Chem. Soc. Volume: 138 Pages: 6592-16595
  • DOI: 10.1021/jacs.6b09890
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] cis-Conformation of Indigo in the Coordination Complex (Indigo-O,O)(Cp*CrIICl) (2016)
  • Author(s): D.V. Konarev, S.S. Khasanov, A.V. Kuzmin, A.F. Shestakov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 45 Pages: 17095-17099
  • DOI: 10.1039/c6dt03545k
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] BEDT-TTF Salts Formed with Tetrahedrally Coordinated Zinc(II) Complex Anions (2016)
  • Author(s): Yukihiro Yoshida, Hiroshi Ito, Yuto Nakamura, Manabu Ishikawa, Akihiro Otsuka, Hiromi Hayama, Mitsuhiko Maesato, Hideki Yamochi, Hideo Kishida, and Gunzi Saito
  • Journal Title: Cryst. Growth Des. Volume: 16 Pages: 6613-6630
  • DOI: 10.1021/acs.cgd.6b01294
  • NAID: 120005997973
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Cationic π-Stacking Columns of Coronene Molecules with Fully Charged and Charge-Disproportionated States (2016)
  • Author(s): Y. Yoshida, K. Isomura, M. Maesato, T. Koretsune, Y. Nakano, H. Yamochi, H. Kishida and G. Saito
  • Journal Title: Cryst. Growth Des. Volume: 16 Pages: 5994-6000
  • DOI: 10.1021/acs.cgd.6b01039
  • NAID: 120005997974
  • Peer Reviewed / Open Access / Acknowledgement Compliant
• [Journal Article] Bis(N-methylimidazole)-Substituted Neutral Phthalocyanines {MIII(MeIm)2(Pc)・3-}0 (M = Al, Ga) Containing Radical Trianionic Phthalocyanine Macrocycles (2016)
  • Author(s): D.V. Konarev, A.V. Kuzmin, S.S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2016 Pages: 4099-4013
  • DOI: 10.1002/ejic.201600680
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] Pressure-Tuned Exchange Coupling of a Quantum Spin Liquid in the Molecular Triangular Lattice κ－(ET)2Ag2(CN)3 (2016)
  • Author(s): Y. Shimizu, T. Hiramatsu, M. Maesato, A. Otsuka, H. Yamochi, A. Ono, M. Itoh, M. Yoshida, M. Takigawa, Y. Yoshida, G. Saito
  • Journal Title: Physical Review Letters 117, 107203 (2016) Volume: 117
  • DOI: 10.1103/physrevlett.117.107203
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] A Crystalline Anionic Complex of Scandium Nitride Endometallo-fullerene: Experimental Observation of Single-bonded (Sc3N@Ih-C80-)2 dimers (2016)
  • Author(s): D.V. Konarev, L.V. Zorina, S.S. Khasanov, A.A. Popov, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Chem. Commun. Volume: 52 Pages: 10763-10766
  • DOI: 10.1039/c6cc05550h
  • Peer Reviewed / Int'l Joint Research
• [Journal Article] SnPhPc phthalocyanines with dianion Pc2－ and radical trianion Pc・3－ macrocycles: syntheses, structures, and properties (2016)
  • Author(s): D.V. Konarev, A.V. Kuzmin, Y. Nakano, S.S. Khasanov, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R.N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 45 Pages: 10780-10788
  • DOI: 10.1039/c6dt01132b
  • NAID: 120006406837
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Synthesis, Structure, and Properties of the Fullerene C60 Salt of Crystal Violet, (CV+)(C60・-)・0.5C6H4Cl2, which Contained Closely Packed Zigzagged C60・- Chains (2016)
  • Author(s): D. V. Konarev, A. V. Kuzmin, S. S. Khasanov, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Chem. Asian J. Volume: 11 Pages: 1705-1710
  • DOI: 10.1002/asia.201600242
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Conducting π-columns of highly symmetric coronene, the smallest fragment of graphene (2016)
  • Author(s): Y. Yoshida, K. Isomura, H. Kishida, Y. Kumagai, M. Mizuno, M. Sakata, T. Koretsune, Y. Nakano, H. Yamochi, M. Maesato, G. Saito
  • Journal Title: Chemistry - A European Journal Volume: 22 Pages: 6023-6030
  • DOI: 10.1002/chem.201505023
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Charge Transfer Complexes of Fullerenes Containing C60・- and C70・- Radical Anions with Paramagnetic CoII(dppe)2Cl+ Cations (dppe: 1,2-Bis(diphenylphosphino)ethane) (2016)
  • Author(s): D. V. Konarev, S. I. Troyanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 45 Pages: 6548-6554
  • DOI: 10.1039/c5dt04627k
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Coordination Complexes of Transition Metals (M = Mo, Fe, Rh, and Ru) with Tin(II) Phthalocyanine in Neutral, Monoanionic, and Dianionic States (2016)
  • Author(s): D. V. Konarev, A. V. Kuzmin, Y. Nakano, M. A. Faraonov, S. S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Inorg. Chem. Volume: 55 Pages: 1390-1402
  • DOI: 10.1021/acs.inorgchem.5b01906
  • NAID: 120006223675
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Metallic Conductivity versus Charge Disproportionation in C60 Complexes with Noninteger Average Charges on Fullerene (2016)
  • Author(s): D.V. Konarev, S.S. Khasanov, M. Ishikawa, E.I. Yudanova, A.F. Shevchun, M.S. Mikhailov, P.A. Stuzhin, A. Otsuka, H. Yamochi, G. Saito , R.N. Lyubovskaya
  • Journal Title: ChemistrySelect Volume: 1 Pages: 323-330
  • DOI: 10.1002/slct.201500021
  • NAID: 120006406840
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Effective Magnetic Coupling with Strong Spin Frustration in (Ph3MeP+)(C60・･) and Reversible C60 Dimerization in (Ph3MeP+)(C60・&#8211;)･C6H5CN. Effect of Solvent on Structure and Properties (2016)
  • Author(s): D. V. Konarev, S. S. Khasanov, A. V. Kuzmin, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: New J. Chem. Volume: 40 Pages: 2792-2798
  • DOI: 10.1039/c5nj02886h
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Anionic coordination complexes of C60 and C70 with cyclopentadienyl and pentamethylcyclopentadienyl molybdenum dicarbonyl (2015)
  • Author(s): D. V. Konarev, A. V. Kuzmin, S. I. Troyanov, Y. Nakano, S. S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Dalton Transactions Volume: 印刷中 Pages: 9672-9681
  • DOI: 10.1039/c5dt00970g
  • NAID: 120006406838
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Formation of {Co(dppe)}2{μ2&#8211;η2:η2-η2:η2-[(C60)2]} Dimers Bonded by Two Single C－C Bonds and Two Bridging η2-Coordinated Cobalt Atoms (2015)
  • Author(s): D. V. Konarev, S. I. Troyanov, K. A. Ustimenko, Y. Nakano, A. F. Shestakov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Inorg. Chem. Volume: 印刷中 Pages: 4597-4599
  • DOI: 10.1021/acs.inorgchem.5b00637
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Local response to Light Excitation in the Chargeordered Phase of (EDO-TTF)2SbF6 (2015)
  • Author(s): M. Servol, N. Moisan, E. Collet, H. Cailleau, W. Kaszub, L. Toupet, D. Boschetto, T. Ishikawa, A. Moreac, S. Koshihara, M. Maesato, M. Uruichi, X. F. Shao, Y. Nakano, H. Yamochi, G. Saito, M. Lorenc
  • Journal Title: Phys. Rev. B Volume: 92
  • DOI: 10.1103/physrevb.92.024304
  • NAID: 120005997937
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Spin Frustration in Antiperovskite Systems: (TTF・+ or TSF・+)3[(Mo6X14)2-Y-] (2015)
  • Author(s): T. Hiramatsu, Y. Yoshida, G. Saito, A. Otsuka, H. Yamochi, Y. Shimizu, Y. Hattori, Y. Nakamura, H. Kishida, H. Ito, K. Kirakci, S. Cordier, C. Perrin
  • Journal Title: J. Mater. Chem. C Volume: 3 Pages: 11046-11054
  • DOI: 10.1039/c5tc02075a
  • NAID: 120005997963
  • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
• [Journal Article] Ambient-Pressure Organic Superconductor κ-(ET)2Ag(CN)[N(CN)2] Formed with Polymeric Silver(I) Complex Anion (2015)
  • Author(s): Y. Yoshida, H. Hayama, M. Ishikawa, A. Otsuka, H. Yamochi, Y. Nakamura, H. Kishida, H. Ito, M. Maesato, G. Saito
  • Journal Title: J. Phys. Soc. Jpn. Volume: 84 Issue: 12 Pages: 123801-123801
  • DOI: 10.7566/jpsj.84.123801
  • NAID: 120006027082
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Coordination Complexes of Pentamethylcyclopentadienyl Iridium(III) Halides with Tin(II) Phthalocyanine and Pentamethylcyclopentadienyl Iridium(II) Halides with Fullerene C60- Anions (2015)
  • Author(s): D. V. Konarev, S. I. Troyanov, A. V. Kuzmin, Y. Nakano, S. S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Organometallics Volume: 34 Pages: 879-889
  • DOI: 10.1021/om501210s
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Synthesis, Structures, and Properties of Crystalline Salts with Radical Anions of Metal-Containing and Metal-Free Phthalocyanines (2015)
  • Author(s): D. V. Konarev, A. V. Kuzmin, M. A. Faraonov, M. Ishikawa, S. S. Khasanov, Y. Nakano, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Chem. Eur. J. Volume: 21 Pages: 1014-1028
  • DOI: 10.1002/chem.201404925
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Molecular Structure, Optical and Magnetic Properties of the {SnIVPc(3-)Cl2}･- Radical Anions Containing Negatively Charged Pc Ligands (2014)
  • Author(s): D. V. Konarev, S. I. Troyanov, M. A. Faraonov, M. Ishikawa, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: J. Porphyrins Phthalocyanines Volume: 18 Pages: 1157-1163
  • DOI: 10.1142/s1088424614501077
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Linear Coordination Fullerene C60 Polymer [{Ni(Me3P)2}(μ-η2, η2-C60)]∞ Bridged by Zerovalent Nickel Atoms (2014)
  • Author(s): D. V. Konarev, S. S. Khasanov, Y. Nakano, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Inorg. Chem. Volume: 53 Pages: 11960-11965
  • DOI: 10.1021/ic501551y
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Molecular structure and optical properties of a nickel-bridged {Ni(Ph3P)}2(μ2-η2, η2-C60)2 dimer (2014)
  • Author(s): D. V. Konarev, S. I. Troyanov, Y. Nakano, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 43 Pages: 17920-17923
  • DOI: 10.1039/c4dt02161d
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Inclusion Complexes of Fullerenes with Flexible Tetrathiafulvalene Derivatives Bearing Four Aryls through the Sulfur Bridges (2014)
  • Author(s): J. Sun, X. Lu, M. Ishikawa, Y. Nakano, S. Zhang, J. Zhao, Y. Shao, Z. Wang, H. Yamochi, X.F. Shao
  • Journal Title: J. Mater. Chem. C Volume: 2 Pages: 8071-8076
  • DOI: 10.1039/c4tc01362j
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Design, crystal structures and magnetic properties of anionic salts containing fullerene C60 and indium(III) bromide phthalocyanine radical anions (2014)
  • Author(s): D. V. Konarev, A. V. Kuzmin, S. S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Dalton Trans. Volume: 43 Pages: 13061-13069
  • DOI: 10.1039/c4dt01153h
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Structural and Physical Properties of (EDO-TTF-Cl)2XF6 (X = As, Sb): Geometrical Aspects for Monosubstituted EDO-TTF (EDO-TTF = 4,5-ethylenedioxytetrathiafulvalene) (2014)
  • Author(s): M. Ishikawa, Y. Nakano, M. Uruichi, A. Otsuka, K. Yakushi, H. Yamochi
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2014 Pages: 3941-3948
  • DOI: 10.1002/ejic.201400128
  • NAID: 120005666189
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Layered Salts with Iron Hexadecachlorophthalocyanine Anions - The Formation of [{FeCl16Pc}2]3- Dimers Containing [FeICl16Pc(2-)]- and diamagnetic [Fe0Cl16Pc(2-)]2- (2014)
  • Author(s): D. V. Konarev, A. V. Kuzmin, M. Ishikawa, Y. Nakano, M. A. Faraonov, S. S. Khasanov, A. Otsuka, H. Yamochi, G. Saito, R. N. Lyubovskaya
  • Journal Title: Eur. J. Inorg. Chem. Volume: 2014 Pages: 3863-3870
  • DOI: 10.1002/ejic.201400126
  • Peer Reviewed / Acknowledgement Compliant
• [Journal Article] Diverse Photoinduced Dynamics in an Organic Charge-Transfer Complex Having Strong Electron-Phonon Interactions (2014)
  • Author(s): K. Onda, H. Yamochi, S. Koshihara
  • Journal Title: Acc. Chem. Res. Volume: 47 Pages: 3949-3503
  • DOI: 10.1021/ar500257b
  • Peer Reviewed / Open Access
• [Presentation] 含ヨウ素ドナー分子EDO-TTF-I から成る(EDO-TTF-I)2XF6 (X = P, As, Sb)の構造と物性 (2018)
  • Author(s): 石田 耕大, 髙橋 佑輔, 中野 義明, 石川 学, 矢持 秀起, 賣市 幹大
  • Organizer: 日本化学会第98春季年会
• [Presentation] 低対称多環芳香族炭化水素benzo[ghi]peryleneを用いた電荷移動錯体の開発：回転ならびに電子的挙動のcoronene錯体との比較 (2017)
  • Author(s): 吉田 幸大，丹後 駿介，磯村 和秀，中村 優斗，岸田 英夫，是常 隆，坂田 雅文，中野 義明，矢持 秀起，齋藤 軍治
  • Organizer: 第11回 分子科学討論会
• [Presentation] 全TTF型電荷秩序絶縁体の構築 (2017)
  • Author(s): 村上 賢太朗，上中 敬太，石川 学，中野 義明，賣市 幹大，大塚 晃弘，矢持 秀起
  • Organizer: 第11回 分子科学討論会
• [Presentation] 全TTF型周期的混晶における置換基サイズ効果の検討 (2017)
  • Author(s): 石川 学，上中 敬太，中野 義明，大塚 晃弘，矢持 秀起
  • Organizer: 第11回 分子科学討論会
• [Presentation] Charge-ordered Cation Radical Salts Prepared with a TTF Derivative Having Anionic Substituents (2016)
  • Author(s): K. Uenaka, M. Ishikawa, Y. Nakano, H. Yamochi
  • Organizer: The 12th Japan-China Joint Symposium on Conduction and Photoconduction in Organic Solids and Related Phenomena
  • Place of Presentation: 早稲田大学 西早稲田キャンパス
  • Year and Date: 2016-10-16
  • Int'l Joint Research
• [Presentation] TP-EDTTのReO4との陽イオンラジカル塩の構造と物性 (2016)
  • Author(s): 石川 学, 中野 義明, 大塚 晃弘, 賣市 幹大, 矢持 秀起
  • Organizer: 第10回 分子科学討論会
  • Place of Presentation: 神戸ファッションマート
  • Year and Date: 2016-09-13
• [Presentation] 3回対称性ドナー分子を用いた電荷移動錯体の合成と物性評価 (2016)
  • Author(s): 中野 義明, 大江 佳毅, 石川 学, 矢持 秀起, 売市 幹大
  • Organizer: 第10回 分子科学討論会
  • Place of Presentation: 神戸ファッションマート
  • Year and Date: 2016-09-13
• [Presentation] 陰イオン部位を持つTTF誘導体を用いた電荷秩序錯体の作製 (2016)
  • Author(s): 矢持 秀起
  • Organizer: 平成28年度物性研究所短期研究会
  • Place of Presentation: 東京大学 物性研究所
  • Year and Date: 2016-08-08
  • Invited
• [Presentation] EDO-TTF-ClのAg(CN)2との陽イオンラジカル塩の構造と物性 (2016)
  • Author(s): 石川 学・中野 義明・賣市 幹大・大塚 晃弘・矢持 秀起
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学 京田辺キャンパス
  • Year and Date: 2016-03-24
• [Presentation] Ag(I)含有ポリマー錯陰イオンを用いた新規BEDT-TTF 常圧超伝導体の開発 (2016)
  • Author(s): 吉田 幸大, 巴山 洋美, 石川 学, 大塚 晃弘, 矢持 秀起, 中村 優斗, 岸田 英夫, 伊東 裕, 前里 光彦, 齋藤 軍治
  • Organizer: 日本化学会第96春季年会
  • Place of Presentation: 同志社大学 京田辺キャンパス
  • Year and Date: 2016-03-24
• [Presentation] 高導電性コロネンπカラムの構築 (2015)
  • Author(s): 吉田 幸大, 磯村 和秀, 岸田 英夫, 熊谷 翼秀, 水野 元博, 坂田 雅文, 是常 隆, 中野 義明, 矢持 秀起, 前里 光彦, 齋藤 軍治
  • Organizer: 第9回 分子科学討論会
  • Place of Presentation: 東京工業大学 大岡山キャンパス
  • Year and Date: 2015-09-16
• [Presentation] 陰イオン部位を持つドナー [EDO-TTF-(CH3)PO3H]- の合成 (2015)
  • Author(s): 上中 敬太, 石川 学, 中野 義明, 矢持 秀起
  • Organizer: 第9回 分子科学討論会
  • Place of Presentation: 東京工業大学 大岡山キャンパス
  • Year and Date: 2015-09-16
• [Presentation] (EDO-TTF-Cl)2PF6の相転移挙動に対する圧力効果 (2015)
  • Author(s): 石川 学, 前里 光彦, 中野 義明, 平松 孝章, 賣市 幹大, 大塚 晃弘, 矢持 秀起, 齋藤 軍治
  • Organizer: 第9回 分子科学討論会
  • Place of Presentation: 東京工業大学 大岡山キャンパス
  • Year and Date: 2015-09-16
• [Presentation] 含ヨウ素TTF誘導体（EDO-TTF-I）を用いた陽イオンラジカル塩の構造と物性 (2015)
  • Author(s): 大江 佳毅, 髙橋 佑輔, 中野 義明, 石川 学, 矢持 秀起, 売市 幹大
  • Organizer: 第9回 分子科学討論会
  • Place of Presentation: 東京工業大学 大岡山キャンパス
  • Year and Date: 2015-09-16
• [Presentation] (TP-EDTT)2Brの合成、構造および物性 (2015)
  • Author(s): 石川 学, 中野 義明, 賣市 幹大, 大塚 晃弘, 矢持 秀起
  • Organizer: 日本化学会第95春季年会
  • Place of Presentation: 日本大学船橋キャンパス
  • Year and Date: 2015-03-26 – 2015-03-29
• [Presentation] (EDO-TTF-Cl)2XF6 (X = P, As, Sb)中の分子配列に対する陰イオンサイズ効果 (2014)
  • Author(s): 石川 学, 中野 義明, 賣市 幹大, 大塚 晃弘, 藥師 久彌, 矢持 秀起, 齋藤 軍治
  • Organizer: 第8回 分子科学討論会
  • Place of Presentation: 広島大学 東広島キャンパス
  • Year and Date: 2014-09-21 – 2014-09-24
• [Presentation] κ-(ET)2X錯体の構造とスピンフラストレーション (2014)
  • Author(s): 平松 孝章, 巴山 洋美, 吉田 幸大, 清水 康弘, 前里 光彦, 伊東 裕, 岸田 英夫, 大塚 晃弘, 矢持 秀起, 齋藤 軍治
  • Organizer: 第8回 分子科学討論会
  • Place of Presentation: 広島大学 東広島キャンパス
  • Year and Date: 2014-09-21 – 2014-09-24
• [Presentation] コロネンラジカル陽イオンを用いた3次元伝導性超分子ローターの開発 (2014)
  • Author(s): 吉田 幸大, 前里 光彦, 熊谷 翼秀, 水野 元博, 磯村 和秀, 岸田 英夫, 和泉 正成, 久保園 芳博, 大塚 晃弘, 矢持 秀起, 齋藤 軍治
  • Organizer: 第8回 分子科学討論会
  • Place of Presentation: 広島大学 東広島キャンパス
  • Year and Date: 2014-09-21 – 2014-09-24
• [Remarks] 理学研究科化学専攻 物性化学講座 分子性材料分科
  • URL: http://mms.ltm.kyoto-u.ac.jp/index.html
• [Remarks] Molecular Materials Science
  • URL: http://mms.ltm.kyoto-u.ac.jp/index_e.html
• [Remarks] ■京化■ 京都大学・理・化 -- 教員紹介（矢持 秀起）
  • URL: http://www.kuchem.kyoto-u.ac.jp/organization/member/yamochi.html
• [Remarks] Academic Staff (Hideki YAMOCHI)
  • URL: http://www.kuchem.kyoto-u.ac.jp/organization/member/yamochi_e.html
• [Remarks] List of Publications
  • URL: http://mms.ltm.kyoto-u.ac.jp/yamochi/list_pub.pdf
• [Remarks] 学会発表一覧(2005年以降)
  • URL: http://mms.ltm.kyoto-u.ac.jp/yamochi/list_presen.pdf
• [Remarks] 学会発表一覧 (2005 年以降)
  • URL: http://mms.ltm.kyoto-u.ac.jp/yamochi/list_presen.pdf