Synthesis and Photophysical Properties of Discrete Molecular Graphenes
| Project/Area Number |
26288038
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Partial Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Functional solid state chemistry
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| Research Institution | Nara Institute of Science and Technology |
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Principal Investigator |
Aratani Naoki 奈良先端科学技術大学院大学, 物質創成科学研究科, 准教授 (60372562)
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| Project Period (FY) |
2014-04-01 – 2017-03-31
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| Project Status |
Completed (Fiscal Year 2016)
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| Budget Amount *help |
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2016: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2015: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2014: ¥14,170,000 (Direct Cost: ¥10,900,000、Indirect Cost: ¥3,270,000)
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| Keywords | アセン / 有機半導体 / 結晶 / グラフェン / 分子デバイス / 超分子 |
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| Outline of Final Research Achievements |
On the basis of transition-metal catalyzed coupling reaction, we have prepared a tetrabenzoperipentacene and a fused pyrene trimer. These structures are considered as nano-graphene models. Oxidative ring closure reaction of a tetranaphthylpyrene derivative allowed synthesis of the all-56-carbon conjugative tetrabenzoperipentacene. From the X-ray structure, it is revealed that three molecules make a triple-layered cluster via π-stacking manner in which each layer rotates by 120°, considered as a petit β-graphite.
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Report
(4 results)
Research Products
(102 results)
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[Journal Article] β-to-β 2,5-Pyrrolylene-Linked Cyclic Porphyrin Oligomers2016
Author(s)
Y. Rao, J. O. Kim, W. Kim, G. Zhong, B. Yin, M. Zhou, H. Shinokubo, N. Aratani, T. Tanaka, S. Liu, A. Osuka, D. Kim, J. Song
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Journal Title
Chem. Eur. J.
Volume: 52
Issue: 26
Pages: 8801-8804
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Benzo[4,5]cyclohepta[1,2-b]fluorene: an isomeric motif for pentacene containing linearly fused five-, six- and seven-membered rings2016
Author(s)
X. Yang, X. Shi, N. Aratani, T. P. Gonalves, K.-W. Huang, H. Yamada, C. Chi, Q. Miao
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Journal Title
Chem. Sci.
Volume: 7
Issue: 9
Pages: 6176-6181
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Toward Tetraradicaloid: The Effect of Fusion Mode on Radical Character and Chemical Reactivity2016
Author(s)
Pan Hu, Sangsu Lee, Tun Seng Herng, Naoki Aratani, Théo P. Gonçalves, Qingbiao Qi, Xueliang Shi, Hiroko Yamada, Kuo-Wei Huang, Jun Ding, Dongho Kim, and Jishan Wu
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Journal Title
J. Am. Chem. Soc.
Volume: 138
Issue: 3
Pages: 1065-1077
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Synthesis, characterization and memory performance of two organic small molecules through donor-acceptor design2015
Author(s)
C. Wang, M. Yamashita, B. Hu, Y. Zhou, J. Wang, J. Wu, F. Huo, P. S. Lee, N. Aratani, H. Yamada, Q. Zhang,
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Journal Title
Asian J. Org. Chem.
Volume: 4
Issue: 7
Pages: 646-651
DOI
Related Report
Peer Reviewed / Int'l Joint Research
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[Journal Article] Evaluation of semiconducting molecular thin films solution-processed via the photoprecursor approach: the case of hexyl-substituted thinoanthracenes2015
Author(s)
C. Quinton, M. Suzuki, Y. Kaneshige, Y. Tatenaka, C. Katagiri, Y. Yamaguchi, D. Kuzuhara, N. Aratani, K. Nakayama, H. Yamada,
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Journal Title
J. Mater. Chem. C
Volume: 3
Issue: 23
Pages: 5995-6005
DOI
Related Report
Peer Reviewed
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[Presentation] イミドナフタレン縮環TTFの合成と物性2015
Author(s)
山下 正貴, 荒谷 直樹, Burnett Ned, Zhang Lei, Briseno Alejandro, 山田容子
Organizer
第26回基礎有機化学討論会
Place of Presentation
愛媛大学（愛媛県松山市）
Year and Date
2015-09-24
Related Report
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